Shared posts

17 Dec 14:58

Control of Anion Binding in Metal–Organic Helicates via Allosteric Regulation

by Ya-Liang Lai, Xue-Zhi Wang, Ye-Ting Wang, Hu Yang, Xian-Chao Zhou, Hao-Jie Zhang, Chuang-Wei Zhou, Dong Luo, Xiao-Ping Zhou & Dan Li1College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Supramolecular Coordination Chemistry, Jinan University, Guangzhou, Guangdong 5106322Department of Ultrasound, Institute of Ultrasound in Musculoskeletal Sports Medicine, The Affiliated Guangdong Second Provincial General Hospital, Jinan University, Guangzhou, Guangdong 510317
CCS Chemistry, Ahead of Print.
Mimicking allosteric regulation in artificial systems could enable the development of highly responsive and adaptive materials and devices. Herein, we described a strategy for controlling the architecture of metal–organic helicates using K+ions as ...
31 May 01:20

Convergent and divergent synthesis of dihydroisoquinoline-1,4-diones enabled by a photocatalytic skeleton-editing [4 + 2] strategy

Chem. Sci., 2025, 16,11833-11840
DOI: 10.1039/D5SC00665A, Edge Article
Open Access Open Access
Hai-Wu Du, Jun-Song Jia, Xiao-Yi Chen, Zhang-Yin Yuan, Jia-Ni Lin, Yu-Long Li, Qiong Yu, Wei Shu
An unprecedented photocatalytic [4 + 2] skeleton-editing strategy enabled direct synthesis of dihydroisoquinoline-1,4-diones from vinyl azides and carboxylic NHPI esters has been developed.
The content of this RSS Feed (c) The Royal Society of Chemistry
22 Feb 01:27

Cerebellar output neurons can impair non-motor behaviors by altering development of extracerebellar connectivity

by Andrew S. Lee

Nature Communications, Published online: 21 February 2025; doi:10.1038/s41467-025-57080-6

The capacity of the brain to compensate for insults during development depends on the type of cell loss. Here authors reveal that embryonic ablation of cerebellar output neurons leads to powerful compensation by extra-cerebellar circuits, whereas mutations (En1/2) disrupt extra-cerebellar circuits regulating non-motor behaviors.
16 Dec 02:17

Cucurbituril-based supramolecular host–guest complexes: single-crystal structures and dual-state fluorescence enhancement

Chem. Sci., 2024, 15,458-465
DOI: 10.1039/D3SC04813F, Edge Article
Open Access Open Access
Hui Wang, Hui Liu, Mingsen Wang, Jiaheng Hou, Yongjun Li, Yuancheng Wang, Yingjie Zhao
Two supramolecular complexes were prepared using cucurbiturils [CBs] as mediators and a four-armed p-xylene derivative (M1) as a guest molecule.
The content of this RSS Feed (c) The Royal Society of Chemistry