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10 Jan 14:20

In Situ Self‐Assembly of Bispecific Peptide for Cancer Immunotherapy

by Man-Di Wang, Gan-Tian Lv, Hong-Wei An, Ni-Yuan Zhang, Hao Wang
In Situ Self-Assembly of Bispecific Peptide for Cancer Immunotherapy

The construction of a bispecific T-cell engager (BiTE)-like molecule is proposed. The peptide consists of dual CD3 and integrin αvβ3 targeting sequence, conjugated by a self-assembling peptide. The molecule is designed to target the CD3 receptor on T cells and induce T cell-mediated cytolysis against tumor cells overexpressing integrin αvβ3.


Abstract

Precise and effective manipulation of protein functions still faces tremendous challenges. Herein we report a programmable peptide molecule, consisted of targeting and self-assembly modules, that enables specific and highly efficient assembly governed by targeting receptor proteins. Upon binding to the cell membrane receptor, peptide conformation is somewhat stabilized along with decreased self-assembly activation energy, promoting peptide-protein complex oligomerization. We first design a GNNQQNY-RGD peptide (G7-RGD) to recognize integrin αVβ3 receptor for proof-of-concept study. In the presence of αVβ3 protein, the critical assembly concentration of free G7-RGD decreases from 525 to 33 μM and the resultant G7-RGD cluster drives integrin receptor oligomerization. Finally, a bispecific assembling peptide antiCD3-G7-RGD is rationally designed for cancer immunotherapy, which validates CD3 oligomerization and concomitant T cell activation, leading to T cell-mediated cancer cell cytolysis.

14 Sep 14:02

Dihydrogen Activation by Lithium‐ and Sodium‐Aluminyls

by Matthew J. Evans, Mathew D. Anker, Claire L. McMullin, Sam E. Neale, Martyn P. Coles
Dihydrogen Activation by Lithium- and Sodium-Aluminyls

It turns out there is nothing special about potassium after all: Sodium and lithium metal reduce AlIII iodide precursors to the M 2[Al(NONDipp)]2 aluminyls (M=Li, Na). Addition of Et2O afforded the monomeric ion pairs (NONDipp)Al-M(Et2O)2 containing unsupported Al−Li and Al−Na bonds. All species activate dihydrogen, albeit at significantly different rates of reaction.


Abstract

To date, aluminyl anions have been exclusively isolated as their potassium salts. We report herein the synthesis of the lithium and sodium aluminyls, M 2[Al(NONDipp)]2 (M=Li, Na. NONDipp=[O(SiMe2NDipp)2]2−; Dipp=2,6-iPr2C6H3). Both compounds crystallize from non-coordinating solvent as “slipped” contacted dimeric pairs with strong M⋅⋅⋅π(aryl) interactions. Isolation from Et2O solution affords the monomeric ion pairs (NONDipp)Al-M(Et2O)2, which contain discrete Al−Li and Al−Na bonds. The ability of the full series of Li, Na and K aluminyls to activate dihydrogen is reported.

09 Oct 14:43

Oxoiron(V) mediated selective electrochemical oxygenation of unactivated C–H and CC bonds using water as the oxygen source

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC03616A, Edge Article
Open Access Open Access
Bittu Chandra, Hellan K. M., Santanu Pattanayak, Sayam Sen Gupta
A biomimetic iron complex-mediated selective and efficient electrochemical oxygenation of unactivated C–H bonds and CC bonds using water as an O-atom source.
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