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14 Jan 00:10

Unprecedented redox-driven ligand ejection in nickel(II)-diiminosemiquinonate radical complexes

Jon Beves

Redox switch

Chem. Commun., 2014, 50,1918-1920
DOI: 10.1039/C3CC48549H, Communication
N. Leconte, J. Ciccione, G. Gellon, C. Philouze, F. Thomas
One polydentate diiminosemiquinonate ligand is ejected upon electrochemical oxidation. The Ni(II) ion remains square planar throughout the process, the ligand alone supporting all the redox events.
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