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10 Oct 04:13

Synthesis of mesoporous zeolites in fluoride media with structure-directing multiammonium surfactants

Publication date: February 2017
Source:Microporous and Mesoporous Materials, Volume 239
Author(s): Changbum Jo, Woojin Park, Ryong Ryoo
Mesoporous zeolite beta in pure-silica form and its analogues, including aluminosilicate, stannosilicate, and titanosilicate, were synthesized at near-neutral pH in the presence of fluoride ion as a mineralizer and piperidinium-functionalized multiammonium surfactant as a zeolite structure-directing agent (SDA). During hydrothermal synthesis, the surfactant headgroup generated zeolite beta frameworks with a thickness of 9 nm while numerous surfactant molecules were self-organized to form a nanosponge-like mesostructure in a disordered manner. The mesopores generated after calcination to remove the surfactant were highly uniform and further tailored with diameters in the range of 3.2–4.5 nm according to the surfactant tail lengths. MFI zeolite was also synthesized with a nanosheet morphology using C16H33 N+(CH3)2 C6H12 N+(CH3)2 C6H13 as the SDA in fluoride media. The zeolite samples obtained in this manner exhibited remarkably enhanced thermal stability, Brønsted acid strength, and hydrophobic nature compared to those synthesized at a high pH using OH as the mineralizer due to the reduced defect sites, as confirmed by 29Si MAS NMR and FT-IR measurements. Due to these advantages, the mesoporous zeolite beta obtained in the fluoride media exhibited high catalytic activity in esterification of oleic acid with methanol.

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12 May 00:37

Selective Hydrogenation of Crotonaldehyde to Crotyl Alcohol over Metal Oxide Modified Ir Catalysts and Mechanistic Insight

by Masazumi Tamura, Kensuke Tokonami, Yoshinao Nakagawa and Keiichi Tomishige

TOC Graphic

ACS Catalysis
DOI: 10.1021/acscatal.6b00400
11 Dec 02:11

Deactivation in Homogeneous Transition Metal Catalysis: Causes, Avoidance, and Cure

by Robert H. Crabtree

TOC Graphic

Chemical Reviews
DOI: 10.1021/cr5004375