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22 Sep 03:27

Conductivity in organic semiconductors hybridized with the vacuum field

by E. Orgiu

Nature Materials. doi:10.1038/nmat4392

Authors: E. Orgiu, J. George, J. A. Hutchison, E. Devaux, J. F. Dayen, B. Doudin, F. Stellacci, C. Genet, J. Schachenmayer, C. Genes, G. Pupillo, P. Samorì & T. W. Ebbesen

15 Sep 09:11

Direct mapping of Li-enabled octahedral tilt ordering and associated strain in nanostructured perovskites

by Ye Zhu

Nature Materials. doi:10.1038/nmat4390

Authors: Ye Zhu, Ray L. Withers, Laure Bourgeois, Christian Dwyer & Joanne Etheridge

15 Sep 09:10

Flexible high power-per-weight perovskite solar cells with chromium oxide–metal contacts for improved stability in air

by Martin Kaltenbrunner

Nature Materials. doi:10.1038/nmat4388

Authors: Martin Kaltenbrunner, Getachew Adam, Eric Daniel Głowacki, Michael Drack, Reinhard Schwödiauer, Lucia Leonat, Dogukan Hazar Apaydin, Heiko Groiss, Markus Clark Scharber, Matthew Schuette White, Niyazi Serdar Sariciftci & Siegfried Bauer

15 Sep 09:08

Perovskite photovoltaics: Hovering solar cells

by Michele Sessolo

Nature Materials. doi:10.1038/nmat4405

Authors: Michele Sessolo & Henk J. Bolink

Ultrathin, flexible and lightweight perovskite solar cells with improved stability in air can now power model airplanes for several hours.

15 Sep 09:04

Infrared Spectroscopic Study of Vibrational Modes in Methylammonium Lead Halide Perovskites

by Tobias Glaser, Christian Müller, Michael Sendner, Christian Krekeler, Octavi E. Semonin, Trevor D. Hull, Omer Yaffe, Jonathan S. Owen, Wolfgang Kowalsky, Annemarie Pucci and Robert Lovrinčić

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01309
15 Sep 09:04

Pathways for H2 Activation on (Ni)-MoS2 Catalysts

by Eva Schachtl, Elena Kondratieva, Oliver Y. Gutiérrez and Johannes A. Lercher

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01217
15 Sep 09:04

Exciton Binding Energy and the Nature of Emissive States in Organometal Halide Perovskites

by Kaibo Zheng, Qiushi Zhu, Mohamed Abdellah, Maria E. Messing, Wei Zhang, Alexander Generalov, Yuran Niu, Lynn Ribaud, Sophie E. Canton and Tõnu Pullerits

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01252
15 Sep 09:03

Spatial Localization of Excitons and Charge Carriers in Hybrid Perovskite Thin Films

by Mary Jane Simpson, Benjamin Doughty, Bin Yang, Kai Xiao and Ying-Zhong Ma

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01050
15 Sep 09:03

Boron Subphthalocyanines as Triplet Harvesting Materials within Organic Photovoltaics

by Jeffrey S. Castrucci, David S. Josey, Emmanuel Thibau, Zheng-Hong Lu and Timothy P. Bender

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01254
15 Sep 09:02

Exploring Thermochromic Behavior of Hydrated Hybrid Perovskites in Solar Cells

by Ansuman Halder, Devika Choudhury, Soham Ghosh, Anand S. Subbiah and Shaibal K Sarkar

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01426
15 Sep 09:02

Observable Hysteresis at Low Temperature in “Hysteresis Free” Organic–Inorganic Lead Halide Perovskite Solar Cells

by Daniel Bryant, Scot Wheeler, Brian C. O’Regan, Trystan Watson, Piers R. F. Barnes, Dave Worsley and James Durrant

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01381
15 Sep 09:02

Cubic Perovskite Structure of Black Formamidinium Lead Iodide, α-[HC(NH2)2]PbI3, at 298 K

by Mark T. Weller, Oliver J. Weber, Jarvist M. Frost and Aron Walsh

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01432
15 Sep 09:02

Surface Charge Trapping in Organolead Halide Perovskites Explored by Single-Particle Photoluminescence Imaging

by Takashi Tachikawa, Izuru Karimata and Yasuhiro Kobori

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01566
15 Sep 09:01

Organometal Trihalide Perovskite Single Crystals: A Next Wave of Materials for 25% Efficiency Photovoltaics and Applications Beyond?

by Jinsong Huang, Yuchuan Shao and Qingfeng Dong

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01419
15 Sep 08:57

Exciton Diffusion in Conjugated Polymers: From Fundamental Understanding to Improvement in Photovoltaic Conversion Efficiency

by Yasunari Tamai, Hideo Ohkita, Hiroaki Benten and Shinzaburo Ito

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01147
15 Sep 08:56

Antagonism between Spin–Orbit Coupling and Steric Effects Causes Anomalous Band Gap Evolution in the Perovskite Photovoltaic Materials CH3NH3Sn1–xPbxI3

by Jino Im, Constantinos C. Stoumpos, Hosub Jin, Arthur J. Freeman and Mercouri G. Kanatzidis

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01738
15 Sep 08:56

Temperature-Dependent Polarization in Field-Effect Transport and Photovoltaic Measurements of Methylammonium Lead Iodide

by John G. Labram, Douglas H. Fabini, Erin E. Perry, Anna J. Lehner, Hengbin Wang, Anne M. Glaudell, Guang Wu, Hayden Evans, David Buck, Robert Cotta, Luis Echegoyen, Fred Wudl, Ram Seshadri and Michael L. Chabinyc

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01669
15 Sep 08:55

Static and Dynamic Energetic Disorders in the C60, PC61BM, C70, and PC71BM Fullerenes

by Naga Rajesh Tummala, Zilong Zheng, Saadullah G. Aziz, Veaceslav Coropceanu and Jean-Luc Brédas

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01709
15 Sep 08:54

Real-Time Observation of Organic Cation Reorientation in Methylammonium Lead Iodide Perovskites

by Artem A. Bakulin, Oleg Selig, Huib J. Bakker, Yves L.A. Rezus, Christian Müller, Tobias Glaser, Robert Lovrincic, Zhenhua Sun, Zhuoying Chen, Aron Walsh, Jarvist M. Frost and Thomas L. C. Jansen

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01555
15 Sep 08:54

Charge Transfer Dynamics from Organometal Halide Perovskite to Polymeric Hole Transport Materials in Hybrid Solar Cells

by Jan C. Brauer, Yong Hui Lee, Mohammad Khaja Nazeeruddin and Natalie Banerji

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01698
15 Sep 08:52

Mixed Iodide–Bromide Methylammonium Lead Perovskite-based Diodes for Light Emission and Photovoltaics

by Lidón Gil-Escrig, Araceli Miquel-Sempere, Michele Sessolo and Henk J. Bolink

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01716
15 Sep 08:51

Modeling Anomalous Hysteresis in Perovskite Solar Cells

by Stephan van Reenen, Martijn Kemerink and Henry J. Snaith

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01645
25 Jul 01:02

Charge Carriers in Planar and Meso-Structured Organic–Inorganic Perovskites: Mobilities, Lifetimes, and Concentrations of Trap States

by Eline M. Hutter, Giles E. Eperon, Samuel D. Stranks and Tom J. Savenije

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b01361
09 Mar 01:23

Correction to “Emergence of Hysteresis and Transient Ferroelectric Response in Organo-Lead Halide Perovskite Solar Cells”

by Hsin-Wei Chen, Nobuya Sakai, Masashi Ikegami and Tsutomu Miyasaka
The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.5b00408
05 Feb 03:10

Zr Incorporation into TiO2 Electrodes Reduces Hysteresis and Improves Performance in Hybrid Perovskite Solar Cells while Increasing Carrier Lifetimes

by Hirokazu Nagaoka, Fei Ma, Dane W. deQuilettes, Sarah M. Vorpahl, Micah S. Glaz, Adam E. Colbert, Mark E. Ziffer and David S. Ginger

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/jz502694g
05 Feb 03:09

Mechanical Origin of the Structural Phase Transition in Methylammonium Lead Iodide CH3NH3PbI3

by Khuong P. Ong, Teck Wee Goh, Qiang Xu and Alfred Huan

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/jz502740d
31 Jan 07:49

Size-Dependent Photon Emission from Organometal Halide Perovskite Nanocrystals Embedded in an Organic Matrix

by Dawei Di, Kevin P. Musselman, Guangru Li, Aditya Sadhanala, Yulia Ievskaya, Qilei Song, Zhi-Kuang Tan, May Ling Lai, Judith L. MacManus-Driscoll, Neil C. Greenham and Richard H. Friend

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/jz502615e
31 Jan 07:48

Fabrication of Planar Heterojunction Perovskite Solar Cells by Controlled Low-Pressure Vapor Annealing

by Yanbo Li, Jason K. Cooper, Raffaella Buonsanti, Cinzia Giannini, Yi Liu, Francesca M. Toma and Ian D. Sharp

TOC Graphic

The Journal of Physical Chemistry Letters
DOI: 10.1021/jz502720a
14 Jan 13:18

Compositional engineering of perovskite materials for high-performance solar cells

by Nam Joong Jeon

Of the many materials and methodologies aimed at producing low-cost, efficient photovoltaic cells, inorganic–organic lead halide perovskite materials appear particularly promising for next-generation solar devices owing to their high power conversion efficiency. The highest efficiencies reported for perovskite solar cells so far have been obtained mainly with methylammonium lead halide materials. Here we combine the promising—owing to its comparatively narrow bandgap—but relatively unstable formamidinium lead iodide (FAPbI3) with methylammonium lead bromide (MAPbBr3) as the light-harvesting unit in a bilayer solar-cell architecture. We investigated phase stability, morphology of the perovskite layer, hysteresis in current–voltage characteristics, and overall performance as a function of chemical composition. Our results show that incorporation of MAPbBr3 into FAPbI3 stabilizes the perovskite phase of FAPbI3 and improves the power conversion efficiency of the solar cell to more than 18 per cent under a standard illumination of 100 milliwatts per square centimetre. These findings further emphasize the versatility and performance potential of inorganic–organic lead halide perovskite materials for photovoltaic applications.

Nature doi: 10.1038/nature14133

14 Jan 08:31

Impact of mesoscale order on open-circuit voltage in organic solar cells

by Carl Poelking

Nature Materials. doi:10.1038/nmat4167

Authors: Carl Poelking, Max Tietze, Chris Elschner, Selina Olthof, Dirk Hertel, Björn Baumeier, Frank Würthner, Klaus Meerholz, Karl Leo & Denis Andrienko