Chem

Inorg. Chem. Front., 2016, 3,78-85
DOI: 10.1039/C5QI00159E, Research Article

Ru-Xin Yao, Xiao-Hui Qiao, Xin Cui, Xiao-Xia Jia, Xian-Ming Zhang
Two magnetic MOFs with a pcu net, constructed by using hexagonal Co₆ rings and zigzag Co₄ clusters, respectively are reported. Furthermore, activated 1 exhibits an excellent catalytic selectivity in the allylic oxidation reaction of cyclohexene to form an [small alpha],[small beta]-unsaturated ketone.
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Chem. Commun., 2015, 51,17630-17630
DOI: 10.1039/C5CC90535D, Correction

Open Access

&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Anthony J. Fitzpatrick, Elzbieta Trzop, Helge Müller-Bunz, Marinela M. Dîrtu, Yann Garcia, Eric Collet, Grace G. Morgan
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Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C5SC03111G, Edge Article

Open Access

&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Matthew Gregson, Nicholas F Chilton, Ana-Maria Ariciu, Floriana Tuna, Iain Crowe, William Lewis, Alexander J. Blake, David Collison, Eric J L McInnes, R E P Winpenny, Stephen Liddle
We report a dysprosium(III) bis(methanediide) single molecule magnet (SMM) where stabilisation of the highly magnetic states and suppression of mixing of opposite magnetic projections is imposed by a linear arrangement...
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Chem. Commun., 2016, Advance Article
DOI: 10.1039/C5CC07025B, Communication

Yi-Fei Deng, Tian Han, Zhenxing Wang, Zhongwen Ouyang, Bing Yin, Zhiping Zheng, J. Krzystek, Yan-Zhen Zheng
Two chromium(II) complexes exhibit single-molecule-magnet behavior due to uniaxial magnetic anisotropy revealed by magnetic and HF-EPR studies.
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DOI: 10.1021/acs.inorgchem.5b01673

DOI: 10.1021/acs.inorgchem.5b02324

DOI: 10.1021/acs.inorgchem.5b01624

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT03712C, Paper

Denis Gentili, Fabiola Liscio, Nicola Demitri, Bernhard Schafer, Francesco Borgatti, Piero Torelli, Benoit Gobaut, Giancarlo Panaccione, Giorgio Rossi, Alessandra Degli Esposti, Massimo Gazzano, Silvia Milita, Ilaria Bergenti, Giampiero Ruani, Ivan Salitros, Mario Ruben, Massimiliano Cavallini
We investigated the influence of surfaces in the formation of different crystal structures (polymorphs) of a room temperature switchable spin crossover compound.
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Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT03141A, Paper

Oliver Clemens, Jochen Rohrer, Gwilherm Nenert
The magnetic structures of the low-temperature phase of Mn₃(VO₄)₂ are solved and discussed in this article.
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Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT03909F, Paper

Sihuai Chen, Valeriu Mereacre, Christopher E. Anson, Annie K. Powell
Under ambient and solvothermal conditions four new compounds [Fe^III₄Ln^III₂([small mu ]₃-OH)₂(mdea)₄(m-NO₂C₆H₄COO)₈][middle dot]3MeCN and [Fe^III₆Ln^III₃([small mu ]₄-O)₃([small mu ]₃-O)(mdea)₅(m-NO₂C₆H₄COO)₉][middle dot]3MeCN (Ln = Y and Dy) have been synthesised and their magnetic properties investigated.
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Dalton Trans., 2015, 44,20883-20888
DOI: 10.1039/C5DT03683F, Paper

I. Yu. Barskaya, S. L. Veber, S. V. Fokin, E. V. Tretyakov, E. G. Bagryanskaya, V. I. Ovcharenko, M. V. Fedin
Although thermally- and light-induced structures of molecular magnets Cu(hfac)₂L^R are principally similar, FTIR reveals differences in packing of peripheral groups.
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Dalton Trans., 2015, 44,20964-20971
DOI: 10.1039/C5DT03130C, Paper

Lei Sun, Hui Chen, Chengbing Ma, Changneng Chen
Dodenuclear Mn/Ln clusters with 2-(hydroxymethyl)pyridine as a ligand have been synthesized. Complexes 1 and 5 showed a frequency-dependent decrease in [small chi][prime or minute]_MT and an out-of-phase [small chi][prime or minute][prime or minute]_M peak maximum, indicating slow magnetic relaxation and potential SMM behaviour.
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Dalton Trans., 2015, 44,21025-21031
DOI: 10.1039/C5DT03607K, Paper

Hongshan Ke, Sheng Zhang, Xin Li, Qing Wei, Gang Xie, Wenyuan Wang, Sanping Chen
A Dy₂ single-molecule magnet, namely [Dy₂(H₃L)₂(PhCOO)₄][middle dot]4H₂O (1), was obtained from the reaction of Dy(PhCOO)₃ with 1,5-bis(2-hydroxy-3-methoxybenzylidene)carbonohydrazide (H₄L).
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Dalton Trans., 2015, 44,20316-20320
DOI: 10.1039/C5DT03931B, Communication

Xiao-Lei Li, Han Li, Di-Ming Chen, Chao Wang, Jianfeng Wu, Jinkui Tang, Wei Shi, Peng Cheng
Coupling Dy₃ triangles results in two unique Dy₆ complexes showing single-molecule magnetic behaviour with high energy barriers of 116 and 181 K for Dy₆-NO₃ and Dy₆-SCN, respectively.
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Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT03790E, Paper

Hong-Ling Gao, Li Jiang, Shuang Liu, Hai-Yun Shen, Wen-Min Wang, Jian-Zhong Cui
A multi-relaxation single-molecule magnet (SMM) of a {Dy₄} complex exhibits two distinct relaxation processes, with a high energy barrier of 121 K.
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Dalton Trans., 2015, 44,20321-20325
DOI: 10.1039/C5DT04072H, Communication

Rebecca J. Holmberg, Le Tuan Anh Ho, Liviu Ungur, Ilia Korobkov, Liviu F. Chibotaru, Muralee Murugesu
A Gadolinium EDTA chelate displays characteristic isotropic behaviour common of Gd^III complexes under zero applied magnetic field, and anisotropic behaviour arising from dipolar coupling and weak spin-phonon coupling under an applied magnetic field.
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Dalton Trans., 2015, 44,21099-21108
DOI: 10.1039/C5DT03518J, Paper

Z. Kozakova, I. Kuritka, N. E. Kazantseva, V. Babayan, M. Pastorek, M. Machovsky, P. Bazant, P. Saha
Iron oxide nanoparticles were prepared by MW assisted solvothermal synthesis. A reaction mechanism was elucidated that allowed us to tailor the properties of particles.
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Dalton Trans., 2015, 44,20834-20838
DOI: 10.1039/C5DT04147C, Communication

Xing-Cai Huang, Ming Zhang, Dayu Wu, Dong Shao, Xin-Hua Zhao, Wei Huang, Xin-Yi Wang
Two one-dimensional coordination polymers with pentagonal bipyramidal Dy^III centres show slow magnetic relaxation featuring single molecule magnet behavior.
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Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT03946K, Paper

Antonio J. Calahorro, Itziar Oyarzabal, Belen Fernandez, Jose M. Seco, Tian Tian, David Fairen-Jimenez, Enrique Colacio, Antonio Rodriguez-Dieguez
We report lanthanide-based MOFs with interesting magnetic behaviours. To the best of our knowledge, Nd³⁺ and Yb³⁺ materials are the first examples of 3D- and 2D-MOFs, respectively, that show slow relaxation of magnetization.
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Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03800F, Paper

Min Ren, Zhong-Li Xu, Ting-Ting Wang, Song-Song Bao, Ze-Hua Zheng, Zai-Chao Zhang, Li-Min Zheng
A pair of enantiopure mononuclear dysprosium/salen-type complexes (Et3NH)[Dy((R,R)/(S,S)-3-NO2salcy)2] (1R/1S), where 3-NO2salcyH2 represent N,N'-(1,2-cyclohexanediylethylene)bis(3-nitrosalicylideneiminato), are reported. The enantiomer contains two crystallographically independent dysprosium(III) ions, each chelated by two enantiopure 3-NO2salcy2- ligands...
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Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02444G, Communication

Zhi Chen, Ming Fang, Yin-Ling Hou, Bin Zhao
A dinuclear Dy(III) compound (1) was structrually and magnetically characterized, displaying a single-molecule magnet (SMM) behavior with relaxation energy barrier of 21(1) K. Interestingly, by only adding a suitable substituent...
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Dalton Trans., 2015, 44,20839-20842
DOI: 10.1039/C5DT04264J, Communication

Anthony J. Fitzpatrick, Helen M. O'Connor, Grace G. Morgan
Two new paramagnetic ionic liquids (ILs) comprising a mononuclear iron(III) or manganese(III) complex cation, charge balanced by a dicyanamide anion are reported which show a range of spin states including spin crossover.
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Chem. Commun., 2016, 52,815-818
DOI: 10.1039/C5CC08215C, Communication

Hiroaki Hagiwara, Shohei Okada
[Fe^IIL^Me(NCS)₂] crystallizes in two solvent-free polymorphs and shows hysteretic spin crossover with polymorphism-dependent T_1/2 shift of 100 K spanning room temperature.
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Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC07629C, Communication

Nathan Yutronkie, Irina Kuehne, Ilia Korobkov, Jaclyn L Brusso, Muralee Murugesu
A dinuclear dysprosium complex, exhibiting SMM behaviour, and its yttrium analogue were prepared via in situ oxidation of Py2TTA, a pincer type ligand, followed by dimerisation. This unique metal complexation...
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Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC08215C, Communication

Hiroaki Hagiwara, Shohei Okada
A neutral mononuclear iron(II) complex with 1,2,3-triazole containing tetradentate ligand has been obtained as two solvent-free polymorphs. Both polymorphs show hysteretic spin crossover with polymorphism-dependent T_1/2 shift of 100 K...
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Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC07397A, Communication

Mamon Dey, Snigdha Dutta, Bipul Sarma, Ramesh Deka, Nayanmoni Gogoi
The possibility to control magnetic anisotropy by tuning contribution of second order perturbation to spin-orbit coupling through modulation of coordination environment is investigated. Subtle variation of the coordination environment triggers...
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Chem. Commun., 2015, 51,17688-17691
DOI: 10.1039/C5CC07025B, Communication

Yi-Fei Deng, Tian Han, Zhenxing Wang, Zhongwen Ouyang, Bing Yin, Zhiping Zheng, J. Krzystek, Yan-Zhen Zheng
Two chromium(II) complexes exhibit single-molecule-magnet behavior due to uniaxial magnetic anisotropy revealed by magnetic and HF-EPR studies.
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Chem. Commun., 2016, 52,677-680
DOI: 10.1039/C5CC07629C, Communication

Open Access

&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Nathan J. Yutronkie, Irina A. Kuhne, Ilia Korobkov, Jaclyn L. Brusso, Muralee Murugesu
A Dy₂ complex, exhibiting SMM behaviour, and its Y analogue were prepared via in situ oxidation of Py₂TTA, a pincer type ligand, followed by dimerisation.
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Chem. Commun., 2016, 52,753-756
DOI: 10.1039/C5CC07397A, Communication

Mamon Dey, Snigdha Dutta, Bipul Sarma, Ramesh Ch. Deka, Nayanmoni Gogoi
Subtle modulation of the coordination environment in seven coordinate Co(II) complexes leads to a remarkable deviation in the axial zero field splitting parameter (D) in a predictable fashion.
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