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27 Nov 20:10

The microbiome of New World vultures

by Michael Roggenbuck

Article

Vultures are scavengers with a high tolerance to bacterial toxins in decaying meat. Here, Roggenbuck et al. show that the vulture’s gut microbiome displays unique features and is dominated by Clostridia and Fusobacteria, two bacterial groups commonly associated with infectious disease in other animals.

Nature Communications doi: 10.1038/ncomms6498

Authors: Michael Roggenbuck, Ida Bærholm Schnell, Nikolaj Blom, Jacob Bælum, Mads Frost Bertelsen, Thomas Sicheritz Pontén, Søren Johannes Sørensen, M. Thomas P. Gilbert, Gary R. Graves, Lars H Hansen

27 Nov 20:03

Three-Step Sequential Solution Deposition of PbI2-Free CH3NH3PbI3 Perovskite

J. Mater. Chem. A, 2014, Accepted Manuscript
DOI: 10.1039/C4TA05384B, Communication
Yixin Zhao, Kai Zhu
We demonstrate a three-step sequential solution process to prepare PbI2-free CH3NH3PbI3 perovskite films. In this three-step method, a thermally unstable stoichiometric PbI2[round bullet, filled]CH3NH3Cl precursor film is first deposited on the mesoporous...
The content of this RSS Feed (c) The Royal Society of Chemistry
27 Nov 17:26

Formation of ring-in-ring complexes between crown ethers and rigid TVBox8+

DJL

TVBOX8+ now available with free Sky+ Movies

Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC08053J, Communication
Junling Sun, Marco Frasconi, Zhichang Liu, Jonathan C Barnes, Yuping Wang, Dongyang Chen, Charlotte L Stern, J. Fraser Stoddart
A rigid octacationic tetraviologen-based cyclophane, TVBox8+, is reported. It possesses a highly electron-deficient rectangular cavity with a length of 23 A and width of 6.1 A and is capable of...
The content of this RSS Feed (c) The Royal Society of Chemistry
26 Nov 11:50

Designing Nanostructured Strontium Aluminates particles for Achieve High Luminescence Properties

DJL

for achieve

J. Mater. Chem. C, 2014, Accepted Manuscript
DOI: 10.1039/C4TC02262A, Paper
Rocio Estefania Rojas, Miguel Angel Rodriguez, Fernando Rubio-Marcos, Aida Serrano, Jose. F. Fernandez Fernandez
The synthesis of submicron phosphorescent particles has been widely studied in the last decade due to the promising industrial applications of these materials. Several matrices have been developed; being the...
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25 Nov 21:11

Chemical vapour deposition of antimony chalcogenides with positional and orientational control: precursor design and substrate selectivity

J. Mater. Chem. C, 2015, 3,423-430
DOI: 10.1039/C4TC02327G, Paper
S. L. Benjamin, C. H. de Groot, A. L. Hector, R. Huang, E. Koukharenko, W. Levason, G. Reid
A series of alkylchalcogenostibines have been synthesised and employed as precursors for the chemical vapour deposition of Sb2Te3 and Sb2Se3. Variations in substrate and temperature give different film morphologies, and patterned arrays can be deposited using substrate selectivity.
The content of this RSS Feed (c) The Royal Society of Chemistry
24 Nov 11:39

Wet-Spun Continuous Graphene Films

by Zheng Liu, Zheng Li, Zhen Xu, Zhixiang Xia, Xiaozhen Hu, Liang Kou, Li Peng, Yangyang Wei, and Chao Gao

TOC Graphic

Chemistry of Materials
DOI: 10.1021/cm5033089
Publication Date (Web): October 24, 2014
24 Nov 11:35

One-step ultrasonic synthesis of graphene quantum dots with high quantum yield and its application in sensing of alkaline phosphatase

Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC07449A, Communication
xiaojun zhang, Yanhong Zhu, Ling Chen, Guangfeng Wang, hong jiang
With only graphene oxide and KMnO4, the luminescent graphene quantum dots (GQDs) in high quantum yield were prepared by one-step synthesis using ultrasonication, and applied it in the label-free, simple...
The content of this RSS Feed (c) The Royal Society of Chemistry
20 Nov 21:57

Thermodynamic N-Donor trans Influence in Labile Pseudo-Octahedral Zinc Complexes: A Delusion?

by Lilit Aboshyan-Sorgho, Timothée Lathion, Laure Guénée, Céline Besnard and Claude Piguet
DJL

A DELUSION

TOC Graphic

Inorganic Chemistry
DOI: 10.1021/ic5022559
19 Nov 20:49

A very simple and high-yield method to synthesize nanolayered Mn oxide

Dalton Trans., 2015, 44,1039-1045
DOI: 10.1039/C4DT02468K, Paper
Mohammad Mahdi Najafpour, Emad Amini
Nanolayered Mn oxides have been prepared by a very simple, low-cost and high-yield method using soap, KOH, MnCl2 and H2O2.
The content of this RSS Feed (c) The Royal Society of Chemistry
19 Nov 20:41

Well-controlled synthesis of wurtzite-type Cu2ZnSnS4 nanoparticles using multiple sulfur sources via a two-step heating process

CrystEngComm, 2015, 17,174-182
DOI: 10.1039/C4CE01852D, Paper
Hiroyasu Nishi, Takahito Nagano, Tatsuya Kameyama, Susumu Kuwabata, Tsukasa Torimoto
Wurtzite-type Cu2ZnSnS4 nanoparticles were successfully synthesized by a new approach that could control the morphology, chemical composition, and crystal structure of the particles. The formation mechanism was discussed in detail.
The content of this RSS Feed (c) The Royal Society of Chemistry
19 Nov 20:40

Continuous synthesis of graphene sheets by spray pyrolysis and their uses as catalysts for fuel cells

Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC08197H, Communication
Jian Nong Wang, Biao Zou, Xiao Xia Wang, Xin Xin Huang
Graphene sheets (GNS) were synthesized continuously by spray pyrolysis of iron carbonyl and pyridine. The Pt catalyst supported on GNS exhibited an excellent durability for oxygen reduction reaction (ORR). The...
The content of this RSS Feed (c) The Royal Society of Chemistry
19 Nov 10:58

Strain and structure heterogeneity in MoS2 atomic layers grown by chemical vapour deposition

by Zheng Liu

Article

Large-size monolayer molybdenum disulfide (MoS 2 ) has recently been produced via chemical vapour deposition (CVD), yet its structures and physical properties are yet to be fully explored. Here, the authors study the growth-induced strain in CVD-grown MoS 2 and strain-based bandgap engineering of MoS 2 .

Nature Communications doi: 10.1038/ncomms6246

Authors: Zheng Liu, Matin Amani, Sina Najmaei, Quan Xu, Xiaolong Zou, Wu Zhou, Ting Yu, Caiyu Qiu, A. Glen Birdwell, Frank J. Crowne, Robert Vajtai, Boris I. Yakobson, Zhenhai Xia, Madan Dubey, Pulickel M. Ajayan, Jun Lou

15 Nov 19:07

Pyridinium based dicationic ionic liquids as base lubricants or lubricant additives

Publication date: February 2015
Source:Tribology International, Volume 82, Part A
Author(s): M. Mahrova , F. Pagano , V. Pejakovic , A. Valea , M. Kalin , A Igartua , E. Tojo
A series of eight new dicationic ionic liquids incorporating polyethylene glycol chains linking two N-alkylpyridinium moieties through rings position 2, were synthesized and investigated for their potential use as lubricants or lubricant additives. Alkylsulfate and bis(trifluoromethanesulfonyl)imide [NTf2] were selected as anions. Dicationic ionic liquids containing [NTf2] anion demonstrated good properties as neat lubricants showing low coefficient of friction and wear comparable with the reference lubricant (glycerol). Even more interesting could be their use as friction modifier additives since an important decrease in the coefficient of friction was achieved with a really low concentration of ionic liquid. The thermal analysis of all ionic liquids by thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC) is also described.

15 Nov 19:05

Highly Efficient Synthesis of Neat Graphene Nanoscrolls from Graphene Oxide by Well-Controlled Lyophilization

by Zhen Xu, Bingna Zheng, Jiewei Chen and Chao Gao
DJL

GRAPHICAL ABSTRACT FAIL! NANOSCOLLS

TOC Graphic

Chemistry of Materials
DOI: 10.1021/cm503418h
15 Nov 18:32

Threading Chalcogenide Layers with Polymer Chains

by Wei-Wei Xiong, Jianwei Miao, Kaiqi Ye, Yue Wang, Bin Liu, Qichun Zhang

Abstract

Inserting polymers into a crystalline inorganic matrix to understand the structure, position, and the structure–property relationships of the resulting composites is important for designing new inorganic-organic materials and tuning their properties. Single crystals of polymer-chalcogenide composites were successfully prepared by trapping polyethyleneglycol within a selenidostannate matrix under surfactant-thermal conditions. This work might provide a new strategy for preparing novel crystalline polymer-inorganic composites through encapsulating polymer chains within inorganic matrices.

Thumbnail image of graphical abstract

Common thread: Inserting a polymer into a crystalline inorganic matrix to understand its structure, position, and the structure–property relationships of the resulting composites is important for designing new inorganic–organic materials and tuning their properties. Single crystals of polymer-chalcogenide composites were isolated by trapping polyethyleneglycol within a selenidostannate matrix under surfactant-thermal conditions.

12 Nov 20:41

Effective Passivation of Exfoliated Black Phosphorus Transistors against Ambient Degradation

by Joshua D. Wood, Spencer A. Wells, Deep Jariwala, Kan-Sheng Chen, EunKyung Cho, Vinod K. Sangwan, Xiaolong Liu, Lincoln J. Lauhon, Tobin J. Marks and Mark C. Hersam

TOC Graphic

Nano Letters
DOI: 10.1021/nl5032293
12 Nov 15:12

Silica-based nanoparticles: a versatile tool for the development of efficient imaging agents

Chem. Soc. Rev., 2015, 44,4645-4671
DOI: 10.1039/C4CS00270A, Review Article
Claudia Caltagirone, Alexandre Bettoschi, Alessandra Garau, Riccardo Montis
In this review a selection of the most recent examples of imaging techniques applied to silica-based NPs for imaging is reported.
The content of this RSS Feed (c) The Royal Society of Chemistry
11 Nov 17:33

Chemical Vapour Deposition of Antimony Chalcogenides with Positional and Orientational Control: Precursor Design and Substrate Selectivity

J. Mater. Chem. C, 2014, Accepted Manuscript
DOI: 10.1039/C4TC02327G, Paper
sophie louise Benjamin, Kees de Groot, Andrew L Hector, Ruomeng Huang, Elena Koukharenko, W Levason, Gillian Reid
A series of alkylchalcogenostibines, Me2SbSenBu, MeSb(SenBu)2, Sb(SenBu)3 and MeSb(TenBu)2, have been designed and synthesised as potential precursors for chemical vapour deposition (CVD) by reaction of nBuELi (E = Se, Te)...
The content of this RSS Feed (c) The Royal Society of Chemistry
11 Nov 17:32

Model for the Phase Transfer of Nanoparticles Using Ionic Surfactants

by Chakra P. Joshi and Terry P. Bigioni

TOC Graphic

Langmuir
DOI: 10.1021/la503574s
11 Nov 12:14

Spheroidal Fat Crystal Microstructures Formed with Confined Gap Shearing

by Tu Tran, Supratim Ghosh and Dérick Rousseau
DJL

Is the word FAT scientific hmmm

TOC Graphic

Crystal Growth & Design
DOI: 10.1021/cg501221d
11 Nov 11:53

Batteries: Knowing when small is better

by Paul V. Braun

Nature Nanotechnology. doi:10.1038/nnano.2014.263

Authors: Paul V. Braun & Ralph G. Nuzzo

A battery fabricated within a ceramic nanopore can be used for studying nanoscale electrochemical effects.

11 Nov 10:54

Multicolor upconversion NaLuF4 fluorescent nanoprobe for plant cell imaging and detection of sodium fluorescein

J. Mater. Chem. C, 2015, 3,153-161
DOI: 10.1039/C4TC01766H, Paper
Zenghui Chen, Xiaofeng Wu, Shigang Hu, Pan Hu, Huanyuan Yan, Zhijun Tang, Yunxin Liu
Detection limit of sodium fluorescein in plant cells can reach 0.14 [small mu ]g cm-3 based on LRET from UCNPs to SF.
The content of this RSS Feed (c) The Royal Society of Chemistry
08 Nov 15:57

The Presence of Pharmaceuticals and Personal Care Products in Swimming Pools

by ShihChi Weng, Peizhe Sun, Weiwei Ben, Ching-Hua Huang, Lester T. Lee, and Ernest R. Blatchley III

TOC Graphic

Environmental Science & Technology Letters
DOI: 10.1021/ez5003133
Publication Date (Web): October 24, 2014
08 Nov 10:26

A damage mechanics approach to fretting fatigue life prediction with consideration of elastic–plastic damage model and wear

Publication date: February 2015
Source:Tribology International, Volume 82, Part A
Author(s): Fei Shen , Weiping Hu , Qingchun Meng
In this investigation an approach to fretting fatigue life prediction is developed with consideration of damage-coupled elastic–plastic constitutive model and wear. Nonlinear kinematic hardening is employed in the analysis of elastic–plastic damage, and the total damage is divided into two parts, elastic damage and plastic damage, which are related to the cyclic stress and accumulated plastic strain, respectively. Wear is modeled by the energy wear law to simulate the evolution of contact geometry. A two dimensional plane strain finite element implementation is presented for fretting, including the case of partial slip and gross sliding. The progressive fatigue damage and wear is simulated and the results are compared with experimental data from the literature.

07 Nov 20:33

Will it crystallise? Predicting crystallinity of molecular materials

CrystEngComm, 2014, Accepted Manuscript
DOI: 10.1039/C4CE01912A, Paper
Jerome Wicker, Richard Cooper
Predicting and controlling crystallinity of molecular materials has applications in a crystal engineering context, as well as process control and formulation in the pharmaceutical industry. Here, we present a machine...
The content of this RSS Feed (c) The Royal Society of Chemistry
07 Nov 20:22

A cheap and facile route to synthesize monodisperse magnetic nanocrystals and their application as MRI agents

Dalton Trans., 2015, 44,247-253
DOI: 10.1039/C4DT02425G, Paper
Guixin Yang, Fei He, Ruichan Lv, Shili Gai, Ziyong Cheng, Yunlu Dai, Piaoping Yang
Monodisperse MnFe2O4 and CoFe2O4 nanocrystals (NCs) were synthesized by a facile thermal decomposition strategy, using very cheap polyisobutylene succimide and paraffin oil as a surfactant and solvent which was used as the effective T2 contrast agent for MRI.
The content of this RSS Feed (c) The Royal Society of Chemistry
07 Nov 18:18

Zinc complexes as fluorescent chemosensors for nucleic acids: new perspectives for a "boring" element

DJL

Why is boring in speechmarks

Dalton Trans., 2015, 44,3527-3535
DOI: 10.1039/C4DT02881C, Perspective
Alessio Terenzi, Antonino Lauria, Anna Maria Almerico, Giampaolo Barone
Recent applications of zinc(II) complexes as fluorescent probes for nucleic acids are described highlighting their potential as diagnostic tools.
The content of this RSS Feed (c) The Royal Society of Chemistry
07 Nov 18:10

MR imaging probes: design and applications

Dalton Trans., 2015, 44,4804-4818
DOI: 10.1039/C4DT02958E, Perspective
Eszter Boros, Eric M. Gale, Peter Caravan
This perspective outlines strategies towards the development of MR imaging probes that our lab has explored.
The content of this RSS Feed (c) The Royal Society of Chemistry
06 Nov 09:52

Observation of Dicke superradiance for two artificial atoms in a cavity with high decay rate

by J. A. Mlynek
DJL

Dr DickeY superradiance

Article

Individual emitters of light in close proximity, such as atoms, can couple together via the light they create leading to a concentrated burst of radiation. Here Mlynek et al. experminetally explore the fundamental origin of this superradiance by studying two superconducting qubits coupled to a microwave cavity.

Nature Communications doi: 10.1038/ncomms6186

Authors: J. A. Mlynek, A. A. Abdumalikov, C. Eichler, A. Wallraff

06 Nov 09:34

Toward hard yet tough ceramic coatings

Publication date: 15 November 2014
Source:Surface and Coatings Technology, Volume 258
Author(s): Yu Xi Wang , Sam Zhang
Over the past decades, hard and super hard ceramic coatings have been developed and widely used in various industrial applications. Meanwhile, an increasing number of studies have realized that the toughness is just as crucial, if not more, than hardness especially for ceramic coatings. However, hardness and toughness do not go naturally hand in hand. In other words, hard coatings usually are brittle and less durable while toughened coatings are of lower strength. For practical engineering applications, it is more desirable to have coatings with high hardness without sacrificing toughness too much. In this article, a review is presented on continuous progress to realize hard-yet-tough ceramic coatings from an angle of hardening as well as toughening.