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03 Feb 17:06

Second harmonic generation in h-BN and MoS2 monolayers: Role of electron-hole interaction

by M. Grüning and C. Attaccalite

Author(s): M. Grüning and C. Attaccalite

We study second harmonic generation in h-BN and MoS2 monolayers using an ab initio approach based on many-body theory. We show that electron-hole interaction doubles the signal intensity at the excitonic resonances with respect to the contribution from independent electronic transitions. This implie...

[Phys. Rev. B 89, 081102] Published Mon Feb 03, 2014

03 Feb 11:23

Lattice vibrational modes and phonon thermal conductivity of monolayer MoS2

by Yongqing Cai, Jinghua Lan, Gang Zhang, and Yong-Wei Zhang

Author(s): Yongqing Cai, Jinghua Lan, Gang Zhang, and Yong-Wei Zhang

The anharmonic behavior of phonons and intrinsic thermal conductivity associated with the umklapp scattering in monolayer MoS2 sheet are investigated via first-principles calculations within the framework of density functional perturbation theory. In contrast to the negative Grüneissen parameter (γ)...

[Phys. Rev. B 89, 035438] Published Fri Jan 31, 2014

03 Feb 11:23

Electron-hole spin flip-flop in semiconductor quantum dots

by Y. Benny, R. Presman, Y. Kodriano, E. Poem, D. Gershoni, T. A. Truong, and P. M. Petroff

Author(s): Y. Benny, R. Presman, Y. Kodriano, E. Poem, D. Gershoni, T. A. Truong, and P. M. Petroff

We use temporally resolved intensity cross-correlation measurements to identify the biexciton-exciton radiative cascades in a negatively charged QD. The polarization sensitive correlation measurements show unambiguously that the excited two-electron triplet states relax nonradiatively to their singl...

[Phys. Rev. B 89, 035316] Published Fri Jan 31, 2014

31 Jan 16:51

Nodal ground states and orbital textures in semiconductor quantum dots

by Jeongsu Lee, Karel Výborný, Jong E. Han, and Igor Žutić

Author(s): Jeongsu Lee, Karel Výborný, Jong E. Han, and Igor Žutić

Conventional understanding implies that the ground state of a nonmagnetic quantum mechanical system should be nodeless. While this notion also provides a valuable guidance in understanding the ordering of energy levels in semiconductor nanostructures, there are reports that nodal ground states for h...

[Phys. Rev. B 89, 045315] Published Fri Jan 31, 2014

31 Jan 12:06

Sodium Assisted Sintering of Chalcogenides and Its Application to Solution Processed Cu2ZnSn(S,Se)4 Thin Film Solar Cells

by Carolin M. Sutter-Fella, Josua A. Stückelberger, Harald Hagendorfer, Fabio La Mattina, Lukas Kranz, Shiro Nishiwaki, Alexander R. Uhl, Yaroslav E. Romanyuk and Ayodhya N. Tiwari

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Chemistry of Materials
DOI: 10.1021/cm403504u
31 Jan 11:59

Kinetic analysis of the temperature dependence of PbSe colloidal quantum dot photoluminescence: Effects of synthesis process and oxygen exposure

by Charles A. Foell, Keith A. Abel, Frank C. J. M. van Veggel, and Jeff F. Young

Author(s): Charles A. Foell, Keith A. Abel, Frank C. J. M. van Veggel, and Jeff F. Young

A kinetic model is derived and used to analyze recently published works and new data on the temperature dependence of the spectrally integrated photoluminescence (PL) from thick-film formulations of PbSe colloidal quantum dots (QDs), with particular attention to the effects of air exposure. The mode...

[Phys. Rev. B 89, 045139] Published Wed Jan 29, 2014

30 Jan 12:32

MoS2/MX2 heterobilayers: bandgap engineering via tensile strain or external electrical field

Nanoscale, 2014, 6,2879-2886
DOI: 10.1039/C3NR06072A, Paper
Ning Lu, Hongyan Guo, Lei Li, Jun Dai, Lu Wang, Wai-Ning Mei, Xiaojun Wu, Xiao Cheng Zeng
We have performed a comprehensive first-principles study of the electronic and magnetic properties of two-dimensional (2D) transition-metal dichalcogenide (TMD) heterobilayers MX2/MoS2 (M = Mo, Cr, W, Fe, V; X = S, Se).
The content of this RSS Feed (c) The Royal Society of Chemistry
30 Jan 12:28

Effect of Structural Dynamics on the Opto-Electronic Properties of Bare and Hydrated ZnS QDs

by Jon M. Azpiroz, Edoardo Mosconi, Jesus M. Ugalde and Filippo De Angelis

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The Journal of Physical Chemistry C
DOI: 10.1021/jp409182r
30 Jan 11:27

Direct Quantitative Electrical Measurement of Many-Body Interactions in Exciton Complexes in InAs Quantum Dots

by P. A. Labud, A. Ludwig, A. D. Wieck, G. Bester, and D. Reuter

Author(s): P. A. Labud, A. Ludwig, A. D. Wieck, G. Bester, and D. Reuter

We present capacitance-voltage spectra for the conduction band states of InAs quantum dots obtained under continuous illumination. The illumination leads to the appearance of additional charging peaks that we attribute to the charging of electrons into quantum dots containing a variable number of il...

[Phys. Rev. Lett. 112, 046803] Published Wed Jan 29, 2014

29 Jan 17:04

Ultra-small fluorescent inorganic nanoparticles for bioimaging

J. Mater. Chem. B, 2014, 2,2793-2818
DOI: 10.1039/C3TB21760D, Feature Article
Zhen Li, Qiao Sun, Yian Zhu, Bien Tan, Zhi Ping Xu, Shi Xue Dou
The recent advances of ultra-small fluorescence inorganic nanoparticles including quantum dots, metal nanoclusters, carbon and graphene dots, up-conversion nanocrystals, and silicon nanoparticles have been comprehensively reviewed.
The content of this RSS Feed (c) The Royal Society of Chemistry
29 Jan 14:58

Synthesis and properties of ZnTe and ZnTe/ZnS core/shell semiconductor nanocrystals

J. Mater. Chem. C, 2014, 2,2877-2886
DOI: 10.1039/C3TC32385D, Paper
Christophe Lincheneau, Matteo Amelia, Marek Oszajca, Alice Boccia, Fabio D'Orazi, Mattia Madrigale, Robertino Zanoni, Raffaello Mazzaro, Luca Ortolani, Vittorio Morandi, Serena Silvi, Konrad Szacilowski, Alberto Credi
Nanocrystals obtained by growing a protecting ZnS shell onto a photoactive ZnTe core afford nanocrystals that can represent alternatives to cadmium-based quantum dots.
The content of this RSS Feed (c) The Royal Society of Chemistry
29 Jan 12:49

Deterministic Nucleation of InP on Metal Foils with the Thin-Film Vapor–Liquid–Solid Growth Mode

by Rehan Kapadia, Zhibin Yu, Mark Hettick, Jingsan Xu, Maxwell S. Zheng, Cheng-Ying Chen, Arunima D. Balan, Daryl C. Chrzan and Ali Javey

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Chemistry of Materials
DOI: 10.1021/cm403403v
28 Jan 11:04

Carrier and Polarization Dynamics in Monolayer MoS2

by D. Lagarde, L. Bouet, X. Marie, C. R. Zhu, B. L. Liu, T. Amand, P. H. Tan, and B. Urbaszek

Author(s): D. Lagarde, L. Bouet, X. Marie, C. R. Zhu, B. L. Liu, T. Amand, P. H. Tan, and B. Urbaszek

In monolayer MoS2, optical transitions across the direct band gap are governed by chiral selection rules, allowing optical valley initialization. In time-resolved photoluminescence (PL) experiments, we find that both the polarization and emission dynamics do not change from 4 to 300 K within our tim...

[Phys. Rev. Lett. 112, 047401] Published Mon Jan 27, 2014

28 Jan 11:01

Type-II band alignment of zinc-blende and wurtzite segments in GaAs nanowires: A combined photoluminescence and resonant Raman scattering study

by Patryk Kusch, Eugen Grelich, Claudio Somaschini, Esperanza Luna, Manfred Ramsteiner, Lutz Geelhaar, Henning Riechert, and Stephanie Reich

Author(s): Patryk Kusch, Eugen Grelich, Claudio Somaschini, Esperanza Luna, Manfred Ramsteiner, Lutz Geelhaar, Henning Riechert, and Stephanie Reich

We used spatially resolved photoluminescence (PL) and resonant Raman spectroscopy to study the electronic structure of single GaAs nanowires (NWs) consisting of zinc-blende (ZB) and wurtzite (WZ) segments. For narrow ZB segments and stacking faults the energy range of the observed PL peak positions ...

[Phys. Rev. B 89, 045310] Published Mon Jan 27, 2014

24 Jan 11:11

Spectroscopic and electronic structure properties of CdSe nanocrystals: spheres and cubes

Phys. Chem. Chem. Phys., 2014, 16,7555-7561
DOI: 10.1039/C3CP55314K, Paper
Vitaly Proshchenko, Yuri Dahnovsky
The optical and energy spectra for CdmSem clusters of various sizes and shapes are studied computationally. Higher level methods than DFT are used for electronic structure calculations, and the results obtained are compared with DFT calculations and available experimental data.
The content of this RSS Feed (c) The Royal Society of Chemistry
24 Jan 11:09

Photoluminescence of Mid-Infrared HgTe Colloidal Quantum Dots

by Sean Keuleyan, John Kohler and Philippe Guyot-Sionnest

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The Journal of Physical Chemistry C
DOI: 10.1021/jp409061g
23 Jan 11:33

Ultrafast Spectroscopy of CdSe Nanocrystals: Morphological and Environmental Effects on Nonradiative and Nonadiabatic Relaxation

by Bryan T. Spann and Xianfan Xu

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The Journal of Physical Chemistry C
DOI: 10.1021/jp4112553
23 Jan 11:32

On the Dual Roles of Ligands in the Synthesis of Colloidal Metal Nanostructures

by Nancy Ortiz and Sara E. Skrabalak

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Langmuir
DOI: 10.1021/la404539p
21 Jan 16:17

Assembly of Multivalent Protein Ligands and Quantum Dots: A Multifaceted Investigation

by Jianpeng Wang, Yunyu Nie, Yao Lu, Jiahui Liu, Jianhao Wang, Aisi Fu, Tiangang Liu and Jiang Xia

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Langmuir
DOI: 10.1021/la403156h
21 Jan 14:15

Nondestructive Monitoring of Defect Evolution in Epitaxial CdTe Thin Layers Grown on Si(111)

by J. M. Oliveira, A. Malachias, C. A. Ospina and S. O. Ferreira

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The Journal of Physical Chemistry C
DOI: 10.1021/jp409538p
21 Jan 14:14

Semiconductor Nanocrystals as Luminescent Down-Shifting Layers To Enhance the Efficiency of Thin-Film CdTe/CdS and Crystalline Si Solar Cells

by Sergii Kalytchuk, Shuchi Gupta, Olga Zhovtiuk, Aleksandar Vaneski, Stephen V. Kershaw, Huiying Fu, Zhiyong Fan, Eric C. H. Kwok, Chiou-Fu Wang, Wey Yang Teoh and Andrey L. Rogach

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The Journal of Physical Chemistry C
DOI: 10.1021/jp410279z
21 Jan 14:14

Exploration of Nanostructured Functional Materials Based on Hybridization of Inorganic 2D Nanosheets

by Jayavant L. Gunjakar, In Young Kim, Jang Mee Lee, Yun Kyung Jo and Seong-Ju Hwang

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The Journal of Physical Chemistry C
DOI: 10.1021/jp410626y
20 Jan 13:31

[Report] Atomic-Scale Variability and Control of III-V Nanowire Growth Kinetics

by Y.-C. Chou
Fluctuations and defects in III-V nanowire growth can be avoided by growing at a low V/III ratio. Authors: Y.-C. Chou, K. Hillerich, J. Tersoff, M. C. Reuter, K. A. Dick, F. M. Ross
20 Jan 13:28

Two-Color Single-Photon Emission from InAs Quantum Dots: Toward Logic Information Management Using Quantum Light

by David Rivas, Guillermo Muñoz-Matutano, Josep Canet-Ferrer, Raúl García-Calzada, Giovanna Trevisi, Luca Seravalli, Paola Frigeri and Juan P. Martínez-Pastor

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Nano Letters
DOI: 10.1021/nl403364h
17 Jan 12:57

Chemical Vapor Deposition: Stable Dropwise Condensation for Enhancing Heat Transfer via the Initiated Chemical Vapor Deposition (iCVD) of Grafted Polymer Films (Adv. Mater. 3/2014)

by Adam T. Paxson, Jose L. Yagüe, Karen K. Gleason, Kripa K. Varanasi
Thumbnail image of graphical abstract

Steam condenses onto a hydrophobic grafted copoly mer film to form discrete condensate drops, leading to a seven-fold increase in heat transfer coefficient over a typical hydrophilic metal surface. Most hydrophobic modifiers quickly degrade in the presence of steam, but this covalently bonded crosslinked fluoropolymer withstands an accelerated endurance test with no change in performance, as described by Kripa K. Varanasi, Karen K. Gleason and co-workers on page 418.

16 Jan 17:35

Effect of the Core/Shell Interface on Auger Recombination Evaluated by Single-Quantum-Dot Spectroscopy

by Young-Shin Park, Wan Ki Bae, Lazaro A. Padilha, Jeffrey M. Pietryga and Victor I. Klimov

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Nano Letters
DOI: 10.1021/nl403289w
16 Jan 17:11

Topological confinement in trilayer graphene

by S. H. R. de Sena, J. M. Pereira, Jr., F. M. Peeters, and G. A. Farias

Author(s): S. H. R. de Sena, J. M. Pereira, Jr., F. M. Peeters, and G. A. Farias

We calculate the spectrum of states that are localized at the interface between two regions of opposite bias in trilayer graphene (TLG). These potential profiles, also known as potential kinks, have been predicted to support two different branches of localized states for the case of bilayer graphene...

[Phys. Rev. B 89, 035420] Published Thu Jan 16, 2014

16 Jan 11:59

Physics: Why penguins do the wave

Physics: Why penguins do the wave

Nature 505, 7483 (2014). doi:10.1038/505265e

Highly read on iopscience.iop.org 9 Dec–8 JanPhysicists have explained how waves of coordinated motion sweep through huddles of male emperor penguins (Aptenodytes forsteri; pictured) as they try to keep warm while incubating eggs in the Antarctic.Daniel Zitterbart and Richard Gerum

13 Jan 11:57

4D Imaging and Diffraction Dynamics of Single-Particle Phase Transition in Heterogeneous Ensembles

by Haihua Liu, Oh-Hoon Kwon, Jau Tang and Ahmed H. Zewail

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Nano Letters
DOI: 10.1021/nl404354g
13 Jan 11:53

Blinking suppression and biexcitonic emission in thick-shell CdSe/CdS nanocrystals at cryogenic temperature

by D. Canneson, L. Biadala, S. Buil, X. Quélin, C. Javaux, B. Dubertret, and J.-P. Hermier

Author(s): D. Canneson, L. Biadala, S. Buil, X. Quélin, C. Javaux, B. Dubertret, and J.-P. Hermier

The fluorescence of single colloidal thick-shell CdSe/CdS nanocrystals (NCs), at cryogenic temperature (4 K) and room temperature (RT), is studied using the intensity autocorrelation function (ACF) and lifetime measurements. The radiative and Auger decay rates corresponding to the desexcitation of t...

[Phys. Rev. B 89, 035303] Published Thu Jan 09, 2014