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31 Oct 11:49

[ASAP] Controllable Density of Atomic Bromine in a Two-Dimensional Hydrogen Bond Network

by Jianchen Lu, Zilin Ruan, Yurou Guan, De-Liang Bao, Xiao Lin, Zhenliang Hao, Hui Zhang, Lingling Song, Cuixia Yan, Jinming Cai, Shixuan Du, Hong-Jun Gao

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The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.8b08964
31 Oct 11:48

[ASAP] Donor/Acceptor Concepts for Developing Efficient Suzuki Cross-Coupling Catalysts Using Graphene-Supported Ni, Cu, Fe, Pd, and Bimetallic Pd/Ni Clusters

by Y. Yang, A. C. Reber, S. E. Gilliland , III, C. E. Castano, B. F. Gupton, S. N. Khanna

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The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.8b07538
04 Jul 13:45

[ASAP] Electron-Beam Manipulation of Silicon Dopants in Graphene

by Mukesh Tripathi, Andreas Mittelberger, Nicholas A. Pike, Clemens Mangler, Jannik C. Meyer, Matthieu J. Verstraete, Jani Kotakoski, Toma Susi

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Nano Letters
DOI: 10.1021/acs.nanolett.8b02406
02 Jul 07:53

[ASAP] Adsorption and Activation of Methane on the (110) Surface of Rutile-type Metal Dioxides

by Yuta Tsuji, Kazunari Yoshizawa

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The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.8b03184
08 May 13:01

Optical properties of silicene, Si/Ag(111), and Si/Ag(110)

by C. Hogan, O. Pulci, P. Gori, F. Bechstedt, D. S. Martin, E. E. Barritt, A. Curcella, G. Prevot, and Y. Borensztein

Author(s): C. Hogan, O. Pulci, P. Gori, F. Bechstedt, D. S. Martin, E. E. Barritt, A. Curcella, G. Prevot, and Y. Borensztein

Silver is a popular choice of substrate for the growth of nanostructured 1D and 2D silicon – possibly silicenelike – layers. First-principles simulations and measurements of reflectance anisotropy and surface differential reflectivity spectroscopy are applied to the study of single monolayer Si/Ag(111) and Si/Ag(110) interfaces. The authors demonstrate the absence of structural and electronic properties of freestanding, graphenelike silicene, finding evidence for strong Si-Ag bonding in the Si/Ag(111) case and the formation of pentagonal nanoribbons on Si/Ag(110). Many-body effects in the optical response of silicene are found to cancel out.


[Phys. Rev. B 97, 195407] Published Mon May 07, 2018

04 May 07:54

Local modification of the surface state properties at dilute coverages: CO/Cu(111)

by Ch. Zaum, K. M. Meyer-auf-der-Heide, and K. Morgenstern

Author(s): Ch. Zaum, K. M. Meyer-auf-der-Heide, and K. Morgenstern

We follow the diffusion of CO molecules on Cu(111) by time-lapsed low-temperature scanning tunneling microscopy. The diffusivity of individual CO molecules oscillates with the distance to its nearest neighbor due to the long-range interaction mediated by the surface state electrons. The markedly dif...


[Phys. Rev. B 97, 155437] Published Mon Apr 30, 2018

04 May 07:53

Copper-catalyzed cross-coupling of aryl-, primary alkyl-, and secondary alkylboranes with heteroaryl bromides

Chem. Commun., 2018, 54,5381-5384
DOI: 10.1039/C8CC03145B, Communication
Allison M. Bergmann, Adam M. Oldham, Wei You, M. Kevin Brown
A method for the Cu-catalyzed cross-coupling of both aryl and alkylboranes with aryl bromides is described.
The content of this RSS Feed (c) The Royal Society of Chemistry
04 May 07:51

[ASAP] Inelastic H Atom Scattering from Ultrathin Aluminum Oxide Films Grown by Atomic Layer Deposition on Pt(111)

by Yvonne Dorenkamp, Christian Volkmann, Vladimir Roddatis, Sven Schneider, Alec M. Wodtke, Oliver Bünermann

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The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.8b02692
02 May 11:58

New perspectives for triplet-triplet annihilation based photon upconversion using all-organic energy donor & acceptor chromophores

Chem. Commun., 2018, 54,5809-5818
DOI: 10.1039/C8CC01553H, Feature Article
Manoj K. Manna, Siamak Shokri, Gary P. Wiederrecht, David J. Gosztola, A. Jean-Luc Ayitou
Tuning the structural complementarities of organic donor and accepter chromophores for photonic amplification.
The content of this RSS Feed (c) The Royal Society of Chemistry
02 May 11:58

Self-assembly and ring-opening metathesis polymerization of cyclic conjugated molecules on highly ordered pyrolytic graphite

Chem. Commun., 2018, 54,5546-5549
DOI: 10.1039/C8CC02224K, Communication
Shih-Ting Chiu, Hsin-Yu Chiang, Yen-Jen Lin, Yun-Yung Lu, Hirofumi Tanaka, Takuya Hosokai, Masaki Horie
We report the STM and AFM images of cyclophane trienes and their ROMP products, presenting unique surface morphologies on HOPG.
The content of this RSS Feed (c) The Royal Society of Chemistry
02 May 11:58

Copper-catalyzed selective radical-radical cross-coupling for C-S bond formation: an access to [small alpha]-alkylthionitriles

Chem. Commun., 2018, 54,5574-5577
DOI: 10.1039/C8CC02371A, Communication
Caihong Zheng, Fangling Lu, Hanwei Lu, Jie Xin, Yi Deng, Dali Yang, Shengchun Wang, Zhiliang Huang, Meng Gao, Aiwen Lei
Oxidative radical-radical cross-coupling: a new protocol for C-S bond formation was developed by selective cross-coupling between a thiyl radical and an isobutyronitrile radical.
The content of this RSS Feed (c) The Royal Society of Chemistry
30 Apr 11:54

[ASAP] Insulator-to-Metallic Spin-Filtering in 2D-Magnetic Tunnel Junctions Based on Hexagonal Boron Nitride

by Maëlis Piquemal-Banci, Regina Galceran, Florian Godel, Sabina Caneva, Marie-Blandine Martin, Robert S. Weatherup, Piran R. Kidambi, Karim Bouzehouane, Stephane Xavier, Abdelmadjid Anane, Frédéric Petroff, Albert Fert, Simon Mutien-Marie Dubois, Jean-Christophe Charlier, John Robertson, Stephan Hofmann, Bruno Dlubak, Pierre Seneor

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ACS Nano
DOI: 10.1021/acsnano.8b01354
05 Sep 11:03

Pronounced Environmental Effects on Injection Currents in EGaIn Tunneling Junctions Comprising Self-Assembled Monolayers

by Marco Carlotti, Maarten Degen, Yanxi Zhang and Ryan C. Chiechi

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The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.6b07089
05 Sep 11:01

Two-dimensional dual-pore covalent organic frameworks obtained from the combination of two D2h symmetrical building blocks

Chem. Commun., 2016, 52,11704-11707
DOI: 10.1039/C6CC06637B, Communication
Yuan Tian, Shun-Qi Xu, Cheng Qian, Zhong-Fu Pang, Guo-Fang Jiang, Xin Zhao
A strategy to construct covalent organic frameworks (COFs) bearing two different kinds of pores has been developed. The as-prepared dual-pore COFs exhibit good adsorption capacities for CO2 and H2.
The content of this RSS Feed (c) The Royal Society of Chemistry
31 Aug 14:48

Substrate-Independent Growth of Atomically Precise Chiral Graphene Nanoribbons

by Dimas G. de Oteyza, Aran García-Lekue, Manuel Vilas-Varela, Néstor Merino-Díez, Eduard Carbonell-Sanromà, Martina Corso, Guillaume Vasseur, Celia Rogero, Enrique Guitián, Jose Ignacio Pascual, J. Enrique Ortega, Yutaka Wakayama and Diego Peña

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ACS Nano
DOI: 10.1021/acsnano.6b05269
31 Aug 14:45

Dysprosium-carboxylate nanomeshes with tunable cavity size and assembly motif through ionic interactions

Chem. Commun., 2016, 52,11227-11230
DOI: 10.1039/C6CC04874A, Communication
B. Cirera, L. Dordevic, R. Otero, J. M. Gallego, D. Bonifazi, R. Miranda, D. Ecija
Tunability of cavity size and assembly motif of dysprosium-directed nanomeshes through ionic interactions.
The content of this RSS Feed (c) The Royal Society of Chemistry
31 Aug 14:44

Host-guest chemistry in two-dimensional supramolecular networks

Chem. Commun., 2016, 52,11465-11487
DOI: 10.1039/C6CC05256H, Feature Article
Joan Teyssandier, Steven De Feyter, Kunal S. Mali
In this feature article, we survey recent developments in host-guest chemistry studied in surface-adsorbed physisorbed supramolecular networks.
The content of this RSS Feed (c) The Royal Society of Chemistry
11 Jul 11:21

Probing Structure of Cross-Linked (1 × 2) Rutile TiO2(110): Adsorption of Trimethyl Acetic Acid

by Ke Zhu, Yaobiao Xia, Zhenrong Zhang and Kenneth Park

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The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.6b04875
11 Jul 11:19

Effects of quantum confinement on excited state properties of SrTiO_{3} from ab initio many-body perturbation theory

by Sebastian E. Reyes-Lillo, Tonatiuh Rangel, Fabien Bruneval, and Jeffrey B. Neaton

Author(s): Sebastian E. Reyes-Lillo, Tonatiuh Rangel, Fabien Bruneval, and Jeffrey B. Neaton

The Ruddlesden-Popper (RP) homologous series Srn+1TinO3n+1 provides a useful template for the study and control of the effects of dimensionality and quantum confinement on the excited state properties of the complex oxide SrTiO3. We use ab initio many-body perturbation theory within the GW approxima…


[Phys. Rev. B 94, 041107(R)] Published Fri Jul 08, 2016

15 Jun 23:16

Oxygen vacancies: The origin of n-type conductivity in ZnO

by Lishu Liu, Zengxia Mei, Aihua Tang, Alexander Azarov, Andrej Kuznetsov, Qi-Kun Xue, and Xiaolong Du

Author(s): Lishu Liu, Zengxia Mei, Aihua Tang, Alexander Azarov, Andrej Kuznetsov, Qi-Kun Xue, and Xiaolong Du

Oxygen vacancy (VO) is a common native point defect that plays crucial roles in determining the physical and chemical properties of metal oxides such as ZnO. However, fundamental understanding of VO is still very sparse. Specifically, whether VO is mainly responsible for the n-type conductivity in Z…


[Phys. Rev. B 93, 235305] Published Wed Jun 15, 2016

15 Jun 23:15

Energetic and Spatial Mapping of Resonant Electronic Excitations

by Andreas Krönlein, Jens Kügel, Konstantin A. Kokh, Oleg. E. Tereshchenko and Matthias Bode

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The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.6b05177
13 Jun 21:08

Ullmann coupling reaction of aryl chlorides on Au(111) using dosed Cu as a catalyst and the programmed growth of 2D covalent organic frameworks

Chem. Commun., 2016, 52,8726-8729
DOI: 10.1039/C6CC03137D, Communication
Ke Ji Shi, Xin Zhang, Chen Hui Shu, Deng Yuan Li, Xin Yan Wu, Pei Nian Liu
The efficiency of Ullmann reaction of aryl chlorides on an Au(111) surface has been substantially increased by using dosed Cu as a catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry
08 Jun 11:34

Charge transfer and electron-phonon coupling in monolayer FeSe on Nb-doped SrTiO_{3}

by Yuanjun Zhou and Andrew J. Millis

Author(s): Yuanjun Zhou and Andrew J. Millis

Monolayer films of FeSe grown on SrTiO3 substrates are electron doped relative to bulk and exhibit a significantly higher superconducting transition temperature. An interaction of electrons in the FeSe layer with SrTiO3 phonons has been suggested. We present density functional calculations and a mod…


[Phys. Rev. B 93, 224506] Published Mon Jun 06, 2016

06 Jun 17:14

High Temperature Ferromagnetism in a GdAg2 Monolayer

by M. Ormaza, L. Fernández, M. Ilyn, A. Magaña, B. Xu, M. J. Verstraete, M. Gastaldo, M. A. Valbuena, P. Gargiani, A. Mugarza, A. Ayuela, L. Vitali, M. Blanco-Rey, F. Schiller and J. E. Ortega

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Nano Letters
DOI: 10.1021/acs.nanolett.6b01197
03 Jun 09:49

Magnetic dipoles at topological defects in the Meissner state of a nanostructured superconductor

by Jun-Yi Ge, Vladimir N. Gladilin, Cun Xue, Jacques Tempere, Jozef T. Devreese, Joris Van de Vondel, Youhe Zhou, and Victor V. Moshchalkov

Author(s): Jun-Yi Ge, Vladimir N. Gladilin, Cun Xue, Jacques Tempere, Jozef T. Devreese, Joris Van de Vondel, Youhe Zhou, and Victor V. Moshchalkov

In a magnetic field, superconductivity is manifested by total magnetic field expulsion (Meissner effect) or by the penetration of integer multiples of the flux quantum Φ0. Here we present experimental results revealing magnetic dipoles formed by Meissner current flowing around artificially introduce…


[Phys. Rev. B 93, 224502] Published Thu Jun 02, 2016

02 Jun 13:25

Covalent functionalization and passivation of exfoliated black phosphorus via aryl diazonium chemistry

by Christopher R. Ryder

Nature Chemistry 8, 597 (2016). doi:10.1038/nchem.2505

Authors: Christopher R. Ryder, Joshua D. Wood, Spencer A. Wells, Yang Yang, Deep Jariwala, Tobin J. Marks, George C. Schatz & Mark C. Hersam

Few-layer black phosphorus (BP) is a promising semiconductor, but it is highly reactive and susceptible to ambient degradation. Covalent functionalization with aryl radicals has now been shown to significantly improve the stability of exfoliated BP, as well as the performance of BP-based electronic devices through a controllable p-type doping effect.

02 Jun 12:43

Tunable two-dimensional electron gas at the surface of thermoelectric material In_{4} Se_{3}

by K. Fukutani, T. Sato, P. V. Galiy, K. Sugawara, and T. Takahashi

Author(s): K. Fukutani, T. Sato, P. V. Galiy, K. Sugawara, and T. Takahashi

We report the discovery of two-dimensional electron gas (2DEG) at the surface of thermoelectric material In4Se3 by angle-resolved photoemission spectroscopy. The observed 2DEG exhibits a nearly isotropic band dispersion with a considerably small effective mass of m*=0.16 m0, and its carrier density …


[Phys. Rev. B 93, 205156] Published Tue May 31, 2016

20 May 16:26

Role of the Shockley State in Doping of Organic Molecule Monolayer

by Azzedine Bendounan and Sonia Aït-Ouazzou

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The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.6b00902
18 May 08:00

Magnetic Hysteresis in Er Trimers on Cu(111)

by Aparajita Singha, Fabio Donati, Christian Wäckerlin, Romana Baltic, Jan Dreiser, Marina Pivetta, Stefano Rusponi and Harald Brune

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Nano Letters
DOI: 10.1021/acs.nanolett.5b05214
12 May 15:39

Electron Interference in Ballistic Graphene Nanoconstrictions

by Jens Baringhaus, Mikkel Settnes, Johannes Aprojanz, Stephen R. Power, Antti-Pekka Jauho, and Christoph Tegenkamp

Author(s): Jens Baringhaus, Mikkel Settnes, Johannes Aprojanz, Stephen R. Power, Antti-Pekka Jauho, and Christoph Tegenkamp

We realize nanometer size constrictions in ballistic graphene nanoribbons grown on sidewalls of SiC mesa structures. The high quality of our devices allows the observation of a number of electronic quantum interference phenomena. The transmissions of Fabry-Perot-like resonances are probed by in situ


[Phys. Rev. Lett. 116, 186602] Published Thu May 05, 2016