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11 Jul 09:44

[ASAP] Anomalous Temperature-Dependent Phonon Anharmonicity and Strain Engineering of Thermal Conductivity in β‑Ga2O3

by Ying Chen, Lei Peng, Yu Wu, Congcong Ma, Ao Wu, Hao Zhang, and Zhilai Fang

TOC Graphic

The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.3c02866
19 May 10:08

[ASAP] β,β-Directly Linked Porphyrin Rings: Synthesis, Photophysical Properties, and Fullerene Binding

by Qiang Chen, Amber L. Thompson, Kirsten E. Christensen, Peter N. Horton, Simon J. Coles, and Harry L. Anderson

TOC Graphic

Journal of the American Chemical Society
DOI: 10.1021/jacs.3c03549
25 Apr 14:02

Bionic Tactile‐Gustatory Receptor for Object Identification Based on All‐Polymer Electrochemical Transistor

by Guocai Liu, Wei Wen, Zhiyuan Zhao, Xin Huang, Yifan Li, Mingcong Qin, Zhichao Pan, Yunlong Guo, Yunqi Liu
Bionic Tactile-Gustatory Receptor for Object Identification Based on All-Polymer Electrochemical Transistor

Iontronic tactile-gustatory receptors are designed using all-polymer electrochemical transistors, such that a single device can accurately recognize various objects perceived by the human tactile and gustatory system. Additionally, by combining device design and microfabrication innovation, an unprecedented device density of 104 167 transistors cm−2 (yield of 97%) is realized, 1 to 5 orders higher than reported values.


Abstract

Human sensory receptors enable the real world to be perceived effortlessly. Hence, massive efforts have been devoted to the development of bionic receptors capable of identifying objects. Unfortunately, most of the existing devices are limited to single sensory emulation and are established on solid-state electronic technologies, which are incompatible with the biological reactions occurring in electrolyte media. Here, an iontronic tactile-gustatory receptor using an all-polymer electrochemical transistor (AECT) is presented. The sensor is biocompatible with the operation voltage of 0.1 V, which is 1 to 2 orders lower than those of reported values. By this study, one receptor is able to accurately recognize various objects perceived by the human tactile and gustatory system without complex circuitry. Additionally, to promote its further application, flexible AECT arrays with channel length of 2 µm and density of 104 167 transistors cm−2 (yield of 97%) are fabricated, 1 to 5 orders higher than those of related works. Finally, a flexible integrated network for electrocardiogram recording is successfully constructed. This study moves a step forward toward state-of-the-art bionic sensors.

19 Apr 14:38

Origin of intersystem crossing in highly distorted organic molecules: a case study with red light-absorbing N,N,O,O-boron-chelated Bodipys

Chem. Sci., 2023, 14,5014-5027
DOI: 10.1039/D3SC00854A, Edge Article
Open Access Open Access
Xue Zhang, Andrey A. Sukhanov, Xi Liu, Maria Taddei, Jianzhang Zhao, Anthony Harriman, Violeta K. Voronkova, Yan Wan, Bernhard Dick, Mariangela Di Donato
A twisted π-conjugated framework does not necessarily promote efficacious ISC, energy matching of S1/Tn excited states offers a more promising route to triplet enhancement.
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