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28 Apr 02:15

Hot Paper: One-Pot Sequence-Controlled Synthesis of Oligosiloxanes

Dr. Kazuhiro Matsumoto, Yuki Oba, Dr. Yumiko Nakajima, Dr. Shigeru Shimada and Dr. Kazuhiko Sato

One-Pot Sequence-Controlled Synthesis of Oligosiloxanes

An orderly approach: A one-pot iteration of B(C6F5)3-catalyzed dehydrocarbonative cross-coupling of alkoxysilanes with hydrosilanes and B(C6F5)3-catalyzed hydrosilylation of carbonyl compounds enables a highly selective sequence-controlled synthesis of linear, branched, and cyclic oligosiloxanes. The sequence of the resulting oligosiloxanes can be controlled precisely by the order of addition of the hydrosilane monomers.

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30 Mar 01:11

[ASAP] Coordination Chemistry of a Strongly-Donating Hydroxylamine with Early Actinides: An Investigation of Redox Properties and Electronic Structure

by Alex McSkimming, Jing Su, Thibault Cheisson, Michael R. Gau, Patrick J. Carroll, Enrique R. Batista, Ping Yang, Eric J. Schelter

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Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.7b03238
26 Mar 10:10

Emerging chemical strategies for imprinting magnetism in graphene and related 2D materials for spintronic and biomedical applications

Chem. Soc. Rev., 2018, 47,3899-3990
DOI: 10.1039/C7CS00288B, Review Article
Jiri Tucek, Piotr Blonski, Juri Ugolotti, Akshaya Kumar Swain, Toshiaki Enoki, Radek Zboril
The review highlights recent theoretical and experimental advancements in imprinting and tuning magnetic properties in graphene and related 2D materials by various chemical approaches.
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22 Mar 01:30

[ASAP] Advances in the Synthesis of Small Molecules as Hole Transport Materials for Lead Halide Perovskite Solar Cells

by Cristina Rodríguez-Seco, Lydia Cabau, Anton Vidal-Ferran and Emilio Palomares

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Accounts of Chemical Research
DOI: 10.1021/acs.accounts.7b00597
22 Mar 01:28

[ASAP] Guanidinium-Formamidinium Lead Iodide: A Layered Perovskite-Related Compound with Red Luminescence at Room Temperature

by Olga Nazarenko, Martin R. Kotyrba, Sergii Yakunin, Marcel Aebli, Gabriele Rainò, Bogdan M. Benin, Michael Wörle and Maksym V. Kovalenko

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Journal of the American Chemical Society
DOI: 10.1021/jacs.8b00194
22 Mar 01:27

[ASAP] All-Inorganic CsPbI2Br Perovskite Solar Cells with High Efficiency Exceeding 13%

by Chong Liu, Wenzhe Li, Cuiling Zhang, Yunping Ma, Jiandong Fan and Yaohua Mai

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Journal of the American Chemical Society
DOI: 10.1021/jacs.7b13229
22 Mar 01:23

[ASAP] Nonfullerene Acceptor Molecules for Bulk Heterojunction Organic Solar Cells

by Guangye Zhang, Jingbo Zhao, Philip C. Y. Chow, Kui Jiang, Jianquan Zhang, Zonglong Zhu, Jie Zhang, Fei Huang and He Yan

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Chemical Reviews
DOI: 10.1021/acs.chemrev.7b00535
12 Mar 01:57

Enhanced Photosensitized Hydrogen Production by Encapsulation of Ferrocenyl Dyes into Single-Walled Carbon Nanotubes

by Noritake Murakami, Hideaki Miyake, Tomoyuki Tajima, Kakeru Nishikawa, Ryutaro Hirayama and Yutaka Takaguchi

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Journal of the American Chemical Society
DOI: 10.1021/jacs.7b12845
05 Mar 01:44

Bonding inside and outside Fullerene Cages

by Lipiao Bao, Ping Peng and Xing Lu

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Accounts of Chemical Research
DOI: 10.1021/acs.accounts.8b00014
05 Mar 01:43

Metal-Free Carbocatalysis in Advanced Oxidation Reactions

by Xiaoguang Duan, Hongqi Sun and Shaobin Wang

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Accounts of Chemical Research
DOI: 10.1021/acs.accounts.7b00535
05 Mar 01:37

Theoretical Insights into Monometallofullerene Th@C76: Strong Covalent Interaction between Thorium and the Carbon Cage

by Pei Zhao, Xiang Zhao and Masahiro Ehara

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Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.7b03114
24 Feb 02:29

Formation of Stable Mixed Guanidinium–Methylammonium Phases with Exceptionally Long Carrier Lifetimes for High-Efficiency Lead Iodide-Based Perovskite Photovoltaics

by Dominik J. Kubicki, Daniel Prochowicz, Albert Hofstetter, Marcin Saski, Pankaj Yadav, Dongqin Bi, Norman Pellet, Janusz Lewiński, Shaik M. Zakeeruddin, Michael Grätzel and Lyndon Emsley

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Journal of the American Chemical Society
DOI: 10.1021/jacs.7b12860
21 Feb 05:38

White-Light Emission from Layered Halide Perovskites

by Matthew D. Smith and Hemamala I. Karunadasa

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Accounts of Chemical Research
DOI: 10.1021/acs.accounts.7b00433
14 Feb 13:35

Mn Self-Doping of Orthorhombic RMnO3 Perovskites: (R0.667Mn0.333)MnO3 with R = Er–Lu

by Lei Zhang, Dominic Gerlach, Andreas Dönni, Toyohiro Chikyow, Yoshio Katsuya, Masahiko Tanaka, Shigenori Ueda, Kazunari Yamaura and Alexei A. Belik

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Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.7b03188
14 Feb 13:33

Steering the Geometry of Butterfly-Shaped Dimetal Carbide Cluster within a Carbon Cage via Trifluoromethylation of Y2C2@C82(6)

by Fei Jin, Nadezhda B. Tamm, Sergey I. Troyanov and Shangfeng Yang

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Journal of the American Chemical Society
DOI: 10.1021/jacs.7b12925
14 Feb 13:28

U2@Ih(7)-C80: Crystallographic Characterization of a Long-Sought Dimetallic Actinide Endohedral Fullerene

by Xingxing Zhang, Yaofeng Wang, Roser Morales-Martínez, Jun Zhong, Coen de Graaf, Antonio Rodríguez-Fortea, Josep M. Poblet, Luis Echegoyen, Lai Feng and Ning Chen

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Journal of the American Chemical Society
DOI: 10.1021/jacs.7b10865
14 Feb 13:25

Electron Accumulative Molecules

by Ana B. Buades, Víctor Sanchez Arderiu, David Olid-Britos, Clara Viñas, Reijo Sillanpää, Matti Haukka, Xavier Fontrodona, Markos Paradinas, Carmen Ocal and Francesc Teixidor

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Journal of the American Chemical Society
DOI: 10.1021/jacs.7b12815
05 Feb 06:29

Fluoranthene-based dopant-free hole transporting materials for efficient perovskite solar cells

Chem. Sci., 2018, 9,2698-2704
DOI: 10.1039/C7SC05484J, Edge Article
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xianglang Sun, Qifan Xue, Zonglong Zhu, Qi Xiao, Kui Jiang, Hin-Lap Yip, He Yan, Zhong'an Li
Unreported 2,3-dicyano-fluoranthene was first prepared as an efficient electron-withdrawing building block for constructing D-A type dopant-free hole transporting materials.
The content of this RSS Feed (c) The Royal Society of Chemistry
05 Feb 06:25

Pseudohalogen-Based 2D Perovskite: A More Complex Thermal Degradation Mechanism Than 3D Perovskite

by Yanping Lv, Duanhui Si, Xuedan Song, Kai Wang, Shi Wang, Zhengyan Zhao, Ce Hao, Lijuan Wei and Yantao Shi

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Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.7b02949
29 Jan 08:51

High-Efficiency Cycloruthenated Sensitizers for Dye-Sensitized Solar Cells

by The-Duy Nguyen, Yen-Po Lan and Chun-Guey Wu

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Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.7b02862
15 Jan 01:09

Molecular design to regulate the photophysical properties of multifunctional TADF emitters towards high-performance TADF-based OLEDs with EQEs up to 22.4% and small efficiency roll-offs

Chem. Sci., 2018, 9,1385-1391
DOI: 10.1039/C7SC04669C, Edge Article
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ling Yu, Zhongbin Wu, Guohua Xie, Weixuan Zeng, Dongge Ma, Chuluo Yang
The photophysical properties of four new quinoxaline derivatives featuring both AIE and TADF characteristics were controlled to give high EQEs.
The content of this RSS Feed (c) The Royal Society of Chemistry
15 Jan 01:07

Mixed Sulfur and Iodide-Based Lead-Free Perovskite Solar Cells

by Riming Nie, Aarti Mehta, Byung-wook Park, Hyoung-Woo Kwon, Jino Im and Sang Il Seok

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Journal of the American Chemical Society
DOI: 10.1021/jacs.7b11332
15 Jan 01:05

Endohedral Metallofullerene as Molecular High Spin Qubit: Diverse Rabi Cycles in Gd2@C79N

by Ziqi Hu, Bo-Wei Dong, Zheng Liu, Jun-Jie Liu, Jie Su, Changcheng Yu, Jin Xiong, Di-Er Shi, Yuanyuan Wang, Bing-Wu Wang, Arzhang Ardavan, Zujin Shi, Shang-Da Jiang and Song Gao

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Journal of the American Chemical Society
DOI: 10.1021/jacs.7b12170
15 Jan 01:04

Chlorine-Incorporation-Induced Formation of the Layered Phase for Antimony-Based Lead-Free Perovskite Solar Cells

by Fangyuan Jiang, Dongwen Yang, Youyu Jiang, Tiefeng Liu, Xingang Zhao, Yue Ming, Bangwu Luo, Fei Qin, Jiacheng Fan, Hongwei Han, Lijun Zhang and Yinhua Zhou

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Journal of the American Chemical Society
DOI: 10.1021/jacs.7b10739
02 Jan 06:22

Exploration of Crystallization Kinetics in Quasi Two-Dimensional Perovskite and High Performance Solar Cells

by Ning Zhou, Yiheng Shen, Liang Li, Shunquan Tan, Na Liu, Guanhaojie Zheng, Qi Chen and Huanping Zhou

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Journal of the American Chemical Society
DOI: 10.1021/jacs.7b11157
23 Dec 06:44

Dopant-Free Tetrakis-Triphenylamine Hole Transporting Material for Efficient Tin-Based Perovskite Solar Cells

by Weijun Ke, Pragya Priyanka, Sureshraju Vegiraju, Constantinos C. Stoumpos, Ioannis Spanopoulos, Chan Myae Myae Soe, Tobin J. Marks, Ming-Chou Chen and Mercouri G. Kanatzidis

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Journal of the American Chemical Society
DOI: 10.1021/jacs.7b10898
18 Dec 11:03

“Double-Cable” Conjugated Polymers with Linear Backbone toward High Quantum Efficiencies in Single-Component Polymer Solar Cells

by Guitao Feng, Junyu Li, Fallon J. M. Colberts, Mengmeng Li, Jianqi Zhang, Fan Yang, Yingzhi Jin, Fengling Zhang, René A. J. Janssen, Cheng Li and Weiwei Li

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Journal of the American Chemical Society
DOI: 10.1021/jacs.7b10499
11 Dec 12:25

Direct Microscopic Analysis of Individual C60 Dimerization Events: Kinetics and Mechanisms

by Satoshi Okada, Satori Kowashi, Luca Schweighauser, Kaoru Yamanouchi, Koji Harano and Eiichi Nakamura

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Journal of the American Chemical Society
DOI: 10.1021/jacs.7b09776
07 Dec 13:29

Facile Access to Azafullerenyl Cation C59N+ and Specific Interaction with Entrapped Molecules

by Yoshifumi Hashikawa and Yasujiro Murata

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Journal of the American Chemical Society
DOI: 10.1021/jacs.7b11322
07 Dec 13:10

Lewis Acid–Base Adducts of Sc2C2@C3v(8)-C82/N-Heterocyclic Carbene: Toward Isomerically Pure Metallofullerene Derivatives

by Lipiao Bao, Muqing Chen, Wangqiang Shen, Le Yang, Peng Jin and Xing Lu

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Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.7b02578