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31 Jan 11:40

One-dimensional van der Waals heterostructures

by Xiang, R., Inoue, T., Zheng, Y., Kumamoto, A., Qian, Y., Sato, Y., Liu, M., Tang, D., Gokhale, D., Guo, J., Hisama, K., Yotsumoto, S., Ogamoto, T., Arai, H., Kobayashi, Y., Zhang, H., Hou, B., Anisimov, A., Maruyama, M., Miyata, Y., Okada, S., Chiashi, S., Li, Y., Kong, J., Kauppinen, E. I., Ikuhara, Y., Suenaga, K., Maruyama, S.

We present the experimental synthesis of one-dimensional (1D) van der Waals heterostructures, a class of materials where different atomic layers are coaxially stacked. We demonstrate the growth of single-crystal layers of hexagonal boron nitride (BN) and molybdenum disulfide (MoS2) crystals on single-walled carbon nanotubes (SWCNTs). For the latter, larger-diameter nanotubes that overcome strain effect were more readily synthesized. We also report a 5-nanometer–diameter heterostructure consisting of an inner SWCNT, a middle three-layer BN nanotube, and an outer MoS2 nanotube. Electron diffraction verifies that all shells in the heterostructures are single crystals. This work suggests that all of the materials in the current 2D library could be rolled into their 1D counterparts and a plethora of function-designable 1D heterostructures could be realized.

04 Oct 12:43

Micromagnetometry of two-dimensional ferromagnets

by M. Kim

Nature Electronics, Published online: 30 September 2019; doi:10.1038/s41928-019-0302-6

Graphene-based Hall magnetometers can be used to study the magnetization of two-dimensional ferromagnets.
01 Jul 02:53

[ASAP] Which Transition Metal Atoms Can Be Embedded into Two-Dimensional Molybdenum Dichalcogenides and Add Magnetism?

by J. Karthikeyan*†, Hannu-Pekka Komsa†, Matthias Batzill‡, and Arkady V. Krasheninnikov*§†

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Nano Letters
DOI: 10.1021/acs.nanolett.9b01555
18 Apr 09:42

[ASAP] Formation and Healing of Defects in Atomically Thin GaSe and InSe

by David G. Hopkinson, Viktor Zólyomi, Aidan P. Rooney, Nick Clark, Daniel J. Terry, Matthew Hamer, David J. Lewis, Christopher S. Allen, Angus I. Kirkland, Yuri Andreev, Zakhar Kudrynskyi, Zakhar Kovalyuk, Amalia Patanè, Vladimir I. Fal’ko, Roman Gorbachev, Sarah J. Haigh

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ACS Nano
DOI: 10.1021/acsnano.8b08253
06 Dec 13:38

Nanoscale tweezers for single-cell biopsies

by Binoy Paulose Nadappuram

Nanoscale tweezers for single-cell biopsies

Nanoscale tweezers for single-cell biopsies, Published online: 03 December 2018; doi:10.1038/s41565-018-0315-8

A nanotweezer system based on dielectrophoresis can trap, manipulate and extract biomolecules and organelles in living cells at physiological conditions with high spatiotemporal resolution and minimal invasiveness.
03 Dec 14:30

[ASAP] Ferromagnet-Free All-Electric Spin Hall Transistors

by Won Young Choi, Hyung-jun Kim, Joonyeon Chang, Suk Hee Han, Adel Abbout, Hamed Ben Mohamed Saidaoui, Aurélien Manchon, Kyung-Jin Lee, Hyun Cheol Koo

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Nano Letters
DOI: 10.1021/acs.nanolett.8b03998
29 Nov 13:34

[ASAP] All-2D Material Inkjet-Printed Capacitors: Toward Fully Printed Integrated Circuits

by Robyn Worsley, Lorenzo Pimpolari, Daryl McManus, Ning Ge, Robert Ionescu, Jarrid A. Wittkopf, Adriana Alieva, Giovanni Basso, Massimo Macucci, Giuseppe Iannaccone, Kostya S. Novoselov, Helen Holder, Gianluca Fiori, Cinzia Casiraghi

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ACS Nano
DOI: 10.1021/acsnano.8b06464
29 Nov 13:30

Direct synthesis of MoS2 or MoO3 via thermolysis of a dialkyl dithiocarbamato molybdenum(IV) complex

Chem. Commun., 2018, Advance Article
DOI: 10.1039/C8CC08932A, Communication
Niting Zeng, David G. Hopkinson, Ben F. Spencer, Simon G. McAdams, Aleksander A. Tedstone, Sarah J. Haigh, David J. Lewis
Direct synthesis of either 2H-MoS2 or α-MoO3 is made possible by thermolysis of the same single source precursor in either argon or air at moderate temperatures.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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14 Nov 11:03

[ASAP] Shape-Pure, Nearly Monodispersed CsPbBr3 Nanocubes Prepared Using Secondary Aliphatic Amines

by Muhammad Imran, Palvasha Ijaz, Dmitry Baranov, Luca Goldoni, Urko Petralanda, Quinten Akkerman, Ahmed L. Abdelhady, Mirko Prato, Paolo Bianchini, Ivan Infante, Liberato Manna

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Nano Letters
DOI: 10.1021/acs.nanolett.8b03598
04 Oct 12:23

Infrared-to-violet tunable optical activity in atomic films of GaSe, InSe, and their heterostructures

by Daniel J Terry, Viktor Zólyomi, Matthew Hamer, Anastasia V Tyurnina, David G Hopkinson, Alexander M Rakowski, Samuel J Magorrian, Nick Clark, Yuri M Andreev, Olga Kazakova, Konstantin Novoselov, Sarah J Haigh, Vladimir I Fal’ko and Roman Gorbachev
Two-dimensional (2D) semiconductors—atomic layers of materials with covalent intra-layer bonding and weak (van der Waals or quadrupole) coupling between the layers—are a new class of materials with great potential for optoelectronic applications. Among those, a special position is now being taken by post-transition metal chalcogenides (PTMC), InSe and GaSe. It has recently been found (Bandurin et al 2017 Nat. Nanotechnol . 12 223–7) that the band gap in 2D crystals of InSe more than doubles in the monolayer compared to thick multilayer crystals, while the high mobility of conduction band electrons is promoted by their light in-plane mass. Here, we use Raman and PL measurements of encapsulated few layer samples, coupled with accurate atomic force and transmission electron microscope structural characterisation to reveal new optical properties of atomically thin GaSe preserved by hBN encapsulation. The band gaps we observe complement the spectral range provided...
23 Aug 11:07

[ASAP] Probing the Internal Atomic Charge Density Distributions in Real Space

by Gabriel Sánchez-Santolino, Nathan R. Lugg, Takehito Seki, Ryo Ishikawa, Scott D. Findlay, Yuji Kohno, Yuya Kanitani, Shinji Tanaka, Shigetaka Tomiya, Yuichi Ikuhara, Naoya Shibata

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ACS Nano
DOI: 10.1021/acsnano.8b03712
09 Aug 13:26

[ASAP] Scalable Patterning of Encapsulated Black Phosphorus

by Nick Clark, Lan Nguyen, Matthew J. Hamer, Fredrik Schedin, Edward A. Lewis, Eric Prestat, Alistair Garner, Yang Cao, Mengjian Zhu, Reza Kashtiban, Jeremy Sloan, Demie Kepaptsoglou, Roman V. Gorbachev, Sarah J. Haigh

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Nano Letters
DOI: 10.1021/acs.nanolett.8b00946
01 May 10:16

InSe monolayer: synthesis, structure and ultra-high second-harmonic generation

by Jiadong Zhou, Jia Shi, Qingsheng Zeng, Yu Chen, Lin Niu, Fucai Liu, Ting Yu, Kazu Suenaga, Xinfeng Liu, Junhao Lin and Zheng Liu
III–IV layered materials such as indium selenide have excellent photoelectronic properties. However, synthesis of materials in such group, especially with a controlled thickness down to monolayer, still remains challenging. Herein, we demonstrate the successful synthesis of monolayer InSe by physical vapor deposition (PVD) method. The high quality of the sample was confirmed by complementary characterization techniques such as Raman spectroscopy, atomic force microscopy (AFM) and high resolution annular dark field scanning transmission electron microscopy (ADF-STEM). We found the co-existence of different stacking sequence ( β - and γ -InSe) in the same flake with a sharp grain boundary in few-layered InSe. Edge reconstruction is also observed in monolayer InSe, which has a distinct atomic structure from the bulk lattice. Moreover, we discovered that the second-harmonic generation (SHG) signal from monolayer InSe shows large optical second-order susceptibility that is...
01 May 10:13

[ASAP] Highly Efficient Visible Colloidal Lead-Halide Perovskite Nanocrystal Light-Emitting Diodes

by Fei Yan, Jun Xing, Guichuan Xing, Lina Quan, Swee Tiam Tan, Jiaxin Zhao, Rui Su, Lulu Zhang, Shi Chen, Yawen Zhao, Alfred Huan, Edward H. Sargent, Qihua Xiong, Hilmi Volkan Demir

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Nano Letters
DOI: 10.1021/acs.nanolett.8b00789
01 May 10:12

[ASAP] Room Temperature Intrinsic Ferromagnetism in Epitaxial Manganese Selenide Films in the Monolayer Limit

by Dante J. O’Hara, Tiancong Zhu, Amanda H. Trout, Adam S. Ahmed, Yunqiu Kelly Luo, Choong Hee Lee, Mark R. Brenner, Siddharth Rajan, Jay A. Gupta, David W. McComb, Roland K. Kawakami

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Nano Letters
DOI: 10.1021/acs.nanolett.8b00683
01 May 10:09

[ASAP] Low-Threshold Lasing from 2D Homologous Organic–Inorganic Hybrid Ruddlesden–Popper Perovskite Single Crystals

by Chinnambedu Murugesan Raghavan, Tzu-Pei Chen, Shao-Sian Li, Wei-Liang Chen, Chao-Yuan Lo, Yu-Ming Liao, Golam Haider, Cheng-Chieh Lin, Chia-Chun Chen, Raman Sankar, Yu-Ming Chang, Fang-Cheng Chou, Chun-Wei Chen

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Nano Letters
DOI: 10.1021/acs.nanolett.8b00990
01 May 10:09

[ASAP] Intrinsic Transport in 2D Heterostructures Mediated through h-BN Tunneling Contacts

by Akshay A. Murthy, Teodor K. Stanev, Jeffrey D. Cain, Shiqiang Hao, Trevor LaMountain, Sungkyu Kim, Nathaniel Speiser, Kenji Watanabe, Takashi Taniguchi, Chris Wolverton, Nathaniel P. Stern, Vinayak P. Dravid

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Nano Letters
DOI: 10.1021/acs.nanolett.8b00444
01 May 10:08

[ASAP] Ultrathin Bismuth Film on 1T-TaS2: Structural Transition and Charge-Density-Wave Proximity Effect

by Keiko Yamada, Seigo Souma, Kunihiko Yamauchi, Natsumi Shimamura, Katsuaki Sugawara, Chi Xuan Trang, Tamio Oguchi, Keiji Ueno, Takashi Takahashi, Takafumi Sato

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Nano Letters
DOI: 10.1021/acs.nanolett.8b01003
01 May 10:06

Electric-field switching of two-dimensional van der Waals magnets

by Shengwei Jiang

Electric-field switching of two-dimensional van der Waals magnets

Electric-field switching of two-dimensional van der Waals magnets, Published online: 12 March 2018; doi:10.1038/s41563-018-0040-6

The application of electric fields enables reversible switching of the magnetic order of CrI3 bilayers between antiferromagnetic and ferromagnetic states.
01 May 10:05

Vapour–liquid–solid growth of monolayer MoS2 nanoribbons

by Shisheng Li

Vapour–liquid–solid growth of monolayer MoS2 nanoribbons

Vapour–liquid–solid growth of monolayer MoS<sub>2</sub> nanoribbons, Published online: 23 April 2018; doi:10.1038/s41563-018-0055-z

Monolayer MoS2 can be laterally grown in the vapour–liquid–solid mode, forming highly crystalline nano- and microribbon structures.
01 May 10:04

Present status and future prospects of perovskite photovoltaics

by Henry J. Snaith

Present status and future prospects of perovskite photovoltaics

Present status and future prospects of perovskite photovoltaics, Published online: 23 April 2018; doi:10.1038/s41563-018-0071-z

Solar cells based on metal halide perovskites continue to approach their theoretical performance limits thanks to worldwide research efforts. Mastering the materials properties and addressing stability may allow this technology to bring profound transformations to the electric power generation industry.
01 May 10:03

An unusual continuous paramagnetic-limited superconducting phase transition in 2D NbSe 2

by Egon Sohn

An unusual continuous paramagnetic-limited superconducting phase transition in 2D NbSe 2

An unusual continuous paramagnetic-limited superconducting phase transition in 2D NbSe<sub> 2 </sub>, Published online: 30 April 2018; doi:10.1038/s41563-018-0061-1

Tunnelling spectroscopy reveals a continuous closing of the superconducting gap at low temperature and high in-plane magnetic field in few-layer NbSe2, due to the Ising spin–orbit coupling of these materials.
14 Aug 10:39

Atomically Flat Zigzag Edges in Monolayer MoS2 by Thermal Annealing

by Qu Chen, Huashan Li, Wenshuo Xu, Shanshan Wang, Hidetaka Sawada, Christopher S. Allen, Angus I. Kirkland, Jeffrey C. Grossman and Jamie H. Warner

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Nano Letters
DOI: 10.1021/acs.nanolett.7b02192
14 Aug 10:30

Stabilizing Cesium Lead Halide Perovskite Lattice through Mn(II) Substitution for Air-Stable Light-Emitting Diodes

by Shenghan Zou, Yongsheng Liu, Jianhai Li, Caiping Liu, Rui Feng, Feilong Jiang, Yongxiang Li, Jizhong Song, Haibo Zeng, Maochun Hong and Xueyuan Chen

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Journal of the American Chemical Society
DOI: 10.1021/jacs.7b04000
14 Jun 08:00

Stabilization of the Metastable Lead Iodide Perovskite Phase via Surface Functionalization

by Yongping Fu, Tao Wu, Jue Wang, Jianyuan Zhai, Melinda J. Shearer, Yuzhou Zhao, Robert J. Hamers, Erjun Kan, Kaiming Deng, X.-Y. Zhu and Song Jin

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Nano Letters
DOI: 10.1021/acs.nanolett.7b01500
31 May 10:30

High-Temperature–Short-Time Annealing Process for High-Performance Large-Area Perovskite Solar Cells

by Minjin Kim, Gi-Hwan Kim, Kyoung Suk Oh, Yimhyun Jo, Hyun Yoon, Ka-Hyun Kim, Heon Lee, Jin Young Kim and Dong Suk Kim

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ACS Nano
DOI: 10.1021/acsnano.7b02015
31 May 10:28

Flexible Multiferroic Bulk Heterojunction with Giant Magnetoelectric Coupling via van der Waals Epitaxy

by Tahta Amrillah, Yugandhar Bitla, Kwangwoo Shin, Tiannan Yang, Ying-Hui Hsieh, Yu-You Chiou, Heng-Jui Liu, Thi Hien Do, Dong Su, Yi-Chun Chen, Shien-Uang Jen, Long-Qing Chen, Kee Hoon Kim, Jenh-Yih Juang and Ying-Hao Chu

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ACS Nano
DOI: 10.1021/acsnano.7b02102
24 May 10:31

Organic–Inorganic Hybrid Perovskite Nanowire Laser Arrays

by Peng Liu, Xianxiong He, Jiahuan Ren, Qing Liao, Jiannian Yao and Hongbing Fu

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ACS Nano
DOI: 10.1021/acsnano.7b01351
23 May 09:14

Manipulating Ion Migration for Highly Stable Light-Emitting Diodes with Single-Crystalline Organometal Halide Perovskite Microplatelets

by Mingming Chen, Xin Shan, Thomas Geske, Junqiang Li and Zhibin Yu

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ACS Nano
DOI: 10.1021/acsnano.7b02629