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05 Feb 23:30

[ASAP] A Genetically Encoded Approach for Breaking Chromatin Symmetry

by Bradley J. Lukasak, Robert E. Thompson, Michelle M. Mitchener, Vanessa J. Feng, John D. Bagert, and Tom W. Muir

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ACS Central Science
DOI: 10.1021/acscentsci.1c01332
05 Feb 23:29

[ASAP] Versatile and Facile One-Pot Biosynthesis for Amides and Carboxylic Acids in E. coli by Engineering Auxin Pathways of Plant Microbiomes

by Navya Menon, Daniel Richmond, Mohammad Rejaur Rahman, and Binuraj R. K. Menon

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ACS Catalysis
DOI: 10.1021/acscatal.1c04901
05 Feb 23:29

[ASAP] Deciphering the Reaction Pathway of Mononuclear Iron Enzyme-Catalyzed N≡C Triple Bond Formation in Isocyanide Lipopeptide and Polyketide Biosynthesis

by Tzu-Yu Chen, Ziyang Zheng, Xuan Zhang, Jinfeng Chen, Lide Cha, Yijie Tang, Yisong Guo, Jiahai Zhou, Binju Wang, Hung-wen Liu, and Wei-chen Chang

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ACS Catalysis
DOI: 10.1021/acscatal.1c04869
05 Feb 23:27

[ASAP] Following Nature’s Footprint: Mimicking the High-Valent Heme-Oxo Mediated Indole Monooxygenation Reaction Landscape of Heme Enzymes

by Pritam Mondal, Shanuk Rajapakse, and Gayan B. Wijeratne

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Journal of the American Chemical Society
DOI: 10.1021/jacs.1c11068
05 Feb 23:26

[ASAP] In Vitro Selection of Foldamer-Like Macrocyclic Peptides Containing 2‑Aminobenzoic Acid and 3‑Aminothiophene-2-Carboxylic Acid

by Takayuki Katoh and Hiroaki Suga

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Journal of the American Chemical Society
DOI: 10.1021/jacs.1c12133
05 Feb 23:26

[ASAP] Metalloradical Activation of In Situ-Generated α‑Alkynyldiazomethanes for Asymmetric Radical Cyclopropanation of Alkenes

by Jing Ke, Wan-Chen Cindy Lee, Xiaoxu Wang, Yong Wang, Xin Wen, and X. Peter Zhang

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Journal of the American Chemical Society
DOI: 10.1021/jacs.1c13154
05 Feb 23:25

[ASAP] Thylakoid Membrane-Inspired Capsules with Fortified Cofactor Shuttling for Enzyme-Photocoupled Catalysis

by Yiying Sun, Jiafu Shi, Zhuo Wang, Han Wang, Shaohua Zhang, Yizhou Wu, Hongjian Wang, Shihao Li, and Zhongyi Jiang

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Journal of the American Chemical Society
DOI: 10.1021/jacs.1c12790
05 Feb 23:25

[ASAP] Enantioselective Synthesis of α‑Trifluoromethyl Amines via Biocatalytic N–H Bond Insertion with Acceptor-Acceptor Carbene Donors

by Donggeon Nam, Antonio Tinoco, Zhuofan Shen, Ronald D. Adukure, Gopeekrishnan Sreenilayam, Sagar D. Khare, and Rudi Fasan

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Journal of the American Chemical Society
DOI: 10.1021/jacs.1c10750
20 May 09:10

A Transition State Theory-influenced Model of Secondary Battery Cycle-life: Towards a Final Regularity Resembling Carnot-efficiency

A transition state theory-influenced approach on maximum battery cycle-life is outlined, arriving at an ideal model of general validity. The outcome may be understood further as a thermodynamic final regularity reminiscent of Carnot-efficiency. In contrast to the common perception which attributes in blanket fashion the causality of changes in cycle-life to the engineering of battery-specific tangibles, this model allows for a more differentiated picture: That changes to battery-specific tangibles may yield differences of several hundred or more cycles is here the result of them being enhanced by a comparatively long, natural constant-based, logarithmic lever. That way such changes can cause big differences though being comparatively small to the lever base value, which emerges as a quantity of natural constants, temperature(s) and relative capacity margins but independent of battery specific energy and applied power. These are findings suggesting a revision of the current empirics-biased consensus opinion about the matter.
16 Apr 11:36

Mapping the multi-step mechanism of a photoredox catalyzed atom-transfer radical polymerization reaction by direct observation of the reactive intermediates

Chem. Sci., 2020, 11,4475-4481
DOI: 10.1039/D0SC01194K, Edge Article
Open Access Open Access
Luke Lewis-Borrell, Mahima Sneha, Aditi Bhattacherjee, Ian P. Clark, Andrew J. Orr-Ewing
Short-lived intermediates are tracked in real-time by transient absorption spectroscopy during a multi-step photoredox catalysed polymerization reaction.
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