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01 Jun 18:37

[ASAP] Reactivity Umpolung of the CN Bond in Quinoxaline Scaffold Enabling Direct Nucleophilic Attack of Alkyl Grignard Reagents at the N‑Terminus

by Yun Peng, Lailin Chen, Hanyang Bao, Bingwei Zhou, Huayue Wu, and Yunkui Liu

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Organic Letters
DOI: 10.1021/acs.orglett.2c01385
16 May 17:26

[ASAP] Kinetic Model for the Reduction of CuII Sites by NO + NH3 and Reoxidation of NH3‑Solvated CuI Sites by O2 and NO in Cu-SSZ-13

by Rohil Daya, Dylan Trandal, Unmesh Menon, Dhruba J. Deka, William P. Partridge, and Saurabh Y. Joshi

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ACS Catalysis
DOI: 10.1021/acscatal.2c01076
03 Nov 16:57

[ASAP] Radical SAM Enzyme Spore Photoproduct Lyase: Properties of the Ω Organometallic Intermediate and Identification of Stable Protein Radicals Formed during Substrate-Free Turnover

by Adrien Pagnier, Hao Yang, Richard J. Jodts, Christopher D. James, Eric M. Shepard, Stella Impano, William E. Broderick, Brian M. Hoffman, and Joan B. Broderick

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Journal of the American Chemical Society
DOI: 10.1021/jacs.0c08585
16 May 18:44

Hydrogen peroxide driven biocatalysis

Green Chem., 2019, 21,3232-3249
DOI: 10.1039/C9GC00633H, Critical Review
B. O. Burek, S. Bormann, F. Hollmann, J. Z. Bloh, D. Holtmann
Peroxyzymes – biocatalysts utilizing environmentally benign hydrogen peroxide as a co-substrate – are a promising class of enzymes catalyzing a variety of important C–H and CC oxidations. This review critically examines recent developments in this field and the opportunities for industrial applications.
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