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02 Feb 03:20

Rapid and living polymerization of renewable methylene butyrolactones via borane/phosphine Lewis pairs

Polym. Chem., 2025, 16,4804-4811
DOI: 10.1039/D5PY00789E, Paper
Yun Bai, Lieqiang Liao, Shuang Liu, Yibao Li, Jianghua He, Yuetao Zhang
This study presents a highly effective organic Lewis pair system, combining tris(pentafluorophenyl)borane (B(C6F5)3) with the strong organophosphorus superbase P(NIiPr)Ph2, enabling rapid and living polymerization of renewable methylene butyrolactones.
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