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22 Jul 05:39

Enhanced water desalination efficiency in an air-cathode stacked microbial electrodeionization cell (SMEDIC)

Publication date: 1 November 2014
Source:Journal of Membrane Science, Volume 469
Author(s): Noura A. Shehab , Gary L. Amy , Bruce E. Logan , Pascal E. Saikaly
A microbial desalination cell was developed that contained a stack of membranes packed with ion exchange resins between the membranes to reduce ohmic resistances and improve performance. This new configuration, called a stacked microbial electro-deionization cell (SMEDIC), was compared to a control reactor (SMDC) lacking the resins. The SMEDIC+S reactors contained both a spacer and 1.4±0.2mL of ion exchange resin (IER) per membrane channel, while the spacer was omitted in the SMEDIC-S reactors and so a larger volume of resin (2.4±0.2mL) was used. The overall extent of desalination using the SMEDIC with a moderate (brackish water) salt concentration (13g/L) was 90–94%, compared to only 60% for the SMDC after 7 fed-batch cycles of the anode. At a higher (seawater) salt concentration of 35g/L, the extent of desalination reached 61–72% (after 10 cycles) for the SMEDIC, compared to 43% for the SMDC. The improved performance was shown to be due to the reduction in ohmic resistances, which were 130Ω (SMEDIC-S) and 180Ω (SMEDIC+S) at the high salt concentration, compared to 210Ω without resin (SMDC). These results show that IERs can improve performance of stacked membranes for both moderate and high initial salt concentrations.

17 Jul 12:08

NiS nanorod-assembled nanoflowers grown on graphene: morphology evolution and Li-ion storage applications

J. Mater. Chem. A, 2014, 2,15152-15158
DOI: 10.1039/C4TA03440F, Paper
Hua Geng, Shao Feng Kong, Yong Wang
The morphology, size and phase of NiS nanoflowers are tuned in the preparation of the NiS-graphene composite, which shows large reversible capacities at both low and high current rates for rechargeable Li-ion batteries.
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