Shared posts

21 May 15:47

[ASAP] Implanting Germanium into Graphene

by Mukesh Tripathi, Alexander Markevich, Roman Böttger, Stefan Facsko, Elena Besley, Jani Kotakoski, Toma Susi

TOC Graphic

ACS Nano
DOI: 10.1021/acsnano.8b01191
15 May 11:55

Competition of Dzyaloshinskii-Moriya and Higher-Order Exchange Interactions in $\mathrm{Rh}/\mathrm{Fe}$ Atomic Bilayers on Ir(111)

by Niklas Romming, Henning Pralow, André Kubetzka, Markus Hoffmann, Stephan von Malottki, Sebastian Meyer, Bertrand Dupé, Roland Wiesendanger, Kirsten von Bergmann, and Stefan Heinze

Author(s): Niklas Romming, Henning Pralow, André Kubetzka, Markus Hoffmann, Stephan von Malottki, Sebastian Meyer, Bertrand Dupé, Roland Wiesendanger, Kirsten von Bergmann, and Stefan Heinze

Using spin-polarized scanning tunneling microscopy and density functional theory we demonstrate the occurrence of a novel type of noncollinear spin structure in Rh/Fe atomic bilayers on Ir(111). We find that higher-order exchange interactions depend sensitively on the stacking sequence. For fcc-Rh/F...


[Phys. Rev. Lett. 120, 207201] Published Mon May 14, 2018

09 May 13:46

Electronic effects and fundamental physics studied in molecular interfaces

Chem. Commun., 2018, 54,5508-5517
DOI: 10.1039/C8CC02191K, Feature Article
Thomas Pope, Shixuan Du, Hong-Jun Gao, Werner A. Hofer
Scanning probe instruments in conjunction with a very low temperature environment have revolutionized the ability of building, functionalizing, and analysing two dimensional interfaces in the last twenty years.
The content of this RSS Feed (c) The Royal Society of Chemistry
20 Apr 10:52

Inducing skyrmions in ultrathin Fe films by hydrogen exposure

by Pin-Jui Hsu

Inducing skyrmions in ultrathin Fe films by hydrogen exposure

Inducing skyrmions in ultrathin Fe films by hydrogen exposure, Published online: 20 April 2018; doi:10.1038/s41467-018-04015-z

Stabilization of skyrmions is one of the key issues in skyrmion-based spintronics. Here the authors demonstrate that hydrogenation can induce the formation of skyrmions in iron thin films, which provides an alternative way to tailor skyrmion states in low-dimensional magnetic materials.
18 Apr 20:34

[ASAP] a-Diazo Ketones in On-Surface Chemistry

by Lacheng Liu, Henning Klaasen, Alexander Timmer, Hong-Ying Gao, Dennis Barton, Harry Mönig, Johannes Neugebauer, Harald Fuchs, Armido Studer

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Journal of the American Chemical Society
DOI: 10.1021/jacs.8b02599
18 Apr 19:09

Bromine adatom promoted C-H bond activation in terminal alkynes at room temperature on Ag(111)

Phys. Chem. Chem. Phys., 2018, 20,11081-11088
DOI: 10.1039/C7CP07972A, Paper
Jing Liu, Qiwei Chen, Qilin He, Yajie Zhang, Xiangyu Fu, Yongfeng Wang, Dahui Zhao, Wei Chen, Guo Qin Xu, Kai Wu
Room temperature C-H bond activation promoted by Br adatoms is achieved in the probe reaction of 2,5-diethynyl-1,4-bis(4-bromophenylethynyl)benzene on Ag(111).
The content of this RSS Feed (c) The Royal Society of Chemistry
18 Apr 19:08

Sulfur-driven switching of the Ullmann coupling on Au(111)

Chem. Commun., 2018, 54,3621-3624
DOI: 10.1039/C8CC01007B, Communication
Jonathan Rodriguez-Fernandez, Soren Birthin Schmidt, Jeppe V. Lauritsen
We demonstrate the inhibition and reactivation of the Ullmann coupling reaction by molecular gases.
The content of this RSS Feed (c) The Royal Society of Chemistry
18 Apr 10:21

[ASAP] Resolving the Controversial Existence of Silicene and Germanene Nanosheets Grown on Graphite

by Wenbing Peng, Tao Xu, Pascale Diener, Louis Biadala, Maxime Berthe, Xiaodong Pi, Yves Borensztein, Alberto Curcella, Romain Bernard, Geoffroy Prévot, Bruno Grandidier

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ACS Nano
DOI: 10.1021/acsnano.8b01467
16 Apr 13:59

[ASAP] On-Demand Final State Control of a Surface-Bound Bistable Single Molecule Switch

by José A. Garrido Torres, Grant J. Simpson, Christopher J. Adams, Herbert A. Früchtl, Renald Schaub

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Nano Letters
DOI: 10.1021/acs.nanolett.8b00336
11 Apr 11:37

2D magnetism gets hot

2D magnetism gets hot

2D magnetism gets hot, Published online: 10 April 2018; doi:10.1038/s41565-018-0128-9

The demonstration of room-temperature ferromagnetism in an atomically thin layer broadens the prospects for device applications of 2D van der Waals materials.
20 Mar 17:57

Structural transformation of h-BN overlayers on Pt(111) in oxidative atmospheres

Phys. Chem. Chem. Phys., 2018, 20,11013-11020
DOI: 10.1039/C8CP00877A, Paper
Caixia Meng, Yifan Li, Hao Wu, Wei Wei, Yanxiao Ning, Yi Cui, Qiang Fu, Xinhe Bao
Controlled structural transformation of h-BN overlayers on Pt(111) in oxidative atmospheres including oxygen intercalation, formation of boron oxide, and oxygen etching.
The content of this RSS Feed (c) The Royal Society of Chemistry
09 Mar 09:51

MIT launches multimillion-dollar collaboration to develop fusion energy

by Jeff Tollefson

MIT launches multimillion-dollar collaboration to develop fusion energy

MIT launches multimillion-dollar collaboration to develop fusion energy, Published online: 09 March 2018; doi:10.1038/d41586-018-02966-3

With corporate participation, researchers seek to build a pilot fusion energy plant within 15 years.
02 Mar 07:58

Analyzing the Wave Nature of Hot Electrons with a Molecular Nanoprobe

by Markus Leisegang, Jens Kügel, Lucas Klein and Matthias Bode

TOC Graphic

Nano Letters
DOI: 10.1021/acs.nanolett.8b00465
28 Feb 13:03

Synthesis of Alternating Donor–Acceptor Ladder-Type Molecules and Investigation of Their Multiple Charge-Transfer Pathways

by Zhengxu Cai, Na Zhang, Mohammad Awais, Alexander Filatov, Luping Yu

Abstract

We describe the synthesis as well as the optical and charge-transport properties of a series of donor–acceptor (D-A) ladder-type heteroacenes. These molecules are stable, soluble, and contain up to 24 fused rings. Structural analyses indicated that the backbones of S 10r and Se 10r are bent in single crystals. The three 10-ring heteroacenes were functionalized with thiol anchoring groups and used for single-molecular conductance measurements. The highest conductance was observed for molecular wires containing a benzoselenadiazole (BSD) moiety, which exhibits the narrowest band gap. Multiple charge-transport pathways were observed in molecular wires containing either benzothiadiazole (BTD) or BSD. The conductance is a complex function of both energy gap and orbital alignment.

Thumbnail image of graphical abstract

Ladders of opportunity: Stable, soluble donor–acceptor (D-A) ladder-type heteroacenes containing up to 24 fused rings were synthesized, and three 10-ring heteroacenes were functionalized with thiol anchoring groups for single-molecular conductance measurements (see picture). Multiple charge-transport pathways (higher and lower conductance, HG and LG) were observed in molecular wires containing a benzothiadiazole or benzoselenadiazole acceptor moiety.

28 Feb 10:05

Surface Adatom Mediated Structural Transformation in Bromoarene Monolayers: Precursor Phases in Surface Ullmann Reaction

by Qitang Fan, Liming Liu, Jingya Dai, Tao Wang, Huanxin Ju, Jin Zhao, Julian Kuttner, Gerhard Hilt, J. Michael Gottfried and Junfa Zhu

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ACS Nano
DOI: 10.1021/acsnano.7b06787
27 Feb 11:10

Interlocking Mechanism between Molecular Gears Attached to Surfaces

by Rundong Zhao, Yan-Ling Zhao, Fei Qi, Klaus E. Hermann, Rui-Qin Zhang and Michel A. Van Hove

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ACS Nano
DOI: 10.1021/acsnano.8b00784
27 Feb 09:48

Long Spin-Relaxation Times in a Transition-Metal Atom in Direct Contact to a Metal Substrate

by Jan Hermenau, Markus Ternes, Manuel Steinbrecher, Roland Wiesendanger and Jens Wiebe

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Nano Letters
DOI: 10.1021/acs.nanolett.7b05392
20 Feb 22:59

Heisenberg spin-$\frac{1}{2}$ XXZ chain in the presence of electric and magnetic fields

by Pradeep Thakur and P. Durganandini

Author(s): Pradeep Thakur and P. Durganandini

We study the interplay of electric and magnetic order in the one-dimensional Heisenberg spin-12 XXZ chain with large Ising anisotropy in the presence of the Dzyaloshinskii-Moriya (DM) interaction and with longitudinal and transverse magnetic fields, interpreting the DM interaction as a coupling betw...


[Phys. Rev. B 97, 064413] Published Tue Feb 20, 2018

12 Jan 20:52

Electron-assisted magnetization tunneling in single spin systems

by Timofey Balashov, Christian Karlewski, Tobias Märkl, Gerd Schön, and Wulf Wulfhekel

Author(s): Timofey Balashov, Christian Karlewski, Tobias Märkl, Gerd Schön, and Wulf Wulfhekel

Magnetic excitations of single atoms on surfaces have been widely studied experimentally in the past decade. Lately, systems with unprecedented magnetic stability started to emerge. Here, we present a general theoretical investigation of the stability of rare-earth magnetic atoms exposed to crystal ...


[Phys. Rev. B 97, 024412] Published Fri Jan 12, 2018

10 Jan 10:31

Persistent Charge-Density-Wave Order in Single-Layer TaSe2

by Hyejin Ryu, Yi Chen, Heejung Kim, Hsin-Zon Tsai, Shujie Tang, Juan Jiang, Franklin Liou, Salman Kahn, Caihong Jia, Arash A. Omrani, Ji Hoon Shim, Zahid Hussain, Zhi-Xun Shen, Kyoo Kim, Byung Il Min, Choongyu Hwang, Michael F. Crommie and Sung-Kwan Mo

TOC Graphic

Nano Letters
DOI: 10.1021/acs.nanolett.7b03264
08 Jan 12:43

Xanthine Quartets on Au(111)

by Chong Chen, Hongqian Sang, Pengcheng Ding, Ye Sun, Manuela Mura, Ying Hu, Lev N. Kantorovich, Flemming Besenbacher and Miao Yu

TOC Graphic

Journal of the American Chemical Society
DOI: 10.1021/jacs.7b10444
08 Jan 12:28

Spin-Crossover Iron(II) Coordination Polymer with Fluorescent Properties: Correlation between Emission Properties and Spin State

by Charles Lochenie, Konstantin Schötz, Fabian Panzer, Hannah Kurz, Bernadette Maier, Florian Puchtler, Seema Agarwal, Anna Köhler and Birgit Weber

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Journal of the American Chemical Society
DOI: 10.1021/jacs.7b10571
08 Jan 12:23

Electronic characterization of silicon intercalated chevron graphene nanoribbons on Au(111)

Chem. Commun., 2018, 54,1619-1622
DOI: 10.1039/C7CC08353J, Communication
O. Deniz, C. Sanchez-Sanchez, R. Jaafar, N. Kharche, L. Liang, V. Meunier, X. Feng, K. Mullen, R. Fasel, P. Ruffieux
The intrinsic electronic structure of chevron graphene nanoribbons are revealed through in situ silicon intercalation.
The content of this RSS Feed (c) The Royal Society of Chemistry
05 Jan 09:49

Orbitally Matched Edge-Doping in Graphene Nanoribbons

by Rebecca A. Durr, Danny Haberer, Yea-Lee Lee, Raymond Blackwell, Alin Miksi Kalayjian, Tomas Marangoni, Jisoon Ihm, Steven G. Louie and Felix R. Fischer

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Journal of the American Chemical Society
DOI: 10.1021/jacs.7b11886
05 Jan 09:48

Negative Differential Conductance in Polyporphyrin Oligomers with Nonlinear Backbones

by Guowen Kuang, Shi Zhang Chen, Linghao Yan, Ke Qiu Chen, Xuesong Shang, Pei Nian Liu and Nian Lin

TOC Graphic

Journal of the American Chemical Society
DOI: 10.1021/jacs.7b11016
28 Dec 11:33

Local Electronic Structure of a Single-Layer Porphyrin-Containing Covalent Organic Framework

by Chen Chen, Trinity Joshi, Huifang Li, Anton D. Chavez, Zahra Pedramrazi, Pei-Nian Liu, Hong Li, William R. Dichtel, Jean-Luc Bredas and Michael F. Crommie

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ACS Nano
DOI: 10.1021/acsnano.7b06529
21 Dec 11:16

Spin Control Induced by Molecular Charging in a Transport Junction

by Sujoy Karan, Carlos García, Michael Karolak, David Jacob, Nicolás Lorente and Richard Berndt

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Nano Letters
DOI: 10.1021/acs.nanolett.7b03411
21 Dec 11:16

On-Surface Route for Producing Planar Nanographenes with Azulene Moieties

by Jeremy Hieulle, Eduard Carbonell-Sanromà, Manuel Vilas-Varela, Aran Garcia-Lekue, Enrique Guitián, Diego Peña and Jose Ignacio Pascual

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Nano Letters
DOI: 10.1021/acs.nanolett.7b04309
12 Dec 12:32

Vibrational Changes Induced by Electron Transfer in Surface Bound Azurin Metalloprotein Studied by Tip-Enhanced Raman Spectroscopy and Scanning Tunneling Microscopy

by Stefan Kradolfer, Ewelina Lipiec, Chiara Baldacchini, Anna Rita Bizzarri, Salvatore Cannistraro and Renato Zenobi

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ACS Nano
DOI: 10.1021/acsnano.7b07768
11 Dec 09:26

Sm cluster superlattice on graphene/Ir(111)

by Dimitris Mousadakos, Marina Pivetta, Harald Brune and Stefano Rusponi
We report on the first example of a self-assembled rare earth cluster superlattice. As a template, we use the moiré pattern formed by graphene on Ir(111); its lattice constant of 2.52 nm defines the interparticle distance. The samarium cluster superlattice forms for substrate temperatures during deposition ranging from 80 to 110 K, and it is stable upon annealing to 140 K. By varying the samarium coverage, the mean cluster size can be increased up to 50 atoms, without affecting the long-range order. The spatial order and the width of the cluster size distribution match the best examples of metal cluster superlattices grown by atomic beam epitaxy on template surfaces.