24 Nov 11:39
by Zheng Liu, Zheng Li, Zhen Xu, Zhixiang Xia, Xiaozhen Hu, Liang Kou, Li Peng, Yangyang Wei, and Chao Gao

Chemistry of Materials
DOI: 10.1021/cm5033089
Publication Date (Web): October 24, 2014
20 Nov 21:57
by Lilit Aboshyan-Sorgho, Timothée Lathion, Laure Guénée, Céline Besnard and Claude Piguet

Inorganic Chemistry
DOI: 10.1021/ic5022559
15 Nov 19:07
Publication date: February 2015
Source:Tribology International, Volume 82, Part A
Author(s): M. Mahrova , F. Pagano , V. Pejakovic , A. Valea , M. Kalin , A Igartua , E. Tojo
A series of eight new dicationic ionic liquids incorporating polyethylene glycol chains linking two N-alkylpyridinium moieties through rings position 2, were synthesized and investigated for their potential use as lubricants or lubricant additives. Alkylsulfate and bis(trifluoromethanesulfonyl)imide [NTf2] were selected as anions. Dicationic ionic liquids containing [NTf2] anion demonstrated good properties as neat lubricants showing low coefficient of friction and wear comparable with the reference lubricant (glycerol). Even more interesting could be their use as friction modifier additives since an important decrease in the coefficient of friction was achieved with a really low concentration of ionic liquid. The thermal analysis of all ionic liquids by thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC) is also described.
15 Nov 19:05
by Zhen Xu, Bingna Zheng, Jiewei Chen and Chao Gao

Chemistry of Materials
DOI: 10.1021/cm503418h
15 Nov 18:32
by Wei-Wei Xiong, Jianwei Miao, Kaiqi Ye, Yue Wang, Bin Liu, Qichun Zhang
Abstract
Inserting polymers into a crystalline inorganic matrix to understand the structure, position, and the structure–property relationships of the resulting composites is important for designing new inorganic-organic materials and tuning their properties. Single crystals of polymer-chalcogenide composites were successfully prepared by trapping polyethyleneglycol within a selenidostannate matrix under surfactant-thermal conditions. This work might provide a new strategy for preparing novel crystalline polymer-inorganic composites through encapsulating polymer chains within inorganic matrices.
Common thread: Inserting a polymer into a crystalline inorganic matrix to understand its structure, position, and the structure–property relationships of the resulting composites is important for designing new inorganic–organic materials and tuning their properties. Single crystals of polymer-chalcogenide composites were isolated by trapping polyethyleneglycol within a selenidostannate matrix under surfactant-thermal conditions.
12 Nov 20:41
by Joshua D. Wood, Spencer A. Wells, Deep Jariwala, Kan-Sheng Chen, EunKyung Cho, Vinod K. Sangwan, Xiaolong Liu, Lincoln J. Lauhon, Tobin J. Marks and Mark C. Hersam

Nano Letters
DOI: 10.1021/nl5032293
11 Nov 17:32
by Chakra P. Joshi and Terry P. Bigioni

Langmuir
DOI: 10.1021/la503574s
11 Nov 12:14
by Tu Tran, Supratim Ghosh and Dérick Rousseau

Crystal Growth & Design
DOI: 10.1021/cg501221d
08 Nov 15:57
by ShihChi Weng, Peizhe Sun, Weiwei Ben, Ching-Hua Huang, Lester T. Lee, and Ernest R. Blatchley III

Environmental Science & Technology Letters
DOI: 10.1021/ez5003133
Publication Date (Web): October 24, 2014
08 Nov 10:26
Publication date: February 2015
Source:Tribology International, Volume 82, Part A
Author(s): Fei Shen , Weiping Hu , Qingchun Meng
In this investigation an approach to fretting fatigue life prediction is developed with consideration of damage-coupled elastic–plastic constitutive model and wear. Nonlinear kinematic hardening is employed in the analysis of elastic–plastic damage, and the total damage is divided into two parts, elastic damage and plastic damage, which are related to the cyclic stress and accumulated plastic strain, respectively. Wear is modeled by the energy wear law to simulate the evolution of contact geometry. A two dimensional plane strain finite element implementation is presented for fretting, including the case of partial slip and gross sliding. The progressive fatigue damage and wear is simulated and the results are compared with experimental data from the literature.
06 Nov 09:34
Publication date: 15 November 2014
Source:Surface and Coatings Technology, Volume 258
Author(s): Yu Xi Wang , Sam Zhang
Over the past decades, hard and super hard ceramic coatings have been developed and widely used in various industrial applications. Meanwhile, an increasing number of studies have realized that the toughness is just as crucial, if not more, than hardness especially for ceramic coatings. However, hardness and toughness do not go naturally hand in hand. In other words, hard coatings usually are brittle and less durable while toughened coatings are of lower strength. For practical engineering applications, it is more desirable to have coatings with high hardness without sacrificing toughness too much. In this article, a review is presented on continuous progress to realize hard-yet-tough ceramic coatings from an angle of hardening as well as toughening.