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[ASAP] Aqueous Polymeric Hollow Particles as an Opacifier by Emulsion Polymerization Using Macro-RAFT Amphiphiles
yang涂料
Scalable and durable polymeric icephobic and hydrate-phobic coatings
yang抗冰超疏水界面大规模制备
DOI: 10.1039/C8SM00225H, Paper
Examination of polymeric icephobic and hydrate-phobic coatings by multiple adhesion/de-adhesion cycles and sand erosion tests.
The content of this RSS Feed (c) The Royal Society of Chemistry
Hot-Pressing Method To Prepare Imidazole-Based Zn(II) Metal–Organic Complexes Coatings for Highly Efficient Air Filtration
yang空气净化
Dual Superlyophobic Copper Foam with Good Durability and Recyclability for High Flux, High Efficiency, and Continuous Oil–Water Separation
yang泡沫铜 油水分离
[ASAP] Porous PVdF/GO Nanofibrous Membranes for Selective Separation and Recycling of Charged Organic Dyes from Water
yang多孔模除染料
[ASAP] Novel Multicharge Hydroacid Complexes That Effectively Remove Heavy Metal Ions from Water in Forward Osmosis Processes
yang重金属离子移出
[ASAP] Iron Mesh-Based Metal Organic Framework Filter for Efficient Arsenic Removal
yang膜除砷
Enrichment of trace rare earth elements from the leaching liquor of ion-absorption minerals using a solid complex centrifugal separation process
yang固体复合离心分离富集离子吸收矿物浸出液中痕量稀土元素
DOI: 10.1039/C7GC03674D, Paper
A novel solid complex centrifugal separation (SCCS) process has been developed to enrich trace rare earth (RE) elements from the leaching liquor of ion-absorption RE minerals.
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Changes in Dissolved Organic Matter Composition and Disinfection Byproduct Precursors in Advanced Drinking Water Treatment Processes
yang河水处理到饮用水
Significantly Enhancing Cu(II) Adsorption onto Zr-MOFs through Novel Cross-Flow Disturbance of Ceramic Membrane
yang二价铜离子吸附
Facile synthesis of magnetic Fe3O4@BiOI@AgI for water decontamination with visible light irradiation: Different mechanisms for different organic pollutants degradation and bacterial disinfection
yang可见光催化有机物降解
Source:Water Research, Volume 137
Author(s): Jialiang Liang, Fuyang Liu, Mian Li, Wen Liu, Meiping Tong
Magnetic Fe3O4@BiOI@AgI (FBA) spheres were synthesized through a multi-step process. The fabricated photocatalysts were characterized by different techniques. To testify the visible light driven photocatalytic activity of FBA, Rhodamine B and Bisphenol A were chosen as model common and emerging organic contaminants, respectively. While, gram-negative strain Escherichia coli was selected as model waterborne bacteria. The results showed that under visible light irradiation, FBA contained strong photocatalytic degradation capacity towards both RhB and BPA. Moreover, FBA was also found to exhibit excellent disinfection activity towards E. coli. The photocatalytic mechanisms for different pollutants by FBA were determined and found to vary for different pollutants. Specifically, scavenger experiments, degradation intermediates determination, as well as theoretical density functional theory (DFT) analysis showed that RhB and BPA were degraded via photosensitization (dominated by e - and ·O2 −) and direct photocatalytic oxidation (contributed by h +, e - and ·O2 −), respectively. Whereas, E. coli cells yet were found to be inactivated by the generation of e - and ·O2 − rather than by the released Ag+. Since it contained superparamagnetic property, FBA could be easily separated from the reaction suspension after use. Due to the excellent photo stability, FBA exhibited strong photocatalytic activity in the fourth reused recycle. Therefore, FBA could serve as a promising alternative for water purification.
Graphical abstract
A versatile CeO2/Co3O4 coated mesh for food wastewater treatment: Simultaneous oil removal and UV catalysis of food additives
yang餐饮废水处理膜
Source:Water Research, Volume 137
Author(s): Ya'nan Liu, Na Liu, Yuning Chen, Weifeng Zhang, Ruixiang Qu, Qingdong Zhang, Tzungyu-Shih, Lin Feng, Yen Wei
Food waste water is one of the most urgent environmental problems for the close connection between food and our daily life. Herein, we use a simple hydrothermal method to prepare a highly efficient catalyst—CeO2/Co3O4 compound on the stainless steel mesh, aiming for food waste water treatment. Possessing the superhydrophilic property and catalytic ability under ultraviolet light, CeO2/Co3O4 coated mesh has successfully processed three representative contaminants in food wastewater, which are soybean oil (food oil), AR (food dye) and VA (food flavor) simultaneously with an one-step filtration. Besides, the mesh is stable in a wide pH range and performs well in reusability. Therefore, such a multifunctional material with simple preparation method, high processing efficiency and facile operation shows a promising prospect for practical production and application for food wastewater treatment.
Graphical abstract
Insights on Carbonaceous Materials Tailoring for Effective Removal of the Anticancer Drug 5-Fluorouracil from Contaminated Waters
yang碳质材料吸附水中抗癌药5-氟尿嘧啶
Facile fabrication of hydrogel coated membrane for controllable and selective oil-in-water emulsion separation
yang油水乳液分离
DOI: 10.1039/C8SM00139A, Paper
For the first time, we report that the hydrogel-networks coated membrane exhibits selective separation for cationic and nonionic types of surfactants-stabilized emulsions.
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Study on the oxygen pressure alkaline leaching of gold with generated thiosulfate from sulfur oxidation
yang硫代硫酸钠浸出低消耗
Source:Hydrometallurgy, Volume 177
Author(s): Bin Xu, Ke Li, Qiang Zhong, Qian Li, Yongbin Yang, Tao Jiang
Thiosulfate leaching is a promising alternative to cyanidation, but high thiosulfate consumption has restricted its wide commercial application. In this study, the simultaneous gold extraction by generated thiosulfate deriving from the oxidation of added sulfur during oxygen pressure alkaline leaching (OPAL) without cupric-ammonia catalysis was investigated, and the results were encouraging. It has been proven that the sulfur can be produced from the oxidation pretreatment of sulfide gold ores or concentrates. Thus, this study provides an enlightenment to solve the problem of high thiosulfate consumption by a two-step process consisting of an appropriate oxidation pretreatment for sulfide gold ores or concentrates and OPAL. The gold extraction from an ore and terminal thiosulfate concentration after the OPAL in this study reached 78.0% and 0.28 M, respectively, and they were further improved to 83.6% and 0.31 M by the addition of humic acid (HA). The function of HA was proposed that it not only prevented passivation species from coating gold surface but also weakened the decomposition of generated thiosulfate. It can also be concluded that the improvement of temperature and oxygen partial pressure can substitute the cupric-ammonia catalysis for thiosulfate leaching.
Exploration of Ultralight Nanofiber Aerogels as Particle Filters: Capacity and Efficiency
yang超轻纳米纤维气凝胶颗粒过滤器
High-Flux Imine-Linked Covalent Organic Framework COF-LZU1 Membranes on Tubular Alumina Supports for Highly Selective Dye Separation by Nanofiltration
yang水中有机污染物清除
Covalent organic frameworks (COFs) with high porosity and well-organized channel structure are attractive candidates for advanced water treatment membranes. In their Communication (DOI: 10.1002/anie.201712816) H. Meng, J. Caro et al. present a two-dimensional imine-linked COF-LZU1 membrane with a thickness of only 400 nm supported on alumina tubes synthesized by an in situ solvothermal method. The membrane exhibits excellent water permeance and high rejection combined with outstanding water stability for water-soluble dyes with a size larger than 1.2 nm.
Fabrication of ultrathin multilayered superomniphobic nanocoatings by liquid flame spray, atomic layer deposition, and silanization
yang超双疏图层
Remarkably efficient adsorbent for the removal of bisphenol A from water: Bio-MOF-1-derived porous carbon
Source:Chemical Engineering Journal, Volume 343
Author(s): Biswa Nath Bhadra, Jungkyu K. Lee, Chang-Woo Cho, Sung Hwa Jhung
Bio-MOF-1, Zn8(adenine)4(biphenyldicarboxylate)6O, was synthesized and used as a precursor for the first time in order to fabricate porous carbons by carbonization of the MOF. The characterization of Bio-MOF-1-derived carbons (BMDCs) revealed that the BMDCs are highly porous carbons (O- and N-doped, with a high degree of graphitization), which might be attractive materials for the study of adsorption. BMDCs, together with a commercial activated carbon (AC), were applied for the adsorption of bisphenol A (BPA), a typical endocrine-disrupting compound, from water. The BMDC-12h adsorbent showed an efficiency ∼5-times (in terms of q 12h, the adsorbed quantity at 12 h) of that of a commercial AC in BPA capture. More importantly, BMDC-12h exhibited the best performance for BPA uptake among the reported adsorbents so far. H-bonding is anticipated as the principal mechanism based on the functional groups present in BPA and those produced on BMDC-12h and the effect of solution pH on the BPA adsorption capacities. Moreover, BMDC-12h can be recycled by simple solvent washing and effectively used in subsequent cycles with negligible loss of performance. Therefore, BMDCs, particularly BMDC-12h, were suggested as remarkably efficient and easily recyclable adsorbents for water purification via BPA adsorption.
Graphical abstract
Conversion of “Waste Plastic” into Photocatalytic Nanofoams for Environmental Remediation
yang白色垃圾回收利用
A New Generation of Surface Active Carbon Textiles As Reactive Adsorbents of Indoor Formaldehyde
yang室内除甲醛
Fe-Ti/Fe (II)-loading on ceramic filter materials for residual chlorine removal from drinking water
yang饮用水处理
Source:Chemosphere, Volume 200
Author(s): Kexin Man, Qi Zhu, Zheng Guo, Zipeng Xing
Ceramic filter material was prepared with silicon dioxide (SiO2), which was recovered from red mud and then modified with Fe (II) and Fe-Ti bimetal oxide. Ceramic filter material can be used to reduce the content of residual chlorine from drinking water. The results showed that after a two-step leaching process with 3 M hydrochloric acid (HCl) and 90% sulfuric acid (H2SO4), the recovery of SiO2 exceeded 80%. Fe (II)/Fe-Ti bimetal oxide, with a high adsorption capacity of residual chlorine, was prepared using a 3:1 M ratio of Fe/Ti and a concentration of 0.4 mol/L Fe2+. According to the zeta-potential, scanning electron microscopy (SEM) and Brunauer–Emmett–Teller (BET) analysis, Fe (II) and Fe-Ti bimetal oxide altered the zeta potential and structural properties of the ceramic filter material. There was a synergistic interaction between Fe and Ti in which FeOTi bonds on the material surface and hydroxyl groups provided the active sites for adsorption. Through a redox reaction, Fe (II) transfers hypochlorite to chloride, and FeOTiCl bonds were formed after adsorption.
Graphical abstract
Superhydrophobicity: 3D-Printed Biomimetic Super-Hydrophobic Structure for Microdroplet Manipulation and Oil/Water Separation (Adv. Mater. 9/2018)
yang油水分离
In article number 1704912, Yong Chen and co-workers demonstrate a biomimetic superhydrophobic microstructure inspired by the Salvinia molesta leaf using the immersed surface accumulation 3D-printing process. The controllable adhesive force can be easily tuned with a different number of eggbeater arms. The 3D-printed eggbeater structures have numerous applications including as microhands for droplet manipulation and microreactors, and for 3D cell culture, oil-spill clean-up, and oil/water separation.
One-step preparation of GO/SiO2 membrane for highly efficient separation of oil-in-water emulsion
yang油水分离
Source:Journal of Membrane Science, Volume 553
Author(s): Jiawei Sun, Hengchang Bi, Shi Su, Haiyang Jia, Xiao Xie, Litao Sun
The development of filtration membranes with ultrahigh water flux for separation of oil-in-water emulsions by low energy consumption approach is currently an urgent demand. A novel nanocomposite membrane with superhydrophilic and underwater superoleophobic properties has been successfully prepared by one-step vacuum filtration of an aqueous graphene/SiO2 dispersion on a microfiltration substrate. Owing to the addition of SiO2 nanoparticles, the interlayer space of graphene oxide (GO) layers is expanded, enabling this composite membrane to separate a variety of oil-in-water emulsions with ultrahigh water flux (> 4550 L m−2 h−1 bar−1), a 2-order-of-magnitude improvement as compared to pure GO membrane, and also superior compared to most commercialized membranes. The proposed convenient, time-saving (< 10 min) and low cost strategy endows possibility of massive production and shed light on commercial applications of water treatment of oil-in-water wastes in industry and daily life.
Graphical abstract
An iron (II) phthalocyanine/poly(vinylidene fluoride) composite membrane with antifouling property and catalytic self-cleaning function for high-efficiency oil/water separation
yang油水分离
Source:Journal of Membrane Science, Volume 552
Author(s): Fengtao Chen, Xingxing Shi, Xiaobing Chen, Wenxing Chen
To endow poly(vinylidene fluoride) (PVDF) membranes with the performance of fouling resistance and the capability of catalytic degradation of organic contaminants, iron (II) phthalocyanine (FePc) as a modifier was incorporated into PVDF matrix to prepare a novel FePc/PVDF composite membrane via non-solvent induced phase separation technique. ATR-FTIR spectroscopy, XPS, SEM, streaming potential analysis, contact angle measurement and cross-flow filtration test were employed to investigate the influence of modification on membrane property and performance. It was found that the introduction of FePc in PVDF membrane matrix resulted in improved porosity, mean pore size, surface hydrophilicity and negative charge of as-prepared composite membranes, and thereby enhanced membrane permeability and antifouling property. Owing to the presence of Fenton-like catalyst FePc, the composite membranes are imparted the catalytic degradation function for adsorbed organic foulants in soaking H2O2 solution. The catalytic self-cleaning capability of the composite membrane with 2.5 wt% FePc was further proved by fluorescence probe technique which was employed to detect the generation of ·OH radicals in catalytic self-cleaning process. This indicates that the FePc/PVDF composite membrane has a potential application in water treatment with its combined advantage of membrane separation and catalytic self-cleaning.
Intensified extraction of uranium(VI) in impinging-jets contactors
Source:Chemical Engineering Journal, Volume 342
Author(s): Dimitrios Tsaoulidis, Eduardo Garciadiego Ortega, Panagiota Angeli
The mass transfer performance of confined impinging-jets (CIJs) contactors was investigated for metal separations. In particular, the extraction of uranium(VI) from aqueous nitric acid solutions (3 M) into 30% v/v TBP/Exxsol D80, relevant to spent nuclear fuel reprocessing, was studied for different cell geometries, i.e. main chamber size (D = 2 and 3.2 mm) and jet diameter (dj = 0.25 and 0.5 mm), and different operating conditions, i.e. residence time (τ = 1–9 s), total jet velocity (utot = 2.6–8.6 m/s), and reactor length (L = 7–85 cm). For all conditions investigated, the aqueous phase was the dispersed one. Drop sizes were also measured with high-speed imaging. It was found that the extraction efficiency increased by increasing residence time for a constant total jet velocity regardless of the chamber size. At a constant residence time, higher extraction efficiency was achieved at high total jet velocities, which are associated with larger interfacial areas (smaller drops). The extraction efficiency reached 70% in most of the cases investigated in less than 2 s. In addition, high overall volumetric mass transfer coefficients (up to 1 s−1) were obtained at short residence times. Using regression analysis, a correlation for the overall volumetric mass transfer coefficient was developed from the experimental data with an average deviation of 9%.
Ultrafast Processing of Hierarchical Nanotexture for a Transparent Superamphiphobic Coating with Extremely Low Roll-Off Angle and High Impalement Pressure
yang超双疏表面
Abstract
Low roll-off angle, high impalement pressure, and mechanical robustness are key requirements for super-liquid-repellent surfaces to realize their potential in applications ranging from gas exchange membranes to protective and self-cleaning materials. Achieving these properties is still a challenge with superamphiphobic surfaces, which can repel both water and low-surface-tension liquids. In addition, fabrication procedures of superamphiphobic surfaces are typically slow and expensive. Here, by making use of liquid flame spray, a silicon dioxide–titanium dioxide nanostructured coating is fabricated at a high velocity up to 0.8 m s−1. After fluorosilanization, the coating is superamphiphobic with excellent transparency and an extremely low roll-off angle; 10 µL drops of n-hexadecane roll off the surface at inclination angles even below 1°. Falling drops bounce off when impacting from a height of 50 cm, demonstrating the high impalement pressure of the coating. The extraordinary properties are due to a pronounced hierarchical nanotexture of the coating.
Superamphiphobic surfaces can repel both water and oils. Impalement pressure and mechanical stability are still challenges. Fabrication is typically slow or expensive. Using liquid flame spraying, an up-scalable method is demonstrated for fabricating SiO2/TiO2 nanostructured coatings at a velocity of 0.8 m s−1. After fluorosilanization, the coating shows extremely low roll-off angles even toward n-hexadecane, high impalement pressure, and good transparency.
Nanosecond Laser-Induced Underwater Superoleophobic and Underoil Superhydrophobic Mesh for Oil/Water Separation
yang油水分离
Application of monochloramine for wastewater reuse: Effect on biostability during transport and biofouling in RO membranes
yang水处理
Source:Journal of Membrane Science, Volume 551
Author(s): N.M. Farhat, E. Loubineaud, E.I.E.C. Prest, J. El-Chakhtoura, C. Salles, Sz.S. Bucs, J. Trampé, W.B.P. Van den Broek, J.M.C. Van Agtmaal, M.C.M. Van Loosdrecht, J.C. Kruithof, J.S. Vrouwenvelder
The rising demand for clean and safe water has increased the interest in advanced wastewater treatment and reuse. Reverse osmosis (RO) can provide reliable and high-quality water from treated wastewater. Biofouling inevitably occurs, certainly with wastewater effluents, resulting in RO performance decline and operational problems. Chlorination of feed water has been commonly applied to limit biological growth. However, chlorine use may lead to a loss of membrane integrity of RO systems. In this study the potential of monochloramine as an alternative for chlorine was studied by (i) evaluating the biological stability of a full-scale wastewater membrane bioreactor (MBR) effluent during transport over 13 km to a full-scale RO plant and (ii) assessing the biofouling control potential in membrane fouling simulator (MFS) and pilot-scale RO installation. Microbial water analysis was performed on samples taken at several locations in the full-scale water reuse system (MBR effluent, during transport, and at the RO inlet and outlet) using a suite of tools including heterotrophic plate counts (HPC), adenosine triphosphate (ATP), flow cytometry (FCM), and 16 S rRNA gene pyrosequencing. Growth potential tests were used to evaluate the effect of monochloramine presence and absence on bacterial growth. Results showed limited changes in the microbial water quality in the presence of monochloramine. MFS studies showed that membrane biofouling could be effectively repressed by monochloramine over prolonged time periods. The normalized salt passage in a pilot RO system with monochloramine dosage was constant over a one year period (data of last 130 days presented), demonstrating that no membrane damage occurred. From this study, it can be concluded that monochloramine dosage in wastewater applications is effective in controlling biofouling in RO systems and maintaining a monochloramine residual during water transport provides biologically stable water.
Graphical abstract
Hydrophilic hollow zeolitic imidazolate framework-8 modified ultrafiltration membranes with significantly enhanced water separation properties
yang油水分离
Source:Journal of Membrane Science, Volume 551
Author(s): Huazhen Sun, Beibei Tang, Peiyi Wu
Metal-organic frameworks (MOFs) are being intensively investigated for the design of advanced composite membranes, primarily due to their favorable polymer affinity, and highly tunable porous structure and surface properties. However, the development of engineered MOF-based ultrafiltration (UF) membranes for water treatment remains in its infancy. In the present study, hydrophilic hollow zeolitic imidazolate framework-8 (hZIF-8) was meticulously synthesized via surface functionalization-assisted etching approach by using tannic acid (TA), and then incorporated into polysulfone (PSf) casting solution to fabricate novel hybrid UF membranes via phase inversion method. The resultant hZIF-8 not only possessed a highly hydrophilic surface derived from the coated TA but also yielded a unique hollow structure without destroying the intrinsic frameworks. Thanks to the well-tailored surface property and nanostructure of hZIF-8, the obtained PSf/hZIF hybrid UF membranes showed highly improved water permeation (597 L m−2 h−1), which was 2.8 times that of the pristine PSf membrane (210 L m−2 h−1), while well maintaining the rejection property. What's more, the incorporation of hZIF-8 rendered the membrane with enhanced resistance to fouling. These results indicated the great application potential of such MOF/polymer hybrid UF membranes in wastewater treatment and separation in many industrial fields.