Shared posts

22 Oct 22:14

Self‐Assembly of MXene‐Surfactants at Liquid–Liquid Interfaces: From Structured Liquids to 3D Aerogels

by Shaowei Shi, Bingqing Qian, Xinyu Wu, Huilou Sun, Haiqiao Wang, Hao-Bin Zhang, Zhong-Zhen Yu, Thomas P. Russell
Angewandte Chemie International Edition Self‐Assembly of MXene‐Surfactants at Liquid–Liquid Interfaces: From Structured Liquids to 3D Aerogels

We're jammin’: The formation, assembly, and jamming of a new type MXene‐based Janus‐like nanoparticle surfactants, termed MXene‐surfactants (MXSs), is reported through the cooperative assembly of MXene and amine‐functionalized polyhedral oligomeric silsesquioxane at the oil–water interface. The MXSs can significantly enhance the interfacial activity of MXene nanosheets.


Abstract

2D transition metal carbides and nitrides (MXenes), a class of emerging nanomaterials with intriguing properties, have attracted significant attention in recent years. However, owing to the highly hydrophilic nature of MXene nanosheets, assembly strategies of MXene at liquid–liquid interfaces have been very limited and challenging. Herein, through the cooperative assembly of MXene and amine‐functionalized polyhedral oligomeric silsesquioxane at the oil–water interface, we report the formation, assembly, and jamming of a new type MXene‐based Janus‐like nanoparticle surfactants, termed MXene‐surfactants (MXSs), which can significantly enhance the interfacial activity of MXene nanosheets. More importantly, this simple assembly strategy opens a new platform for the fabrication of functional MXene assemblies from mesoscale (e.g., structured liquids) to macroscale (e.g., aerogels), that can be used for a range of applications, including nanocomposites, electronic devices, and all‐liquid microfluidic devices.

29 Sep 12:21

A fluid state of mind

by Christine-Maria Horejs

A fluid state of mind

A fluid state of mind, Published online: 24 September 2018; doi:10.1038/s41578-018-0055-2

A fluid state of mind
05 Jan 12:12

Nonvolatile Reconfigurable Phase-Change Metadevices for Beam Steering in the Near Infrared

by Carlota Ruiz de Galarreta, Arseny M. Alexeev, Yat-Yin Au, Martin Lopez-Garcia, Maciej Klemm, Martin Cryan, Jacopo Bertolotti, C. David Wright

Abstract

The development of flat, compact beam-steering devices with no bulky moving parts is opening up a new route to a variety of exciting applications, such as LIDAR scanning systems for autonomous vehicles, robotics and sensing, free-space, and even surface wave optical signal coupling. In this paper, the design, fabrication and characterization of innovative, nonvolatile, and reconfigurable beam-steering metadevices enabled by a combination of optical metasurfaces and chalcogenide phase-change materials is reported. The metadevices reflect an incident optical beam in a mirror-like fashion when the phase-change layer is in the crystalline state, but reflect anomalously at predesigned angles when the phase-change layer is switched into its amorphous state. Experimental angle-resolved spectrometry measurements verify that fabricated devices perform as designed, with high efficiencies, up to 40%, when operating at 1550 nm. Laser-induced crystallization and reamorphization experiments confirm reversible switching of the device. It is believed that reconfigurable phase-change-based beam-steering and beam-shaping metadevices, such as those reported here, can offer real applications advantages, such as high efficiency, compactness, fast switching times and, due to the nonvolatile nature of chalcogenide phase-change materials, low power consumption.

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Beam-steering devices with no moving parts are likely to find widespread applications in areas such as LIDAR scanning systems for autonomous vehicles, robotics and sensing, telecommunications, and optical signal coupling. Here, the design, fabrication and characterization of innovative, fast, nonvolatile, and reconfigurable beam-steering devices enabled by a combination of optical metasurfaces and chalcogenide phase-change materials is reported.

20 May 09:38

Lithium–sulfur batteries: Making the invisible visible

by com.springer.oscar.shared.search.Author@28cfdd00[name=Patrik Johansson,email=some(patrik.johansson@chalmers.se)]

Lithium–sulfur batteries: Making the invisible visible

Nature Energy, Published online: 8 May 2017; doi:10.1038/nenergy.2017.76

The presence of polysulfides in Li–S batteries significantly affects battery operation, but their presence and reaction mechanisms are not well understood. Now, an operando X-ray diffraction approach is used to directly observe these polysulfides, offering insights on their formation and evolution.

07 Jan 13:05

Facile Synthesis of a 3D Nanoarchitectured Li4Ti5O12 Electrode for Ultrafast Energy Storage

by Bote Zhao, Xiang Deng, Ran Ran, Meilin Liu, Zongping Shao

Despite enormous efforts devoted to the development of high-performance batteries, the obtainable energy and power density, durability, and affordability of the existing batteries are still inadequate for many applications. Here, a self-standing nanostructured electrode with ultrafast cycling capability is reported by in situ tailoring Li4Ti5O12 nanocrystals into a 3D carbon current collector (derived from filter paper) through a facile wet chemical process involving adsorption of titanium source, boiling treatment, and subsequent chemical lithiation. This 3D architectural electrode is charged/discharged to ≈60% of the theoretical capacity of Li4Ti5O12 in ≈21 s at 100 C rate (17 500 mA g−1 ), which also shows stable cycling performance for 1000 cycles at a cycling rate of 50 C. Additionally, modified 3D carbon current collector with much smaller pores and finer fiber diameters are further used, which significantly improve the specific capacity based on the weight of the entire electrode. These novel electrodes are promising for high-power applications such as electric vehicles and smart grids. This unique electrode architecture also simplifies the electrode fabrication process and significantly enhances current collection efficiency (especially at high rate). Further, the conceptual electrode design is applicable to other oxide electrode materials for high-performance batteries, fuel cells, and supercapacitors.

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A novel electrode architecture is designed and realized by in situ tailoring of Li4Ti5O12 nanocrystals into a 3D current collector (derived from filter paper) through a facile route. The electrode can be charged/discharged in 21 s (100 C) to ≈60% of its theoretical capacity and deliver an excellent cycling stability at 50 C.

21 May 04:43

Convenient Recycling of 3D AgX/Graphene Aerogels (X = Br, Cl) for Efficient Photocatalytic Degradation of Water Pollutants

by Yingying Fan, Weiguang Ma, Dongxue Han, Shiyu Gan, Xiandui Dong, Li Niu
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3D AgX/graphene aerogel (GA) composites (X = Br, Cl) are synthesized. Not only is the photocatalytic performance increased in comparison with pristine AgX, but also the photocatalytic cycling process is facilitated just using tweezers Thus, the comprehensive performance of the AgX/GA composites provides robust support for future industrial applications of the photocatalyst.

14 Mar 15:06

Tunable Optics: Ultrafast All-Polymer Electrically Tunable Silicone Lenses (Adv. Funct. Mater. 11/2015)

by Luc Maffli, Samuel Rosset, Michele Ghilardi, Federico Carpi, Herbert Shea
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On page 1656, S. Rosset, H. Shea, and colleagues present a soft, flexible, and deformable biomimetic lens based on dielectric elastomer actuators (a.k.a. artificial muscles) that is capable of electrically modulating its focal length by 20% in less than 200 microseconds.