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14 Feb 06:52

Postsynthesis Mn-doping in CsPbI3 nanocrystals to stabilize the black perovskite phase

Nanoscale, 2019, 11,4278-4286
DOI: 10.1039/C9NR00248K, Paper
Wasim J. Mir, Abhishek Swarnkar, Angshuman Nag
Postsynthesis Mn-doping elucidates the role of lattice contraction and surface passivation in stabilizing the black phase of CsPbI3 nanocrystals under ambient conditions.
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14 Nov 00:05

An Ambipolar Superconducting Field‐Effect Transistor Operating above Liquid Helium Temperature

by Genta Kawaguchi, Andrey A. Bardin, Masayuki Suda, Mikio Uruichi, Hiroshi M. Yamamoto
Advanced Materials An Ambipolar Superconducting Field‐Effect Transistor Operating above Liquid Helium Temperature

An ambipolar superconducting field‐effect transistor is developed using a strongly correlated molecular system laminated on a SiO2/Si substrate. The low‐temperature electronic state is fine tuned in the vicinity of the superconductor‐to‐Mott‐insulator transition, utilizing the negative pressure effect from the substrate, which allows a small dose of hole or electron injection by the SiO2 dielectric to control the superconductivity above 4.2 K.


Abstract

Superconducting (SC) devices are attracting renewed attention as the demands for quantum‐information processing, meteorology, and sensing become advanced. The SC field‐effect transistor (FET) is one of the elements that can control the SC state, but its variety is still limited. Superconductors at the strong‐coupling limit tend to require a higher carrier density when the critical temperature (T C) becomes higher. Therefore, field‐effect control of superconductivity by a solid gate dielectric has been limited only to low temperatures. However, recent efforts have resulted in achieving n‐type and p‐type SC FETs based on organic superconductors whose T C exceed liquid He temperature (4.2 K). Here, a novel “ambipolar” SC FET operating at normally OFF mode with T C of around 6 K is reported. Although this is the second example of an SC FET with such an operation mode, the operation temperature exceeds that of the first example, or magic‐angle twisted‐bilayer graphene that operates at around 1 K. Because the superconductivity in this SC FET is of unconventional type, the performance of the present device will contribute not only to fabricating SC circuits, but also to elucidating phase transitions of strongly correlated electron systems.