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How Robust are Semiconductor Nanorods? Investigating the Stability and Chemical Decomposition Pathways of Photoactive Nanocrystals
Low-Temperature Synthesis of n-Type WS2 Thin Films via H2S Plasma Sulfurization of WO3
Isothermal Cold Crystallization Kinetics Study of Sildenafil
High-Performance Electrocatalysis Using Metallic Cobalt Pyrite (CoS2) Micro- and Nanostructures
Hollow and Concave Nanoparticles via Preferential Oxidation of the Core in Colloidal Core/Shell Nanocrystals
Influence of Shell Thickness and Surface Passivation on PbS/CdS Core/Shell Colloidal Quantum Dot Solar Cells
Atomic Force Microscopy Characterization and Lithography of Cu-Ligated Mercaptoalkanoic Acid “Molecular Ruler” Multilayers
High-Performing Red-Light-Emitting Pyrotechnic Illuminants through the Use of Perchlorate-Free Materials
DJLThere's going to be fireworks
Abstract
The development of perchlorate-free M662 40 mm illuminating pyrotechnic compositions is described. On the bases of cost, performance, and sensitivity, potassium periodate was determined to be most effective potassium perchlorate replacement in the compositions tested. The optimal periodate-based composition exceeded the performance of the perchlorate-containing control, exhibited low sensitivity values to impact, friction, and electrostatic discharge, and had high thermal onset temperatures.
Illuminating experience: Potassium periodate proved itself as a viable alternate to potassium perchlorate in developing an environmentally conscious US Army 40 mm red-light-emitting illuminant (see figure). The optimal periodate-based formulation exhibited high performance and low sensitivity. Derivatives of this formulation may be of interest to the civilian fireworks community.
Effects of surface nanocrystallization on tribological properties of 316L stainless steel under MoDTC/ZDDP lubrications
Source:Tribology International, Volume 79
Author(s): Yanyan Wang , Wen Yue , Dingshun She , Zhiqiang Fu , Haipeng Huang , Jiajun Liu
In this paper, 316L stainless steel (316LSS) is treated by a ultrasonic cold forging technology (UCFT) which is one of the methods of surface nanocrystallization. The tribological properties of UCFT sample are investigated by a SRV tribometer under lubrications with MoDTC and ZDDP. The chemical analysis of tribofilms is performed using X-ray photoelectron spectroscopy (XPS). The results show that the UCFT sample exhibits the lowest coefficient of friction (0.066) under MoDTC lubrication and the lowest wear rate under ZDDP lubrication, indicating that surface nanocrystallization has synergistic effects on low friction and antiwear performances of both MoDTC and ZDDP. The obviously synergistic effects between UCFT steel and MoDTC/ZDDP may be attributed to the higher hardness and surface reactivity of the UCFT surface.
The effect of surface roughness characteristics on the elastic–plastic contact performance
Source:Tribology International, Volume 79
Author(s): Shengguang Zhang , Wenzhong Wang , Ziqiang Zhao
Rough surface elastic–plastic contact performance is investigated in this paper. First, a computer program is developed to generate rough surfaces with given parameters; Then, the elastic–plastic contact model is developed based on minimization of complementary energy and semi-analytical method; finally, contact analysis for rough surfaces are conducted. The results show that kurtosis and skewness have significant effects on the contact performance under light-medium load; for heavy load condition and small skewness, the contact characteristic parameters change slightly along with kurtosis. Comparing with elastic contact, the low contact pressure and large contact area are predicted in elastic–plastic contacts.
Bandgap-Graded Cu2Zn(Sn1–xGex)S4 Thin-Film Solar Cells Derived from Metal Chalcogenide Complex Ligand Capped Nanocrystals
Adaptation in Constitutional Dynamic Libraries and Networks, Switching between Orthogonal Metalloselection and Photoselection Processes
DJLTake a walk down memory Lehn
Electrical and optical characterization of atomically thin WS2
DOI: 10.1039/C3DT52353E, Communication
Atomically thin layers of materials which are just a few atoms in thickness present an attractive option for future electronic devices.
The content of this RSS Feed (c) The Royal Society of Chemistry
High-Throughput Synthesis of Single-Layer MoS2 Nanosheets as a Near-Infrared Photothermal-Triggered Drug Delivery for Effective Cancer Therapy
Hydrophilic, Bright CuInS2 Quantum Dots as Cd-Free Fluorescent Labels in Quantitative Immunoassay
Cavitation damage to potential sewer and drain pipe materials
DJLCATASTROPHIC FAIL OF THE SOIL STACK
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Source:Wear, Volume 317, Issues 1–2
Author(s): C.A. Fairfield
High-pressure water-jet testing of a range of polymeric and ceramic (clay and concrete) materials was carried out with a view to assessing their performance as potential materials for use in the manufacture of non-pressurised drain and sewer pipes. This work describes test equipment calibration, jetting resistance tests on 20 potential pipe materials, and post-processing of the eroded test samples. The relationships between spatial and temporal fluctuations observed in the water-jet formed the basis for the understanding of the cavitation erosion mechanisms giving rise to the observed damage rates. Mie scattering data provided evidence of droplet and cavity sizes in the cavitating jet upon which initial cavity radii for future Rayleigh–Plesset equation analysis could be based. Those candidate materials with the longest time until the onset of damage (in descending order) for the top five of the materials tested were concrete, clay, 30% (by volume (v/v)) glass-filled nylon, polysulphone, and polyetherimide. The candidate materials capable of resisting the greatest pressure without showing signs of damage for 30s (in descending order) were polyetheretherketone, clay, polyetherimide, polyphenylene sulphide, and polysulphone.
Exploiting Intrinsic Nanoparticle Toxicity: The Pros and Cons of Nanoparticle-Induced Autophagy in Biomedical Research
Multiple exciton generation in cluster-free alloy CdxHg1-xTe colloidal quantum dots synthesized in water
DOI: 10.1039/C4CP01465K, Paper
Efficient generation of infrared exciton pairs from single short wavelength photons with quantum yield 199% is observed in CdxHg1-xTe QDs.
The content of this RSS Feed (c) The Royal Society of Chemistry
Progress in flexible dye solar cell materials, processes and devices
DOI: 10.1039/C4TA00902A, Feature Article
The progress in the development of materials, processes, devices and industrialization of flexible dye solar cells is analyzed in this review.
The content of this RSS Feed (c) The Royal Society of Chemistry
Themed issue on flexible energy storage and conversion
DOI: 10.1039/C4TA90093F, Editorial
Guest editors Guozhen Shen, Shu-Hong Yu, Yongyao Xia, and Xiong Wen (David) Lou introduce this Journal of Materials Chemistry A themed issue on flexible energy storage and conversion.
The content of this RSS Feed (c) The Royal Society of Chemistry
Unzipping Carbon Nanotubes at High Impact
Asymmetric Growth of Bilayer Graphene on Copper Enclosures Using Low-Pressure Chemical Vapor Deposition
Effects of Surface Compositional and Structural Heterogeneity on Nanoparticle–Protein Interactions: Different Protein Configurations
DJLHow is striped nanoparticles still getting published
Comparative Study of Wear Behaviors of a Selected Titanium Alloy and AISI H13 Steel as a Function of Temperature and Load
High-Efficiency Perovskite Solar Cells Based on the Black Polymorph of HC(NH2)2PbI3
Perovskite solar cells with power conversion efficiencies exceeding 16% at AM 1.5G one sun illumination are developed using the black polymorph of formamidnium lead iodide, HC(NH2)2PbI3. Compared with CH3NH3PbI3, HC(NH2)2PbI3 extends its absoprtion to 840 nm and shows no phase transition between 296 and 423 K. Moreover, a solar cell based on HC(NH2)2PbI3 exhibits photostability and little I–V hysteresis.
Graphene oxide nanosheet: an emerging star material for novel separation membranes
DOI: 10.1039/C4TA02359E, Feature Article
Due to their unique physical and chemical properties, graphene oxide nanosheets represent an emerging star material for novel separation membranes.
The content of this RSS Feed (c) The Royal Society of Chemistry
Dynamic friction coefficient of two plastics against aluminum under impact loading
Source:Tribology International, Volume 79
Author(s): Yuliang Lin , Jingui Qin , Fangyun Lu , Rong Chen , Xiangyu Li
We present a new dynamic friction coefficient testing device modified from the conventional split Hopkinson pressure bar (SHPB). In the experiment, the normal pressure and friction force are applied to the tribo pair simultaneously via the wedge structure of the incident bar. The geometry of tribo pairs can be cylindrical or cuboid which can be as simple as the samples in SHPB experiments, and the time-resolved interfacial friction coefficient can be directly calculated without any assumptions or theoretical derivation. The interfacial friction between two plastics and aluminum was tested by the novel setup, the normal pressure and friction force histories were measured, and the time-resolved dynamic friction coefficient was obtained.
















