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[ASAP] Roles of Iron Complexes in Catalytic Radical Alkene Cross-Coupling: A Computational and Mechanistic Study
Technology and Market Perspective for Indoor Photovoltaic Cells
Publication date: 19 June 2019
Source: Joule, Volume 3, Issue 6
Author(s): Ian Mathews, Sai Nithin Kantareddy, Tonio Buonassisi, Ian Marius Peters
Context & Scale
The Internet of Things (IoT) ecosystem promises large networks of connected devices collecting the big data upon which our medical, manufacturing, infrastructure, and energy industries will be monitored and optimized. Billions of wireless sensors are expected to be installed over the coming decade, with almost half to be located inside buildings. Currently, the use of batteries to power these devices places significant constraints on their power consumption, where the range and frequency of data transmission are curtailed to achieve sufficient battery life, and the range of applications is also limited to the ones that allow battery replacement. Additional operation and maintenance costs are also incurred by providing replacement batteries.
Indoor photovoltaics has the potential to solve these hardware issues, providing greater reliability and operational lifetimes in wireless sensor networks. Persistently powering individual nodes by harvesting ambient light using small ∼cm2 photovoltaic cells is becoming possible for more and more wireless technologies and devices. Characterizing IPV cells is a growing research field with the performance of a considerable number of different PV technologies having now been measured under ambient light sources. Given the interest in commercializing different photovoltaic cells in this growing market, we discuss here the outstanding research questions that must be answered by the indoor photovoltaic community to enable self-powered, indoor-located IoT nodes.
Summary
Indoor photovoltaic cells have the potential to power the Internet of Things ecosystem, including distributed and remote sensors, actuators, and communications devices. As the power required to operate these devices continues to decrease, the type and number of nodes that can now be persistently powered by indoor photovoltaic cells are rapidly growing. This will drive significant growth in the demand for indoor photovoltaics, creating a large alternative market for existing and novel photovoltaic technologies. With the re-emergence of interest in indoor photovoltaic cells, we provide an overview of this burgeoning field focusing on the technical challenges that remain to create energy autonomous sensors at viable price points and to overcome the commercial challenges for individual photovoltaic technologies to accelerate their market adoption.
Nitrogen-coordinated single iron atom catalysts derived from metal organic frameworks for oxygen reduction reaction
Publication date: July 2019
Source: Nano Energy, Volume 61
Author(s): Fei Xiao, Gui-Liang Xu, Cheng-Jun Sun, Mingjie Xu, Wen Wen, Qi Wang, Meng Gu, Shangqian Zhu, Yueying Li, Zidong Wei, Xiaoqing Pan, Jiangan Wang, Khalil Amine, Minhua Shao
Abstract
Iron and nitrogen co-doped carbon (Fe-N-C) catalysts hold great promise to replace platinum group metal used for the oxygen reduction reaction (ORR) in low-temperature fuel cells. However, general synthesis routes require tedious acid washing and extensive heat treatment, usually resulting in uncontrollable morphologies and undesirable compounds. In this work, a zeolitic imidazolate framework (ZIF-8) was employed as a self-template for one-pot synthesis of a Fe-N-C catalyst consisting of uniformly dispersed Fe single atoms. Atomically dispersed Fe atoms were well distributed along the edges of the porous carbon matrix. Each of the Fe atoms was coordinated with four N atoms in the plane and two O atoms in the axial direction. The optimized Fe-N-C catalyst showed excellent ORR activities with half-wave potentials of 0.81 and 0.90 V in acidic and alkaline solutions, respectively. The results may be important for the optimization of single-atom-based catalysts for various reactions.
Graphical abstract
Defect-rich and ultrathin N doped carbon nanosheets as advanced trifunctional metal-free electrocatalysts for the ORR, OER and HER
DOI: 10.1039/C8EE03276A, Paper
Defect-rich and ultrathin N doped carbon nanosheets exhibited low overpotentials and robust stability for simultaneous ORR, OER and HER.
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