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29 Aug 17:08

[ASAP] Two-Dimensional Band Structure in Honeycomb Metal–Organic Frameworks

by Avijit Kumar, Kaustuv Banerjee, Adam S. Foster, Peter Liljeroth

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Nano Letters
DOI: 10.1021/acs.nanolett.8b02062
22 Aug 17:13

[ASAP] Locally Induced Spin States on Graphene by Chemical Attachment of Boron Atoms

by Qing Li, Haiping Lin, Ruitao Lv, Mauricio Terrones, Lifeng Chi, Werner A. Hofer, Minghu Pan

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Nano Letters
DOI: 10.1021/acs.nanolett.8b01798
21 Aug 09:46

[ASAP] Tuning Band Gap and Work Function Modulations in Monolayer hBN/Cu(111) Heterostructures with Moiré Patterns

by Qiang Zhang, Jin Yu, Philipp Ebert, Chendong Zhang, Chi-Ruei Pan, Mei-Yin Chou, Chih-Kang Shih, Changgan Zeng, Shengjun Yuan

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ACS Nano
DOI: 10.1021/acsnano.8b04444
20 Aug 09:13

[ASAP] Edge State Engineering of Graphene Nanoribbons

by Xuelei Su, Zhijie Xue, Gang Li, Ping Yu

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Nano Letters
DOI: 10.1021/acs.nanolett.8b02356
17 Aug 11:55

Building a 22-ring nanographene by combining in-solution and on-surface syntheses

Chem. Commun., 2018, 54,10256-10259
DOI: 10.1039/C8CC05353G, Communication
Rafal Zuzak, Jesus Castro-Esteban, Pedro Brandimarte, Mads Engelund, Agustín Cobas, Piotr Piątkowski, Marek Kolmer, Dolores Pérez, Enrique Guitián, Marek Szymonski, Daniel Sánchez-Portal, Szymon Godlewski, Diego Peña
A nanographene formed by the fusion of 22 benzene rings has been prepared by combining in-solution cycloaddition reactions and on-surface cyclodehydrogenations.
The content of this RSS Feed (c) The Royal Society of Chemistry
16 Aug 10:50

Engineering the spin couplings in atomically crafted spin chains on an elemental superconductor

by A. Kamlapure

Engineering the spin couplings in atomically crafted spin chains on an elemental superconductor

Engineering the spin couplings in atomically crafted spin chains on an elemental superconductor, Published online: 14 August 2018; doi:10.1038/s41467-018-05701-8

Magnetic atomic chains assembled on the surface of superconductors are a potential platform for engineering topological superconducting phases. Here the authors step towards this by manipulating magnetic atoms at interstitial sites to tune interatomic interactions and control the Yu-Shiba-Rusinov states that form.
13 Aug 17:13

[ASAP] Diacetylene Linked Anthracene Oligomers Synthesized by One-Shot Homocoupling of Trimethylsilyl on Cu(111)

by Shigeki Kawai, Ondrej Krejcí, Adam S. Foster, Rémy Pawlak, Feng Xu, Lifen Peng, Akihiro Orita, Ernst Meyer

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ACS Nano
DOI: 10.1021/acsnano.8b05116
10 Aug 09:37

Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation

by Cornelius Krull

Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation

Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation, Published online: 10 August 2018; doi:10.1038/s41467-018-05543-4

Polynuclear metal-organic coordination complexes are often inaccessible by traditional synthetic chemistry methods. Here, the authors use on-surface supramolecular chemistry to form a planar trinuclear Fe complex, in which an accumulation of electrons around the positive mixed-valence polynuclear centre suggests a catalytically active core.
20 Jul 12:47

[ASAP] Observation of Gap Opening in 1T' Phase MoS2 Nanocrystals

by Hai Xu, Dong Han, Yang Bao, Fang Cheng, Zijing Ding, Sherman J. R. Tan, Kian Ping Loh

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Nano Letters
DOI: 10.1021/acs.nanolett.8b01953
12 Jul 08:57

[ASAP] Size-Selective Carbon Clusters as Obstacles to Graphene Growth on a Metal

by Alexandre Artaud, Laurence Magaud, Kitti Ratter, Bruno Gilles, Valérie Guisset, Philippe David, Jose Ignacio Martinez, Jose Angel Martin-Gago, Claude Chapelier, Johann Coraux

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Nano Letters
DOI: 10.1021/acs.nanolett.8b01379
10 Jul 14:42

Scanning tunneling microscopy investigations of unoccupied surface states in two-dimensional semiconducting β-√3 × √3-Bi/Si(111) surface

Phys. Chem. Chem. Phys., 2018, 20,20188-20193
DOI: 10.1039/C8CP01356J, Paper
Jian Gou, Long-Juan Kong, Wen-Bin Li, Shao-Xiang Sheng, Hui Li, Sheng Meng, Peng Cheng, Ke-Hui Wu, Lan Chen
The lowest unoccupied states with Rashba splitting of β-√3 × √3-Bi are proved to be contributed by surface bismuth atoms.
The content of this RSS Feed (c) The Royal Society of Chemistry
10 Jul 13:28

[ASAP] Molecular Beam Epitaxy of Highly Crystalline MoSe2 on Hexagonal Boron Nitride

by Sock Mui Poh, Xiaoxu Zhao, Sherman Jun Rong Tan, Deyi Fu, Wenwen Fei, Leiqiang Chu, Dan Jiadong, Wu Zhou, Stephen J. Pennycook, Antonio H. Castro Neto, Kian Ping Loh

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ACS Nano
DOI: 10.1021/acsnano.8b04037
04 Jul 11:12

[ASAP] Mapping the Conductance of Electronically Decoupled Graphene Nanoribbons

by Peter H. Jacobse, Mark J. J. Mangnus, Stephan J. M. Zevenhuizen, Ingmar Swart

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ACS Nano
DOI: 10.1021/acsnano.8b02770
03 Jul 17:42

[ASAP] A Monolayer of Hexagonal Boron Nitride on Ir(111) as a Template for Cluster Superlattices

by Moritz Will, Nicolae Atodiresei, Vasile Caciuc, Philipp Valerius, Charlotte Herbig, Thomas Michely

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ACS Nano
DOI: 10.1021/acsnano.8b02127
25 Jun 08:36

Inducing Kondo screening of vacancy magnetic moments in graphene with gating and local curvature

by Yuhang Jiang

Inducing Kondo screening of vacancy magnetic moments in graphene with gating and local curvature

Inducing Kondo screening of vacancy magnetic moments in graphene with gating and local curvature, Published online: 14 June 2018; doi:10.1038/s41467-018-04812-6

Observing and tuning the Kondo effect in graphene is experimentally challenging. Here, the authors identify the spectroscopic signature of Kondo screening in graphene, along with a quantum phase transition between screened and unscreened phases of vacancy magnetic moments.
25 Jun 08:30

Controlling the Self‐Metalation Rate of Tetraphenylporphyrins on Cu(111) via Cyano Functionalization

by Michael Lepper , Julia Köbl , Dr. Liang Zhang , Manuel Meusel , Helen Hölzel , Dr. Dominik Lungerich , Prof. Dr. Norbert Jux , Prof. Dr. Abner de Siervo , Prof. Dr. Bernd Meyer , Prof. Dr. Hans‐Peter Steinrück , Dr. Hubertus Marbach
Angewandte Chemie International Edition, EarlyView.
25 Jun 08:17

On‐Surface Bottom‐Up Synthesis of Azine Derivatives Displaying Strong Acceptor Behavior

by Nerea Ruiz del Árbol , Irene Palacio , Gonzalo Otero‐Irurueta , José I. Martínez , Pedro L. de Andrés , Oleksander Stetsovych , María Moro‐Lagares , Pingo Mutombo , Martin Svec , Pavel Jelínek , Albano Cossaro , Luca Floreano , Gary J. Ellis , María F. López , Prof. José A. Martín‐Gago
Angewandte Chemie International Edition, EarlyView.
20 Jun 13:59

[ASAP] Designing Optoelectronic Properties by On-Surface Synthesis: Formation and Electronic Structure of an Iron–Terpyridine Macromolecular Complex

by Agustin Schiffrin, Martina Capsoni, Gelareh Farahi, Chen-Guang Wang, Cornelius Krull, Marina Castelli, Tanya Roussy, Katherine A. Cochrane, Yuefeng Yin, Nikhil V. Medhekar, Michael Fuhrer, Adam Q. Shaw, Wei Ji, Sarah A. Burke

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ACS Nano
DOI: 10.1021/acsnano.8b01026
19 Jun 18:21

[ASAP] Remarkable Multichannel Conductance of Novel Single-Molecule Wires Built on Through-Space Conjugated Hexaphenylbenzene

by Shijie Zhen, Jin-Chuan Mao, Long Chen, Siyang Ding, Wenwen Luo, Xiao-Shun Zhou, Anjun Qin, Zujin Zhao, Ben Zhong Tang

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Nano Letters
DOI: 10.1021/acs.nanolett.8b01082
13 Jun 10:04

Magnetism of metallacrown single-molecule magnets: From a simplest model to realistic systems

by Y. Pavlyukh, E. Rentschler, H. J. Elmers, W. Hübner, and G. Lefkidis

Author(s): Y. Pavlyukh, E. Rentschler, H. J. Elmers, W. Hübner, and G. Lefkidis

Electronic and magnetic properties of molecular nanomagnets are determined by competing energy scales due to the crystal field splitting, the exchange interactions between transition metal atoms, and relativistic effects. We present a comprehensive theory embracing all these phenomena based on first...


[Phys. Rev. B 97, 214408] Published Fri Jun 08, 2018

13 Jun 10:02

[ASAP] Precise Monoselective Aromatic C–H Bond Activation by Chemisorption of Meta-Aryne on a Metal Surface

by Qitang Fan, Simon Werner, Jalmar Tschakert, Daniel Ebeling, André Schirmeisen, Gerhard Hilt, Wolfgang Hieringer, J. Michael Gottfried

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Journal of the American Chemical Society
DOI: 10.1021/jacs.8b01658
13 Jun 09:47

[ASAP] Fermi Level Manipulation through Native Doping in the Topological Insulator Bi2Se3

by Lee A. Walsh, Avery J. Green, Rafik Addou, Westly Nolting, Christopher R. Cormier, Adam T. Barton, Tyler R. Mowll, Ruoyu Yue, Ning Lu, Jiyoung Kim, Moon J. Kim, Vincent P. LaBella, Carl A. Ventrice , Jr., Stephen McDonnell, William G. Vandenberghe, Robert M. Wallace, Alain Diebold, Christopher L. Hinkle

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ACS Nano
DOI: 10.1021/acsnano.8b03414
04 Jun 12:36

Amplifier for scanning tunneling microscopy at MHz frequencies. (arXiv:1806.00374v1 [physics.app-ph])

by K.M. Bastiaans, T. Benschop, D. Chatzopoulos, D.H. Cho, Q. Dong, Y. Jin, M.P. Allan

Conventional scanning tunneling microscopy (STM) is limited to a bandwidth of circa 1kHz around DC. Here, we develop, build and test a novel amplifier circuit capable of measuring the tunneling current in the MHz regime while simultaneously performing conventional STM measurements. This is achieved with an amplifier circuit including a LC tank with a quality factor exceeding 600 and a home-built, low-noise high electron mobility transistor (HEMT). The amplifier circuit functions while simultaneously scanning with atomic resolution in the tunneling regime, i.e. at junction resistances in the range of giga-ohms, and down towards point contact spectroscopy. To enable high signal-to-noise and meet all technical requirements for the inclusion in a commercial low temperature, ultra-high vacuum STM, we use superconducting cross-wound inductors and choose materials and circuit elements with low heat load. We demonstrate the high performance of the amplifier by spatially mapping the Poissonian noise of tunneling electrons on an atomically clean Au(111) surface. We also show differential conductance spectroscopy measurements at 3MHz, demonstrating superior performance over conventional spectroscopy techniques. Further, our technology could be used to perform impedance matched spin resonance and distinguish Majorana modes from more conventional edge states.

30 May 10:18

Single-molecule magnet properties of a monometallic dysprosium pentalene complex

Chem. Commun., 2018, 54,7085-7088
DOI: 10.1039/C8CC03516D, Communication
Alexander F. R. Kilpatrick, Fu-Sheng Guo, Benjamin M. Day, Akseli Mansikkamaki, Richard A. Layfield, F. Geoffrey N. Cloke
The pentalene-ligated dysprosium complex [([small eta]8-Pn[dagger])Dy(Cp*)] (1Dy) (Pn[dagger] = [1,4-(iPr3Si)2C8H4]2-) and its magnetically dilute analogue are single-molecule magnets, with energy barriers of 245 cm-1.
The content of this RSS Feed (c) The Royal Society of Chemistry
28 May 17:23

Magnetotransport Properties of Graphene Nanoribbons with Zigzag Edges

by Shuang Wu, Bing Liu, Cheng Shen, Si Li, Xiaochun Huang, Xiaobo Lu, Peng Chen, Guole Wang, Duoming Wang, Mengzhou Liao, Jing Zhang, Tingting Zhang, Shuopei Wang, Wei Yang, Rong Yang, Dongxia Shi, Kenji Watanabe, Takashi Taniguchi, Yugui Yao, Weihua Wang, and Guangyu Zhang

Author(s): Shuang Wu, Bing Liu, Cheng Shen, Si Li, Xiaochun Huang, Xiaobo Lu, Peng Chen, Guole Wang, Duoming Wang, Mengzhou Liao, Jing Zhang, Tingting Zhang, Shuopei Wang, Wei Yang, Rong Yang, Dongxia Shi, Kenji Watanabe, Takashi Taniguchi, Yugui Yao, Weihua Wang, and Guangyu Zhang

The determination of the electronic structure by edge geometry is unique to graphene. In theory, an evanescent nonchiral edge state is predicted at the zigzag edges of graphene. Up to now, the approach used to study zigzag-edged graphene has mostly been limited to scanning tunneling microscopy. The ...


[Phys. Rev. Lett. 120, 216601] Published Tue May 22, 2018

28 May 12:53

[ASAP] Autonomous Scanning Probe Microscopy in Situ Tip Conditioning through Machine Learning

by Mohammad Rashidi, Robert A. Wolkow

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ACS Nano
DOI: 10.1021/acsnano.8b02208
21 May 15:10

Electron and Cooper-pair transport across a single magnetic molecule explored with a scanning tunneling microscope

by J. Brand, S. Gozdzik, N. Néel, J. L. Lado, J. Fernández-Rossier, and J. Kröger

Author(s): J. Brand, S. Gozdzik, N. Néel, J. L. Lado, J. Fernández-Rossier, and J. Kröger

The interplay of magnetism and superconductivity gives rise to the emergence of various interesting phenomena in condensed matter physics, such as the Yu-Shiba-Rusinov in-gap modes created by local magnetic moments in superconducting hosts. Using normal-metal and superconducting tips the authors have formed contacts to an individual magnetic molecule adsorbed on a conventional superconductor. Spectroscopy of the differential conductance with tunable junction transparency has unveiled the crossover from quasiparticle tunneling, which probes the Bardeen-Cooper-Schrieffer energy gap as well as the Yu-Shiba-Rusinov levels, to the contact range where multiple Andreev reflection takes over.


[Phys. Rev. B 97, 195429] Published Thu May 17, 2018

21 May 15:05

NextGen postdocs

by Costello, T. J.
21 May 14:59

[ASAP] Wearable Contact Lens Biosensors for Continuous Glucose Monitoring Using Smartphones

by Mohamed Elsherif, Mohammed Umair Hassan, Ali K. Yetisen, Haider Butt

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ACS Nano
DOI: 10.1021/acsnano.8b00829
21 May 01:12

[ASAP] Monolayer Molybdenum Disulfide Transistors with Single-Atom-Thick Gates

by Yibo Zhu, Yijun Li, Ghidewon Arefe, Robert A. Burke, Cheng Tan, Yufeng Hao, Xiaochi Liu, Xue Liu, Won Jong Yoo, Madan Dubey, Qiao Lin, James C. Hone

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Nano Letters
DOI: 10.1021/acs.nanolett.8b01091