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19 Feb 19:56

Nanoscale Imaging of Charge Carrier and Exciton Trapping at Structural Defects in Organic Semiconductors

by Christoph Große, Olle Gunnarsson, Pablo Merino, Klaus Kuhnke and Klaus Kern

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Nano Letters
DOI: 10.1021/acs.nanolett.6b00190
19 Feb 13:19

Reversible Bergman cyclization by atomic manipulation

by Bruno Schuler

Nature Chemistry 8, 220 (2016). doi:10.1038/nchem.2438

Authors: Bruno Schuler, Shadi Fatayer, Fabian Mohn, Nikolaj Moll, Niko Pavliček, Gerhard Meyer, Diego Peña & Leo Gross

The Bergman cyclization is a fascinating rearrangement reaction with implications beyond organic chemistry. It has now been shown that a reversible Bergman cyclization reaction in a single molecule sitting on an ultrathin NaCl film can be triggered and directly imaged using atomic force microscopy. The interconverted diradical and diyne products are shown to have distinct chemical and physical properties.

17 Feb 09:37

Charge-Transfer-Induced Magic Cluster Formation of Azaborine Heterocycles on Noble Metal Surfaces

by Colin J. Murphy, Daniel P. Miller, Scott Simpson, Andrew Baggett, Alex Pronschinske, Melissa L. Liriano, Andrew J. Therrien, Axel Enders, Shih-Yuan Liu, Eva Zurek and E. Charles H. Sykes

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The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.5b11970
16 Feb 22:31

Comparing Ullmann Coupling on Noble Metal Surfaces: On-Surface Polymerization of 1,3,6,8-Tetrabromopyrene on Cu(111) and Au(111)

by Tuan Anh Pham, Fei Song, Manh-Thuong Nguyen, Zheshen Li, Florian Studener, Meike Stöhr

Abstract

The on-surface polymerization of 1,3,6,8-tetrabromopyrene (Br4Py) on Cu(111) and Au(111) surfaces under ultrahigh vacuum conditions was investigated by a combination of scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy (XPS) and density functional theory (DFT) calculations. Deposition of Br4Py on Cu(111) held at 300 K resulted in a spontaneous debromination reaction, generating the formation of a branched coordination polymer network stabilized by C−Cu−C bonds. After annealing at 473 K, the C−Cu−C bonds were converted to covalent C−C bonds, leading to the formation of a covalently linked molecular network of short oligomers. In contrast, highly ordered self-assembled two-dimensional (2D) patterns stabilized by both Br−Br halogen and Br−H hydrogen bonds were observed upon deposition of Br4Py on Au(111) held at 300 K. Subsequent annealing of the sample at 473 K led to a dissociation of the C−Br bonds and the formation of disordered metal-coordinated molecular networks. Further annealing at 573 K resulted in the formation of covalently linked disordered networks. Importantly, we found that the chosen substrate not only plays an important role as catalyst for the Ullmann reaction, but also influences the formation of different types of intermolecular bonds and thus, determines the final polymer network morphology. DFT calculations further support our experimental findings obtained by STM and XPS and add complementary information on the reaction pathway of Br4Py on the different substrates.

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On-surface polymerization: The chosen precursor was deposited on both Cu(111) and Au(111) surfaces under ultrahigh vacuum conditions. The impact of different metal substrates on the formation and morphology of polymer networks upon annealing was successfully demonstrated by a combination of scanning tunneling microscopy, X-ray photoelectron spectroscopy and density functional theory calculations.

15 Feb 20:53

Magnetization switching by spin–orbit torque in an antiferromagnet–ferromagnet bilayer system

by Shunsuke Fukami

Nature Materials. doi:10.1038/nmat4566

Authors: Shunsuke Fukami, Chaoliang Zhang, Samik DuttaGupta, Aleksandr Kurenkov & Hideo Ohno

15 Feb 18:38

Intrinsic Two-Dimensional Organic Topological Insulators in Metal–Dicyanoanthracene Lattices

by L. Z. Zhang, Z. F. Wang, B. Huang, B. Cui, Zhiming Wang, S. X. Du, H.-J. Gao and Feng Liu

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Nano Letters
DOI: 10.1021/acs.nanolett.6b00110
12 Feb 08:54

Room-Temperature Quantum Coherence and Rabi Oscillations in Vanadyl Phthalocyanine: Toward Multifunctional Molecular Spin Qubits

by Matteo Atzori, Lorenzo Tesi, Elena Morra, Mario Chiesa, Lorenzo Sorace and Roberta Sessoli

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Journal of the American Chemical Society
DOI: 10.1021/jacs.5b13408
11 Feb 18:17

Detection of Light Emission from (S)-PTCDI Molecules Adsorbed on Au(111) and NiAl(110) Surfaces Induced by a Scanning Tunneling Microscope

by Pawel Krukowski, Takuro Tsuzuki, Yuto Minagawa, Nami Yajima, Songpol Chaunchaiyakul, Megumi Akai-Kasaya, Akira Saito, Yusuke Miyake, Mitsuhiro Katayama and Yuji Kuwahara

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The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.5b12313
11 Feb 16:39

Imaging Cyclotron Orbits of Electrons in Graphene

by Sagar Bhandari, Gil-Ho Lee, Anna Klales, Kenji Watanabe, Takashi Taniguchi, Eric Heller, Philip Kim and Robert M. Westervelt

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Nano Letters
DOI: 10.1021/acs.nanolett.5b04609
11 Feb 16:37

Nanoscale Control of Rewriteable Doping Patterns in Pristine Graphene/Boron Nitride Heterostructures

by Jairo Velasco, Long Ju, Dillon Wong, Salman Kahn, Juwon Lee, Hsin-Zon Tsai, Chad Germany, Sebastian Wickenburg, Jiong Lu, Takashi Taniguchi, Kenji Watanabe, Alex Zettl, Feng Wang and Michael F. Crommie

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Nano Letters
DOI: 10.1021/acs.nanolett.5b04441
11 Feb 16:37

Effects of Surface Electron Doping and Substrate on the Superconductivity of Epitaxial FeSe Films

by W. H. Zhang, X. Liu, C. H. P. Wen, R. Peng, S. Y. Tan, B. P. Xie, T. Zhang and D. L. Feng

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Nano Letters
DOI: 10.1021/acs.nanolett.5b05243
11 Feb 09:10

Nanoscale control of rewriteable doping patterns in pristine graphene/boron nitride heterostructures. (arXiv:1602.03245v1 [cond-mat.mes-hall])

by Jairo Velasco Jr., Long Ju, Dillon Wong, Salman Kahn, Juwon Lee, Hsin-Zon Tsai, Chad Germany, Sebastian Wickenburg, Jiong Lu, Takashi Taniguchi, Kenji Watanabe, Alex Zettl, Feng Wang, Michael F. Crommie

Nanoscale control of charge doping in two-dimensional (2D) materials permits the realization of electronic analogs of optical phenomena, relativistic physics at low energies, and technologically promising nanoelectronics. Electrostatic gating and chemical doping are the two most common methods to achieve local control of such doping. However, these approaches suffer from complicated fabrication processes that introduce contamination, change material properties irreversibly, and lack flexible pattern control. Here we demonstrate a clean, simple, and reversible technique that permits writing, reading, and erasing of doping patterns for 2D materials at the nanometer scale. We accomplish this by employing a graphene/boron nitride (BN) heterostructure that is equipped with a bottom gate electrode. By using electron transport and scanning tunneling microscopy (STM), we demonstrate that spatial control of charge doping can be realized with the application of either light or STM tip voltage excitations in conjunction with a gate electric field. Our straightforward and novel technique provides a new path towards on-demand graphene pn junctions and ultra-thin memory devices.

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10 Feb 22:08

Does it take too long to publish research?

by Kendall Powell

Does it take too long to publish research?

Nature 530, 7589 (2016). http://www.nature.com/doifinder/10.1038/530148a

Author: Kendall Powell

Scientists are becoming increasingly frustrated by the time it takes to publish a paper. Something has to change, they say.

10 Feb 18:02

Tunable Band Alignment with Unperturbed Carrier Mobility of On-Surface Synthesized Organic Semiconducting Wires

by Andrea Basagni, Guillaume Vasseur, Carlo A. Pignedoli, Manuel Vilas-Varela, Diego Peña, Louis Nicolas, Lucia Vitali, Jorge Lobo-Checa, Dimas G. de Oteyza, Francesco Sedona, Maurizio Casarin, J. Enrique Ortega and Mauro Sambi

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ACS Nano
DOI: 10.1021/acsnano.5b07683
08 Feb 22:12

Possible light-induced superconductivity in K3C60 at high temperature

by M. Mitrano

Nature advance online publication 08 February 2016. doi:10.1038/nature16522

Authors: M. Mitrano, A. Cantaluppi, D. Nicoletti, S. Kaiser, A. Perucchi, S. Lupi, P. Di Pietro, D. Pontiroli, M. Riccò, S. R. Clark, D. Jaksch & A. Cavalleri

The non-equilibrium control of emergent phenomena in solids is an important research frontier, encompassing effects such as the optical enhancement of superconductivity. Nonlinear excitation of certain phonons in bilayer copper oxides was recently shown to induce superconducting-like optical properties at temperatures far greater than the superconducting transition temperature, Tc (refs 4, 5, 6). This effect was accompanied by the disruption of competing charge-density-wave correlations, which explained some but not all of the experimental results. Here we report a similar phenomenon in a very different compound, K3C60. By exciting metallic K3C60 with mid-infrared optical pulses, we induce a large increase in carrier mobility, accompanied by the opening of a gap in the optical conductivity. These same signatures are observed at equilibrium when cooling metallic K3C60 below Tc (20 kelvin). Although optical techniques alone cannot unequivocally identify non-equilibrium high-temperature superconductivity, we propose this as a possible explanation of our results.

08 Feb 21:19

Out-of-Plane Alignment of Er(trensal) Easy Magnetization Axes Using Graphene

by Jan Dreiser, Giulia E. Pacchioni, Fabio Donati, Luca Gragnaniello, Alberto Cavallin, Kasper S. Pedersen, Jesper Bendix, Bernard Delley, Marina Pivetta, Stefano Rusponi and Harald Brune

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ACS Nano
DOI: 10.1021/acsnano.5b08178
06 Feb 10:43

Monolayer-to-bilayer transformation of silicenes and their structural analysis

by Ritsuko Yaokawa

Article

Two dimensional forms of silicon offer different conductive properties to that of the bulk material, promising applications in new electronic technologies. Here, the authors report the fabrication of bilayer silicenes which, unlike their monolayer form, are indirect bandgap semiconductors.

Nature Communications doi: 10.1038/ncomms10657

Authors: Ritsuko Yaokawa, Tetsu Ohsuna, Tetsuya Morishita, Yuichiro Hayasaka, Michelle J. S. Spencer, Hideyuki Nakano

05 Feb 17:37

Interplay between Steps and Oxygen Vacancies on Curved TiO2(110)

by Luis A. Miccio, Martin Setvin, Moritz Müller, Mikel Abadía, Ignacio Piquero, Jorge Lobo-Checa, Frederik Schiller, Celia Rogero, Michael Schmid, Daniel Sánchez-Portal, Ulrike Diebold and J. Enrique Ortega

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Nano Letters
DOI: 10.1021/acs.nanolett.5b05286
04 Feb 22:27

[Working Life] Retire the letter of reference

by Rima Wilkes
Author: Rima Wilkes
04 Feb 22:18

[Report] Electrical switching of an antiferromagnet

by P. Wadley
Antiferromagnets are hard to control by external magnetic fields because of the alternating directions of magnetic moments on individual atoms and the resulting zero net magnetization. However, relativistic quantum mechanics allows for generating current-induced internal fields whose sign alternates with the periodicity of the antiferromagnetic lattice. Using these fields, which couple strongly to the antiferromagnetic order, we demonstrate room-temperature electrical switching between stable configurations in antiferromagnetic CuMnAs thin-film devices by applied current with magnitudes of order 106 ampere per square centimeter. Electrical writing is combined in our solid-state memory with electrical readout and the stored magnetic state is insensitive to and produces no external magnetic field perturbations, which illustrates the unique merits of antiferromagnets for spintronics. Authors: P. Wadley, B. Howells, J. Železný, C. Andrews, V. Hills, R. P. Campion, V. Novák, K. Olejník, F. Maccherozzi, S. S. Dhesi, S. Y. Martin, T. Wagner, J. Wunderlich, F. Freimuth, Y. Mokrousov, J. Kuneš, J. S. Chauhan, M. J. Grzybowski, A. W. Rushforth, K. W. Edmonds, B. L. Gallagher, T. Jungwirth
04 Feb 20:17

High-frequency magnetization dynamics of individual atomic-scale magnets

by S. Krause, A. Sonntag, J. Hermenau, J. Friedlein, and R. Wiesendanger

Author(s): S. Krause, A. Sonntag, J. Hermenau, J. Friedlein, and R. Wiesendanger

The magnetization dynamics of individual nanomagnets is studied by spin-polarized scanning tunneling microscopy, combining real-time telegraphic noise analysis with pump-probe schemes. A transition between two Arrhenius regimes is observed as a function of temperature. The switching rates at high te…


[Phys. Rev. B 93, 064407] Published Thu Feb 04, 2016

04 Feb 09:28

Absence of a spin-signature from a single Ho adatom as probed by spin-sensitive tunneling

by M. Steinbrecher

Article

Magnetic stability of holmium atoms on a platinum(111) surface has recently been reported, raising prospects for atomic-scale spintronics, however contradictory results have since emerged. Here, Steinbrecher et al. find evidence for an invisibility of the holmium spin to scanning tunnelling spectroscopy techniques which challenges recent results.

Nature Communications doi: 10.1038/ncomms10454

Authors: M. Steinbrecher, A. Sonntag, M. dos Santos Dias, M. Bouhassoune, S. Lounis, J. Wiebe, R. Wiesendanger, A. A. Khajetoorians

03 Feb 10:13

Non-Boolean computing with nanomagnets for computer vision applications

by Sanjukta Bhanja

Nature Nanotechnology 11, 177 (2016). doi:10.1038/nnano.2015.245

Authors: Sanjukta Bhanja, D. K. Karunaratne, Ravi Panchumarthy, Srinath Rajaram & Sudeep Sarkar

03 Feb 10:11

Towards a new scale

by Christian Martin

Nature Nanotechnology 11, 112 (2016). doi:10.1038/nnano.2016.8

Author: Christian Martin

Work on a new technology roadmap and an exceptional wave of consolidation hint at fundamental changes in the micro- and nanoelectronics industry, as Christian Martin explains.

02 Feb 14:25

2H-Tetrakis(3,5-di-tert-butyl)phenylporphyrin on a Cu(110) Surface: Room-Temperature Self-Metalation and Surface-Reconstruction-Facilitated Self-Assembly

by Liang Zhang, Michael Lepper, Michael Stark, Ralf Schuster, Dominik Lungerich, Norbert Jux, Hans-Peter Steinrück, Hubertus Marbach

Abstract

The adsorption behavior of 2H-tetrakis(3,5-di-tert-butyl)phenylporphyrin (2HTTBPP) on Cu(110) and Cu(110)–(2×1)O surfaces have been investigated by using variable-temperature scanning tunneling microscopy (STM) under ultrahigh vacuum conditions. On the bare Cu(110) surface, individual 2HTTBPP molecules are observed. These molecules are immobilized on the surface with a particular orientation with respect to the crystallographic directions of the Cu(110) surface and do not form supramolecular aggregates up to full monolayer coverage. In contrast, a chiral supramolecular structure is formed on the Cu(110)–(2×1)O surface, which is stabilized by van der Waals interactions between the tert-butyl groups of neighboring molecules. These findings are explained by weakened molecule–substrate interactions on the Cu(110)–(2×1)O surface relative to the bare Cu(110) surface. By comparison with the corresponding results of Cu–tetrakis(3,5-di-tert-butyl)phenylporphyrin (CuTTBPP) on Cu(110) and Cu(110)–(2×1)O surfaces, we find that the 2HTTBPP molecules can self-metalate on both surfaces with copper atoms from the substrate at room temperature (RT). The possible origins of the self-metalation reaction at RT are discussed. Finally, peculiar irreversible temperature-dependent switching of the intramolecular conformations of the investigated molecules on the Cu(110) surface was observed and interpreted.

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Role of the substrate: 2H-Tetrakis(3,5-di-tert-butyl)phenylporphyrin (2HTTBPP) molecules can self-metalate with copper atoms from the substrate on both Cu(110) and Cu(110)–(2×1)O surfaces at room temperature (RT; see figure). The (2×1) surface reconstruction of Cu(110) by oxygen atoms also significantly modifies the molecule–substrate interaction and facilitates the self-assembly of 2HTTBPP molecules at RT.

01 Feb 21:58

Growth Mechanism and Morphology of Hexagonal Boron Nitride

by Zhuhua Zhang, Yuanyue Liu, Yang Yang and Boris I. Yakobson

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Nano Letters
DOI: 10.1021/acs.nanolett.5b04874
30 Jan 15:55

Bottom-Up Synthesis of N = 13 Sulfur-Doped Graphene Nanoribbons

by Giang D. Nguyen, Francesca M. Toma, Ting Cao, Zahra Pedramrazi, Chen Chen, Daniel J. Rizzo, Trinity Joshi, Christopher Bronner, Yen-Chia Chen, Marco Favaro, Steven G. Louie, Felix R. Fischer and Michael F. Crommie

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The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.5b09986
29 Jan 10:01

Mussel-Directed Synthesis of Nitrogen-Doped Anatase TiO2

by Jingjing Xie, Hao Xie, Bao-Lian Su, Yi-bing Cheng, Xiaodong Du, Hui Zeng, Menghu Wang, Weimin Wang, Hao Wang, Zhengyi Fu

Abstract

Structure-forming processes leading to biominerals are well worth learning in pursuit of new synthetic techniques. Strategies that attempt to mimic nature in vitro cannot replace an entire complex natural organism, requiring ingenuity beyond chemists′ hands. A “bioprocess-inspired synthesis” is demonstrated for fabrication of N-doped TiO2 materials at ambient temperature by direct implantation of precursor into living mussels. The amorphous precursor transforms into N-doped anatase TiO2 with a hierarchical nanostructure. Synthetic TiO2 exhibits high phase stability and enhanced visible-light photocatalytic activity as a result of modifications to its band gap during in vivo mineralization. Intracellular proteins were found to be involved in TiO2 mineralization. Our findings may inspire material production by new synthetic techniques, especially under environmentally benign conditions.

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The pearl is the oyster′s autobiography: Based on a natural pearl culture process, hierarchically meso/macroporous nitrogen-doped TiO2 is obtained directly in living Cristaria plicata at ambient temperature, demonstrating enhanced visible-light photocatalytic activity in both chemical waste remediation and hydrogen generation. Intracellular proteins are found to be involved in the formation of TiO2.

29 Jan 10:00

Observing spin excitations in 3d transition-metal adatoms on Pt(111) with inelastic scanning tunneling spectroscopy: A first-principles perspective

by Benedikt Schweflinghaus, Manuel dos Santos Dias, and Samir Lounis

Author(s): Benedikt Schweflinghaus, Manuel dos Santos Dias, and Samir Lounis

Spin excitations in atomic-scale nanostructures have been investigated with inelastic scanning tunneling spectroscopy, sometimes with conflicting results. In this work, we present a theoretical viewpoint on a recent experimental controversy regarding the spin excitations of Co adatoms on Pt(111). Wh…


[Phys. Rev. B 93, 035451] Published Wed Jan 27, 2016

29 Jan 09:58

Magnetic ground state of an individual Fe2+ ion in strained semiconductor nanostructure

by T. Smoleński

Article

Iron Fe 2+ ions embedded in semiconductor matrix usually have zero magnetic moment in the ground state. Here, the authors show theoretically and experimentally that a nearly doubly degenerate magnetic ground state is produced when iron ions are subjected to strain in epitaxial quantum dots, suggesting they could be used in spintronics and solotronics.

Nature Communications doi: 10.1038/ncomms10484

Authors: T. Smoleński, T. Kazimierczuk, J. Kobak, M. Goryca, A. Golnik, P. Kossacki, W. Pacuski