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24 Feb 10:49

MoS2 atomic layers with artificial active edge sites as transparent counter electrodes for improved performance of dye-sensitized solar cells

Nanoscale, 2014, 6,5279-5283
DOI: 10.1039/C3NR05979K, Paper
Jing Zhang, Sina Najmaei, Hong Lin, Jun Lou
The performance of dye-sensitized solar cells with MoS2 counter electrodes could be significantly improved by creating active edge sites.
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24 Feb 10:49

Halide ion-mediated growth of single crystalline Fe nanoparticles

Nanoscale, 2014, 6,4852-4856
DOI: 10.1039/C4NR00193A, Paper
Sen Zhang, Guangming Jiang, Gabriel T. Filsinger, Liheng Wu, Huiyuan Zhu, Jonghun Lee, Zhongbiao Wu, Shouheng Sun
We report a facile halide ion (Cl- or Br-) mediated synthesis of Fe nanoparticles (NPs) by thermal decomposition of Fe(CO)5.
The content of this RSS Feed (c) The Royal Society of Chemistry
24 Feb 10:42

The Effects of the Size and the Doping Concentration on the Power Factor of n-type Lead Telluride Nanocrystals for Thermoelectric Energy Conversion

by Haiyu Fang, Zhiqiang Luo, Haoran Yang and Yue Wu

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Nano Letters
DOI: 10.1021/nl403677k
21 Feb 14:24

High performance photoelectrochemical hydrogen generation and solar cells with a double type II heterojunction

Phys. Chem. Chem. Phys., 2014, 16,7531-7537
DOI: 10.1039/C4CP00632A, Paper
Lai-Hung Lai, Widianta Gomulya, Loredana Protesescu, Maksym V. Kovalenko, Maria A. Loi
We report on the fabrication of CdSe quantum dot (QD) sensitized electrodes by direct adsorption of colloidal QDs on mesoporous TiO2 followed by 3-mercaptopropionic acid (MPA) ligand exchange.
The content of this RSS Feed (c) The Royal Society of Chemistry
21 Feb 11:15

First-principles Raman spectra of MoS2, WS2 and their heterostructures

Nanoscale, 2014, 6,5394-5401
DOI: 10.1039/C3NR06906K, Paper
Liangbo Liang, Vincent Meunier
Raman spectra of MoS2, WS2, and their heterostructures are studied by density functional theory.
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21 Feb 11:09

Growth of Large-Area 2D MoS2(1-x)Se2x Semiconductor Alloys

by Qingliang Feng, Yiming Zhu, Jinhua Hong, Mei Zhang, Wenjie Duan, Nannan Mao, Juanxia Wu, Hua Xu, Fengliang Dong, Fang Lin, Chuanhong Jin, Chunming Wang, Jin Zhang, Liming Xie
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Semiconducting MoS2(1-x)Se2x mono­layers where x = 0–0.40 are successfully grown over large areas. A random arrangement of the S and Se atoms and a tunable bandgap photoluminescence are observed. Atomically thin, 2D semiconductor alloys with tunable bandgaps have potential applications in nano- and opto-electronics. Field-effect transistors fabricated with the monolayers exhibit high on/off ratios of >105.

20 Feb 12:49

Charge-extraction strategies for colloidal quantum dot photovoltaics

by Xinzheng Lan

Nature Materials 13, 233 (2014). doi:10.1038/nmat3816

Authors: Xinzheng Lan, Silvia Masala & Edward H. Sargent

19 Feb 13:20

Two Dimensional Materials Beyond MoS2: Noble-Transition-Metal Dichalcogenides

by Pere Miró, Mahdi Ghorbani-Asl, Thomas Heine

Abstract

The structure and electronic structure of layered noble-transition-metal dichalcogenides MX2 (M=Pt and Pd, and chalcogenides X=S, Se, and Te) have been investigated by periodic density functional theory (DFT) calculations. The MS2 monolayers are indirect band-gap semiconductors whereas the MSe2 and MTe2 analogues show significantly smaller band gap and can even become semimetallic or metallic materials. Under mechanical strain these MX2 materials become quasi-direct band-gap semiconductors. The mechanical-deformation and electron-transport properties of these materials indicate their potential application in flexible nanoelectronics.

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Show you're metal: The structure and electronic structure of layered noble-transition-metal dichalcogenides MX2 with metals M (Pt and Pd) and chalcogenides X (S, Se, and Te) have been investigated with periodic density functional theory calculations. The MS2 monolayers are indirect band-gap semiconductors whereas the MSe2 and MTe2 analogues show a significant decrease in their band-gaps and can even become semimetallic or metallic materials.

18 Feb 13:15

Photoexcited carrier dynamics of double-layered CdS/CdSe quantum dot sensitized solar cells measured by heterodyne transient grating and transient absorption methods

Phys. Chem. Chem. Phys., 2014, 16,5774-5778
DOI: 10.1039/C3CP55177F, Paper
N. Osada, T. Oshima, S. Kuwahara, T. Toyoda, Q. Shen, K. Katayama
Charge carrier flow in CdS/CdSe double-layer quantum dot sensitized solar cell is clarified by the combination technique of transient grating and transient absorption methods.
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18 Feb 13:07

Band alignment by ternary crystalline potential-tuning interlayer for efficient electron injection in quantum dot-sensitized solar cells

J. Mater. Chem. A, 2014, 2,7004-7014
DOI: 10.1039/C3TA15435A, Paper
Zhenhua Chen, Wenqin Peng, Kun Zhang, Jing Zhang, Xudong Yang, Youhei Numata, Liyuan Han
A facile way to enhance electron injection efficiency of solar cells by interlayer CdS1-xSex quantum dots has been developed.
The content of this RSS Feed (c) The Royal Society of Chemistry
18 Feb 12:02

Composite ZnSe-CdSe Quantum Dot Sensitizers of Solid-State Solar Cells and the Beneficial Effect of Added Na2S

by Georgia Sfyri, Stavroula Sfaelou, Konstantinos S. Andrikopoulos, Nikolaos Balis, George A. Voyiatzis and Panagiotis Lianos

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The Journal of Physical Chemistry C
DOI: 10.1021/jp412134m
18 Feb 12:01

Effect of Different Face Centered Cubic Nanoparticle Distributions on Particle Size and Surface Area Determination: A Theoretical Study

by Giovanni Agostini, Andrea Piovano, Luca Bertinetti, Riccardo Pellegrini, Giuseppe Leofanti, Elena Groppo and Carlo Lamberti

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The Journal of Physical Chemistry C
DOI: 10.1021/jp4091014
18 Feb 11:36

Tailoring the Physical Properties of Molybdenum Disulfide Monolayers by Control of Interfacial Chemistry

by Sina Najmaei, Xiaolong Zou, Dequan Er, Junwen Li, Zehua Jin, Weilu Gao, Qi Zhang, Sooyoun Park, Liehui Ge, Sidong Lei, Junichiro Kono, Vivek B. Shenoy, Boris I. Yakobson, Antony George, Pulickel M. Ajayan and Jun Lou

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Nano Letters
DOI: 10.1021/nl404396p
11 Feb 17:58

Auger-Assisted Electron Transfer from Photoexcited Semiconductor Quantum Dots

by Haiming Zhu, Ye Yang, Kim Hyeon-Deuk, Marco Califano, Nianhui Song, Youwei Wang, Wenqing Zhang, Oleg V. Prezhdo and Tianquan Lian

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Nano Letters
DOI: 10.1021/nl4041687
11 Feb 15:30

Stacking effects on the electronic and optical properties of bilayer transition metal dichalcogenides MoS2, MoSe2, WS2, and WSe2

by Jiangang He, Kerstin Hummer, and Cesare Franchini

Author(s): Jiangang He, Kerstin Hummer, and Cesare Franchini

Employing the random phase approximation we investigate the binding energy and Van der Waals (vdW) interlayer spacing between the two layers of bilayer transition metal dichalcogenides MoS2, MoSe2, WS2, and WSe2 for five different stacking patterns, and examine the stacking-induced modifications on ...

[Phys. Rev. B 89, 075409] Published Mon Feb 10, 2014

11 Feb 11:37

Designing High-Performance PbS and PbSe Nanocrystal Electronic Devices through Stepwise, Post-Synthesis, Colloidal Atomic Layer Deposition

by Soong Ju Oh, Nathaniel E. Berry, Ji-Hyuk Choi, E. Ashley Gaulding, Hangfei Lin, Taejong Paik, Benjamin. T. Diroll, Shin Muramoto, Christopher B. Murray and Cherie R. Kagan

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Nano Letters
DOI: 10.1021/nl404818z
11 Feb 11:33

Experimental observation of exciton splitting and relaxation dynamics from PbS quantum dots in a glass matrix

by Fangyu Yue, Jens W. Tomm, and D. Kruschke

Author(s): Fangyu Yue, Jens W. Tomm, and D. Kruschke

Multiple optical transitions from PbS quantum dots (QDs) in glass matrix are observed. Energy separations between them amount up to ∼200 meV. Instead of being due to a size distribution of QDs, they are found to be related to a splitting of the lowest exciton levels. Systematic analysis of the relax...

[Phys. Rev. B 89, 081303] Published Mon Feb 10, 2014

10 Feb 11:23

Photovoltaics: The Complete In-Gap Electronic Structure of Colloidal Quantum Dot Solids and Its Correlation with Electronic Transport and Photovoltaic Performance (Adv. Mater. 6/2014)

by Khabiboulakh Katsiev, Alexander H. Ip, Armin Fischer, Iori Tanabe, Xin Zhang, Ahmad R. Kirmani, Oleksandr Voznyy, Lisa R. Rollny, Kang Wei Chou, Susanna M. Thon, Graham H. Carey, Xiaoyu Cui, Aram Amassian, Peter Dowben, Edward H. Sargent, Osman M. Bakr
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Surface defects, acting as traps for charge carriers, are a key factor limiting the performance of colloidal quantum dot (CQD) photovoltaics. Revealing the full electronic band structure of PbS CQD devices, subjected to the latest surface passivation treatments, enables a direct correlation of features in the band structure with device performance characteristics, as described by Osman M. Bakr and co-workers on page 937.

10 Feb 11:18

InP Quantum Dots: An Environmentally Friendly Material with Resonance Energy Transfer Requisites

by Anoop Thomas, Pratheesh V. Nair and K. George Thomas

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The Journal of Physical Chemistry C
DOI: 10.1021/jp500125v
07 Feb 11:02

Influence of the core size on biexciton quantum yield of giant CdSe/CdS nanocrystals

Nanoscale, 2014, 6,3712-3720
DOI: 10.1039/C3NR06558H, Paper
Benjamin D. Mangum, Siddharth Sampat, Yagnaseni Ghosh, Jennifer A. Hollingsworth, Han Htoon, Anton V. Malko
We show that core size is an effective tuning parameter for achieving high bi-exciton quantum yields in CdSe/CdS core/shell nanocrystals.
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07 Feb 10:54

Stimulated Emission and Lasing from CdSe/CdS/ZnS Core-Multi-Shell Quantum Dots by Simultaneous Three-Photon Absorption

by Yue Wang, Van Duong Ta, Yuan Gao, Ting Chao He, Rui Chen, Evren Mutlugun, Hilmi Volkan Demir, Han Dong Sun
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Three-photon pumped stimulated emission and coherent random lasing from colloidal CdSe/CdS/ZnS core–multishell quantum dots are achieved for the first time. These results can offer new possibilities in biology and photonics, as well as at their intersection of biophotonics.

07 Feb 10:47

Organolead Halide Perovskite: New Horizons in Solar Cell Research

by Hui-Seon Kim, Sang Hyuk Im and Nam-Gyu Park

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The Journal of Physical Chemistry C
DOI: 10.1021/jp409025w
07 Feb 10:36

Precise Control of Quantum Dot Location within the P3HT-b-P2VP/QD Nanowires Formed by Crystallization-Driven 1D Growth of Hybrid Dimeric Seeds

by Yong-Jae Kim, Chul-Hee Cho, Kwanyeol Paek, Mijung Jo, Mi-kyoung Park, Na-Eun Lee, Youn-joong Kim, Bumjoon J. Kim and Eunji Lee

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Journal of the American Chemical Society
DOI: 10.1021/ja410165f
07 Feb 10:29

Monolayer behaviour in bulk ReS2 due to electronic and vibrational decoupling

by Sefaattin Tongay

Article

Monolayers of transition metal dichalcogenides have emerged as interesting two-dimensional materials. Here, the authors show that in a new member of this family of compounds, rhenium disulphide, the layers in the bulk are vibrationally and electronically decoupled, so that they behave almost as monolayers.

Nature Communications doi: 10.1038/ncomms4252

Authors: Sefaattin Tongay, Hasan Sahin, Changhyun Ko, Alex Luce, Wen Fan, Kai Liu, Jian Zhou, Ying-Sheng Huang, Ching-Hwa Ho, Jinyuan Yan, D. Frank Ogletree, Shaul Aloni, Jie Ji, Shushen Li, Jingbo Li, F. M. Peeters, Junqiao Wu

05 Feb 12:30

Prolonging the lifetime of excited electrons of QDs by capping them with [small pi]-conjugated thiol ligands

J. Mater. Chem. C, 2014, 2,2939-2943
DOI: 10.1039/C3TC32523G, Paper
Jie Chang, Hongbo Xia, Suli Wu, Shufen Zhang
A new strategy is reported here to stabilize the excited electrons within QDs using-conjugated ligand. An electron delocalized field is formed by mixing the LUMO energy levels of [small pi]-conjugated ligand with conductive band-edge energy (Ecb) of CdTe QDs, which will supply the excited electron with a more stable environment.
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05 Feb 12:30

Correlation between surface state and band edge emission of white light ZnxCd1-xS nanocrystals

J. Mater. Chem. C, 2014, 2,2664-2667
DOI: 10.1039/C4TC00076E, Communication
Hong-Shuo Chen, Shu-Ru Chung, Tsan-Yao Chen, Kuan-Wen Wang
In this study, we have demonstrated a facile thermal pyrolyzed route to prepare ternary ZnxCd1-xS nanocrystals with high quantum yield and white light emission.
The content of this RSS Feed (c) The Royal Society of Chemistry
05 Feb 12:23

Thermoelectric alloys between PbSe and PbS with effective thermal conductivity reduction and high figure of merit

J. Mater. Chem. A, 2014, 2,3169-3174
DOI: 10.1039/C3TA14929C, Paper
Heng Wang, Jianli Wang, Xianlong Cao, G. Jeffrey Snyder
The n-type alloys between PbSe and PbS behave as solid solutions. zT values of these alloys are high but not better than the binary PbSe.
The content of this RSS Feed (c) The Royal Society of Chemistry
05 Feb 12:13

Effect of Pressure and Temperature on Structural Stability of MoS2

by Nirup Bandaru, Ravhi S. Kumar, Daniel Sneed, Oliver Tschauner, Jason Baker, Daniel Antonio, Sheng-Nian Luo, Thomas Hartmann, Yusheng Zhao and Rama Venkat

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The Journal of Physical Chemistry C
DOI: 10.1021/jp410167k
05 Feb 10:46

Investigation of Indium Phosphide Quantum Dot Nucleation and Growth Utilizing Triarylsilylphosphine Precursors

by Dylan C. Gary, Benjamin A. Glassy and Brandi M. Cossairt

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Chemistry of Materials
DOI: 10.1021/cm500102q
04 Feb 11:59

Ultrafast Charge- and Energy-Transfer Dynamics in Conjugated Polymer: Cadmium Selenide Nanocrystal Blends

by Frederik S. F. Morgenstern, Akshay Rao, Marcus L. Böhm, René J. P. Kist, Yana Vaynzof and Neil C. Greenham

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ACS Nano
DOI: 10.1021/nn405978f