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14 Aug 10:55

Field-Induced n-Doping of Black Phosphorus for CMOS Compatible 2D Logic Electronics with High Electron Mobility

by Yijun Xu, Jian Yuan, Kai Zhang, Yuan Hou, Qiu Sun, Yingming Yao, Shaojuan Li, Qiaoliang Bao, Han Zhang, Yuegang Zhang

Black phosphorus (BP) has been considered as a promising two-dimensional (2D) semiconductor beyond graphene owning to its tunable direct bandgap and high carrier mobility. However, the hole-transport-dominated characteristic limits the application of BP in versatile electronics. Here, we report a stable and complementary metal oxide semiconductor (COMS) compatible electron doping method for BP, which is realized with the strong field-induced effect from the K+ center of the silicon nitride (SixNy). An obvious change from pristine p-type BP to n type is observed after the deposit of the SixNy on the BP surface. This electron doping can be kept stable for over 1 month and capable of improving the electron mobility of BP towards as high as ~176 cm2 V–1 s–1. Moreover, high-performance in-plane BP p-n diode and further logic inverter were realized by utilizing the n-doping approach. The BP p-n diode exhibits a high rectifying ratio of ~104. And, a successful transfer of the output voltage from “High” to “Low” with very few voltage loss at various working frequencies were also demonstrated with the constructed BP inverter. Our findings paves the way for the success of COMS compatible technique for BP-based nanoelectronics.

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A stable and complementary metal oxide semiconductor (CMOS) compatible electron doping strategy for black phosphorus is realized with a field-induced effect. The effective electron doping with highly improved electron mobility enables the fabrication of high-performance logic devices, including a PN diode with rectifying ratio up to ≈104 and an inverter that is compatible with various driving frequencies.

18 Jun 12:07

Molybdenum Disulfide–Black Phosphorus Hybrid Nanosheets as a Superior Catalyst for Electrochemical Hydrogen Evolution

by Rong He, Jian Hua, Anqi Zhang, Chuanhao Wang, Jiayu Peng, Weijia Chen and Jie Zeng

TOC Graphic

Nano Letters
DOI: 10.1021/acs.nanolett.7b01334
28 Dec 02:50

2,4,6-Tri(hydroxy)-1,3,5-triphosphinine, P3C3(OH)3: The Phosphorus Analogue of Cyanuric Acid

by Riccardo Suter, Yanbo Mei, Matthew Baker, Zoltan Benkő, Zhongshu Li, Hansjörg Grützmacher

Abstract

Cyanuric acid (C3H3N3O3) is widely used as cross-linker in basic polymers (often in combination with other crosslinking agents like melamine) but also finds application in more sophisticated materials such as in supramolecular assemblies and molecular sheets. The unknown phosphorus analogue of cyanuric acid, P3C3(OH)3, may become an equally useful building block for phosphorus-based polymers or materials which have unique properties. Herein we describe a straightforward synthesis of 2,4,6-tri(hydroxy)-1,3,5-triphosphinine and its derivatives P3C3(OR)3 which have been applied as strong π-acceptor η6-ligands in piano stool Mo(CO)3 complexes.

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Done in three ticks: The trimerization of boryl-substituted phosphaalkynes allows the straightforward synthesis of triphosphabenzenes on a multi-gram scale. These compounds give stable metal complexes and can be further functionalized at the oxygen centers.

30 Oct 14:00

Josephson current signatures of the Majorana flat bands on the surface of time-reversal-invariant Weyl and Dirac semimetals. (arXiv:1610.08553v3 [cond-mat.supr-con] UPDATED)

by Anffany Chen, D.I. Pikulin, M. Franz

A linear Josephson junction mediated by the surface states of a time-reversal-invariant Weyl or Dirac semimetal localizes Majorana flat bands protected by the time-reversal symmetry. We show that as a result, the Josephson current exhibits a discontinuous jump at $\pi$ phase difference which can serve as an experimental signature of the Majorana bands. The magnitude of the jump scales proportionally to the junction width and the momentum space distance between the Weyl nodes. It also exhibits a characteristic dependence on the junction orientation. We demonstrate that the jump is robust against the effects of non-zero temperature and weak non-magnetic disorder.

21 Sep 03:14

Hotspot-engineered quasi-3D metallic network for surface-enhanced Raman scattering based on colloid monolayer templating

by Wei Du, Long Liu, Ping Gu, Jingguo Hu, Peng Zhan, Fanxin Liu and Zhenlin Wang

A hotspot-engineered quasi-3D metallic network with controllable nanogaps is purposed as a high-quality surface-enhanced Raman scattering (SERS) substrate, which is prepared by a combination of non-close-packed colloid monolayer templating and metal physical deposition. The significant SERS effect arises from a strongly enhanced local electric field originating from the ultra-small-gaps between neighboring metal-caps and tiny interstices and between the metal-caps and the metal-bumps on the base, which is recognized by the numerical simulation. A remarkable average SERS enhancement factor of up to 1.5 × 108 and a SERS intensity relative standard deviation (RSD) of 10.5% are achieved by optimizing the nanogap size to sub-10 nm scale, leading to an excellent capability for Raman detection, which is represented by the clearly identified SERS signal of the Rhodamine 6G solution with a fairly low concentration of 1 nM.

20 Sep 09:31

Decoration of exfoliated black phosphorus with nickel nanoparticles and application in catalysis. (arXiv:1609.05010v3 [cond-mat.mes-hall] UPDATED)

by Maria Caporali, Manuel Serrano-Ruiz, Francesca Telesio, Stefan Heun, Giuseppe Nicotra, Corrado Spinella, Stefano Caporali, Maurizio Peruzzini

Nickel nanoparticles were dispersed on the surface of exfoliated black phosphorus and the resulting nanohybrid Ni/2DBP showed an improved stability respect to pristine 2D BP when kept in ambient conditions in the darkness. Ni/2DBP was applied as catalyst in the semihydrogenation of phenylacetylene and exhibited high conversion and selectivity towards styrene. These features were preserved after recycling tests revealing the high stability of the nanohybrid.

12 Aug 22:54

First-principles calculations of the superconducting properties in Li-decorated monolayer graphene within the anisotropic Migdal-Eliashberg formalism

by Jing-Jing Zheng and E. R. Margine

Author(s): Jing-Jing Zheng and E. R. Margine

The ab initio anisotropic Migdal-Eliashberg formalism has been used to examine the pairing mechanism and the nature of the superconducting gap in the recently discovered lithium-decorated monolayer graphene superconductor. Our results provide evidence that the superconducting transition in Li-decora…


[Phys. Rev. B 94, 064509] Published Fri Aug 12, 2016

11 May 09:13

Hall viscosity and electromagnetic response of electrons in graphene. (arXiv:1605.02782v2 [cond-mat.mes-hall] UPDATED)

by Mohammad Sherafati, Alessandro Principi, Giovanni Vignale

We derive an analytic expression for the geometric Hall viscosity of non-interacting electrons in a single graphene layer in the presence of a perpendicular magnetic field. We show that a recently-derived formula in [C. Hoyos and D. T. Son, Phys. Rev. Lett. {\bf 108}, 066805 (2012)], which connects the coefficient of $q^2$ in the wave vector expansion of the Hall conductivity $\sigma_{xy}(q)$ of the two-dimensional electron gas (2DEG) to the Hall viscosity and the orbital diamagnetic susceptibility of that system, continues to hold for graphene -- in spite of the lack of Galilean invariance -- with a suitable definition of the effective mass. We also show that, for a sufficiently large number of occupied Landau levels in the positive energy sector, the Hall conductivity of electrons in graphene reduces to that of a Galilean-invariant 2DEG with an effective mass given by $\hbar k_F/v_F$ (cyclotron mass). Even in the most demanding case, i.e. when the chemical potential falls between the zero-th and the first Landau level, the cyclotron mass formula gives results accurate to better than 1$\%$. The connection between the Hall conductivity and the viscosity provides a possible avenue to measure the Hall viscosity in graphene.

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09 Dec 12:41

RKKY interaction of magnetic impurities in Dirac and Weyl semimetals

by Hao-Ran Chang, Jianhui Zhou, Shi-Xiong Wang, Wen-Yu Shan, and Di Xiao

Author(s): Hao-Ran Chang, Jianhui Zhou, Shi-Xiong Wang, Wen-Yu Shan, and Di Xiao

We theoretically study the Ruderman-Kittel-Kasuya-Yosida (RKKY) interaction between magnetic impurities in both Dirac and Weyl semimetals (SMs). We find that the internode process, as well as the unique three-dimensional spin-momentum locking, has significant influences on the RKKY interaction, resu…


[Phys. Rev. B 92, 241103(R)] Published Thu Dec 03, 2015

13 Aug 22:02

Black Phosphorus Terahertz Photodetectors

by Leonardo Viti, Jin Hu, Dominique Coquillat, Wojciech Knap, Alessandro Tredicucci, Antonio Politano, Miriam Serena Vitiello
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The first room-temperature terahertz (THz)-frequency nanodetector exploiting a 10 nm thick flake of exfoliated crystalline black phosphorus as an active channel of a field-effect transistor, is devised. By engineering and embedding planar THz antennas for efficient light harvesting, the first technological demonstration of a phosphorus-based active THz device is described.

02 Aug 02:26

Scattering of electrically excited surface plasmon polaritons by gold nanoparticles studied by optical interferometry with a scanning tunneling microscope

by Tao Wang, Benoît Rogez, Geneviève Comtet, Eric Le Moal, Wafa Abidi, Hynd Remita, Gérald Dujardin, and Elizabeth Boer-Duchemin

Author(s): Tao Wang, Benoît Rogez, Geneviève Comtet, Eric Le Moal, Wafa Abidi, Hynd Remita, Gérald Dujardin, and Elizabeth Boer-Duchemin

We study the scattering of electrically excited surface plasmon polaritons (SPP) from individual nanostructures. The tunneling electrons from a scanning tunneling microscope (STM) are used to excite an out-going, circular SPP wave on a thin (50-nm) gold film on which isolated gold nanoparticles (NPs…


[Phys. Rev. B 92, 045438] Published Fri Jul 31, 2015

14 Jul 05:52

Hierarchy of gaps and magnetic minibands in graphene in the presence of the Abrikosov vortex lattice. (arXiv:1507.03115v1 [cond-mat.mes-hall])

by Xi Chen, Vladimir I. Fal'ko

We determine the structure of band and gaps in graphene encapsulated in hexagonal boron nitride and subjected to magnetic field of Abrikosov lattice of vortices in the underlying superconducting film. The spectrum features one non-dispersive magnetic miniband at zero energy, separated by the largest gaps in the miniband spectrum from a pair of minibands resembling slightly broadened first Landau levels in graphene, suggesting the persistence of $\nu = \pm 2$ quantum Hall effect states. Also, we identify occasional merging point of magnetic minibands which feature Dirac-type dispersion at the consecutive miniband edges.

21 Nov 14:05

Lecturer Position | University of Massachusetts Amherst

US - MA - Amherst, Lecturer PositionPhysics DepartmentUniversity of Massachusetts Amherst   The Physics Department of the University of Massachusetts Amherst invites applications for a Lecturer position to start
02 Apr 15:14

Spin-Orbit Interaction and Isotropic Electronic Transport in Graphene

by Mahmoud M. Asmar and Sergio E. Ulloa

Author(s): Mahmoud M. Asmar and Sergio E. Ulloa

Broken symmetries in graphene affect the massless nature of its charge carriers. We present an analysis of scattering by defects in graphene in the presence of spin-orbit interactions (SOIs). A characteristic constant ratio (≃2) of the transport to elastic times for massless electrons signals the an...

[Phys. Rev. Lett. 112, 136602] Published Tue Apr 01, 2014

03 Oct 15:41

Assistant Professor - Electrical Engineering Technology

CUNY - FACULTY VACANCY ANNOUNCEMENTThe Department of Electrical and Telecommunications Engineering Technology ofthe New York City College of Technology (C...
09 Aug 22:08

[Perspective] Applied Physics: Graphene for Terahertz Applications

by Philippe Tassin
The optoelectronic properties of graphene are being explored for possible use in plasmonics and metamaterials at terahertz frequencies.

Authors: Philippe Tassin, Thomas Koschny, Costas M. Soukoulis
16 Jul 13:15

Magneto-optical conductivity of graphene on polar substrates. (arXiv:1307.4008v1 [cond-mat.mes-hall])

by Benedikt Scharf, Vasili Perebeinos, Jaroslav Fabian, Igor Žutić

We theoretically study the effect of polar substrates on the magneto-optical conductivity of doped monolayer graphene, where we particularly focus on the role played by surface polar phonons (SPPs). Our calculations suggest that polaronic shifts of the intra- and interband absorption peaks can be significantly larger for substrates with strong electron-SPP coupling than those in graphene on non-polar substrates, where only intrinsic graphene optical phonons contribute. Electron-phonon scattering and phonon-assisted transitions are, moreover, found to result in a loss of spectral weight at the absorption peaks. The strength of these processes is strongly temperature-dependent and with increasing temperatures the magneto-optical conductivity becomes increasingly affected by polar substrates, most noticeably in polar substrates with small SPP energies such as HfO2. The inclusion of a Landau level-dependent scattering rate to account for Coulomb impurity scattering does not alter this qualitative picture, but can play an important role in determining the lineshape of the absorption peaks, especially at low temperatures, where impurity scattering dominates.