Ellen Jamieson
Shared posts
Pd-Catalyzed Diastereoselective Trifluoromethylthiolation of Functionalized Acrylamides
Asymmetric Synthesis of 3,4-Disubstituted 2-(Trifluoromethyl)pyrrolidines through Rearrangement of Chiral 2-(2,2,2-Trifluoro-1-hydroxyethyl)azetidines
Ladder-type Heteroarenes: Up to 15 Rings with Five Imide Groups
Abstract
A series of novel imide-functionalized ladder-type heteroarenes with well-defined structure and controllable conjugation lengths were synthesized and characterized. The synthetic route shows remarkable efficacy for constructing the electron-deficient ladder backbones. π-Conjugation extension leads to narrowed band gaps with enhanced electron affinities. The ladder arenes are incorporated into organic thin-film transistors, and show encouraging electron mobilities of 0.013–0.045 cm2 V−1 s−1. The heteroarenes reported here provide a remarkable platform for fundamental physicochemical studies and materials innovation in organic electronics.
Climbing the ladder: A series of novel ladder-type heteroarenes with well-defined structures and precisely controllable conjugation lengths were synthesized with remarkable efficacy and characterized. Compared to most ladder-type arenes, these imide-functionalized building blocks are highly electron-deficient, and thus provide a remarkable platform for materials innovation in organic electronics.
New amidinate complexes of indium(III): promising CVD precursors for transparent and conductive In2O3 thin films
DOI: 10.1039/C7DT01280B, Paper
Heteroleptic and homoleptic In(III)-amidinate complexes as promising CVD precursors for In2O3 thin films.
The content of this RSS Feed (c) The Royal Society of Chemistry