23 Oct 15:01

A Softer World: 1164


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23 Oct 08:11

EXPECTING TO FLY for October 23nd 2014

comic
23 Oct 06:45

Цитата #430676

xxx: На работе внедрили систему оповещения. Рассылает емейлы, смс, умеет звонить и синтезированным голосом начитывать любой текст.
xxx: Недавно выяснили, что один из админов настроил её звонить ему в восемь утра и женским голосом говорить "Вставай, Пашенька, уже утро"
23 Oct 03:20

The Only Thing I Have To Say About Gamer Gate

thisfeliciaday:

I had a day off this weekend from shooting Supernatural, and I was walking around downtown Vancouver on Saturday, sampling all the artisan coffee I could get my throat around. At one point I saw a pair of guys walking towards me wearing gamer shirts. Black short-sleeved, one Halo and one Call of Duty. 

Now in my life up until this point, that kind of outfit has meant one thing: Potential comrades. I love games, I love gaming. If it’s Friday night, I’m not out hanging at a club, I’m diving into a new game I downloaded on Steam. And I am blessed with the fact that my career is largely built upon that love, which I channeled into fiction so many years ago with “The Guild”. If there’s anything I’m proud of in this world, it’s the fact that I’ve had people come up to me on the street and at conventions over the years to tell me that they feel confident to call themselves a gamer because of my work, where before they were ashamed. Hearing that kind of stuff has kept me going, against the mainstream, against all odds. 

So seeing another gamer on the street used to be an auto-smile opportunity, or an entry into a conversation starting with, “Hey, dude! I love that game too!” Me and that stranger automatically had something in common: A love for something unconventional. Outsiders in arms. We had an auto-stepping stone to hurtle over human-introduction-awkwardness, into talking about something we loved together. Instant connection!

But for the first time maybe in my life, on that Saturday afternoon, I walked towards that pair of gamers and I didn’t smile. I didn’t say hello. In fact, I crossed the street so I wouldn’t walk by them. Because after all the years of gamer love and inclusiveness, something had changed in me. A small voice of doubt in my brain now suspected that those guys and I might not be comrades after all. That they might not greet me with reflected friendliness, but contempt.  

I went home and was totally, utterly depressed.

I have not said many public things about Gamer Gate. I have tried to leave it alone, aside from a few @ replies on Twitter that journalists have decided to use in their articles, siding me against the hashtag. Why have I remained mostly silent?

Self-protection and fear. 

I have been through a lot in my years on the internet. I have encountered a small fraction of the attacks from people like the ones who currently represent the worst of this “movement”. In the past, I worked through it alone because I felt shining a light on their words gave them exactly what they wanted: Attention and credibility. To say that their attacks and contempt didn’t set me back creatively would be a lie, but overall I got through the twists and turns, emotionally battered, but alright. My philosophy has always been, “Exist and represent yourself the way you want to exist as a woman who loves games, not as a reflection of what other people think or want of you. You will change minds by BEING. Show, don’t tell.” The attacks I experienced over the years were NOTHING compared to people who are the victims of these attacks now, but I still thought early on during the Gamer Gate phenomenon, “These trolls will dissipate into the night like they always do, it will be fine.”

But they have not dissipated. And because of the frightening emotions and actions attached to what has happened over the last month, the events are sure to have a long-lasting affect on gaming as a culture. The fact that it has affected me, to the point where I decided to cross the street last weekend away from those gamers, was heartbreaking. Because I realized my silence on the issue was not motivated by some grand strategy, but out of fear that the issue has created about speaking out. 

I have been terrified of inviting a deluge of abusive and condescending tweets into my timeline. I did one simple @ reply to one of the main victims several weeks back, and got a flood of things I simply couldn’t stand to read directed at me. I had to log offline for a few days until it went away. I have tried to retweet a few of the articles I’ve seen dissecting the issue in support, but personally I am terrified to be doxxed for even typing the words “Gamer Gate”. I have had stalkers and restraining orders issued in the past, I have had people show up on my doorstep when my personal information was HARD to get. To have my location revealed to the world would give a entry point for any mentally ill person who has fixated on me, and allow them to show up and make good on the kind of threats I’ve received that make me paranoid to walk around a convention alone. I haven’t been able to stomach the risk of being afraid to get out of my car in my own driveway because I’ve expressed an opinion that someone on the internet didn’t agree with. 

HOW SICK IS THAT? 

I have allowed a handful of anonymous people censor me. They have forced me, out of fear, into seeing myself a potential victim. 

And that makes me loathe not THEM, but MYSELF. 

So I write this to urge any person, male or female, who now has the impulse to do what I did, to walk away from something they loved before, to NOT. 

Don’t let other people drive you away from gaming. 

Games are beautiful, they are creative, they are worlds to immerse yourself in. They are art. And they are worth fighting for, even if the atmosphere is ugly right now. A small minority are putting up barbed wire walls between us who love games. And that is sad. Because odds are 99% certain that those guys on the street who I avoided would have been awesome to talk to. I realize that letting the actions of a few hateful people influence my behavior is the absolutely worst thing I could do in life. And not an example I want to set, ever.

So to myself and to everyone else who operates out of love not vengeance: Don’t abandon games. Don’t cross the street. Gaming needs you. To create, to play, to connect. 

To represent.

I know this entry will probably draw contempt from people in the Gamer Gate movement. Something to scorn, something to rile them up against me and everything I’ve ever made. Especially, and most hurtfully, to mock my vulnerability. I just have one thing to say to you who do that: I’m genuinely sorry you are so angry. 

I have lived a large part of my life ruled by negative emotions, mainly fear and anxiety. From my experience of working through those issues, I have this to say: Steeping yourself in the emotions that you’re surrounding yourself with, of hatred and bile and contempt, is ultimately not destructive to others like you want it to be. It’s destructive to yourself. 

I know it feels good to belong to a group, to feel righteous in belonging to a cause, but causing fear and pushing people away from gaming is not the way to go about doing it. Think through the repercussions of your actions and the people you are aligning yourself with. And think honestly about whether your actions are genuinely going to change gaming life for the better. Or whether they’re just going to make someone cross the street away from you. And away from something, ironically, that we both love.

I am so lucky that this woman is my friend.

23 Oct 01:54

l0kasenna: lunarobverse: A brilliant metaphor 6. Cycle lanes...











l0kasenna:

lunarobverse:

A brilliant metaphor

6. Cycle lanes are built just for you, and then the cars drive in those too.

23 Oct 00:35

interninet: this gif needs to be destroyed



interninet:

this gif needs to be destroyed

22 Oct 20:11

Photo



22 Oct 20:04

Zinc-Catalyzed Cyclopropenation of Alkynes via 2-Furylcarbenoids

by María J. González, Luis A. López and Rubén Vicente

TOC Graphic

Organic Letters
DOI: 10.1021/ol502848n
22 Oct 19:30

A Catalytic Diastereoselective Formal [5+2] Cycloaddition Approach to Azepino[1,2-a]indoles: Putative Donor–Acceptor Cyclobutanes as Reactive Intermediates

by Raynold Shenje, M. Cynthia Martin, Stefan France

Abstract

A catalytic formal [5+2] cycloaddition approach to the diastereoselective synthesis of azepino[1,2-a]indoles is reported. The reaction presumably proceeds through a Lewis acid catalyzed formal [2+2] cycloaddition of an alkene with an N-indolyl alkylidene β-amide ester to form a donor–acceptor cyclobutane intermediate, which subsequently undergoes an intramolecular ring-opening cyclization. Azepine products are formed in up to 92 % yield with high degrees of diastereoselectivity (up to 34:1 d.r.).

Thumbnail image of graphical abstract

The diastereoselective synthesis of azepino[1,2-a]indoles is enabled by a formal [5+2] cycloaddition approach. The reaction presumably proceeds through a Lewis acid catalyzed formal [2+2] cycloaddition of an alkene with an N-indolyl alkylidene β-amide ester to form a donor–acceptor cyclobutane intermediate, which subsequently undergoes an intramolecular ring-opening cyclization.

22 Oct 17:41

Advances in Catalytic Enantioselective Fluorination, Mono-, Di-, and Trifluoromethylation, and Trifluoromethylthiolation Reactions

by Xiaoyu Yang, Tao Wu, Robert J. Phipps and F. Dean Toste

TOC Graphic

Chemical Reviews
DOI: 10.1021/cr500277b
22 Oct 16:01

Snappy coroner's answers to stupid cross-examiner's questions

by Cory Doctorow


"How can you be sure [the patient wasn't alive] Doctor?" "Because his brain was sitting on my desk in a jar." Read the rest

22 Oct 15:52

Construction of Erythrinane Skeleton via Pd(0)-Catalyzed Intramolecular Dearomatization of para-Aminophenols

by Ren-Qi Xu, Qing Gu, Wen-Ting Wu, Zhuo-An Zhao and Shu-Li You

TOC Graphic

Journal of the American Chemical Society
DOI: 10.1021/ja508645j
22 Oct 05:11

Цитата #430652

Лежу ночью, а над ухом комары мозг выносят. И всё бы ничего, но я же музыкант - я слышу малую терцию, причём один кормар - зараза! - ещё и низит на четверть тона!!!
22 Oct 04:44

Combined GIFs [imgur]Previously: Reversed GIFs





















Combined GIFs [imgur]

Previously: Reversed GIFs

22 Oct 04:01

Chocolate Chip Cookie Dough Dip

by Michelle

Chocolate Chip Cookie Dough Dip - A sweet, creamy dip that tastes like chocolate chip cookie dough without the guilt of raw egg! | browneyedbaker.com #recipe

When I was a kid and my mom would bake cookies, there was an unwritten rule that my sister and I would get to lick the beaters when my mom was done. This usually happened in the midst of holiday baking, and I have such fond memories of hanging out in the kitchen, waiting for her to be done with the mixer so that I could swipe some of that sweet, sugary cookie dough off the beater. At some point along the way, raw cookie dough became bad news amidst worries over salmonella. I don’t think my mom ever made us stop eating cookie dough, but it sure took some of the fun out of it! Luckily, this sweet dip tastes almost exactly like raw cookie dough (minus the gritty, sugary texture), which means all the sinful goodness without the raw eggs!

Chocolate Chip Cookie Dough Dip - A sweet, creamy dip that tastes like chocolate chip cookie dough without the guilt of raw egg! | browneyedbaker.com #recipe

Almost ten years ago, one of my best friends and I were lucky enough to work at the same place. We routinely used our work breaks to bring binders full of recipes to the corporate cafeteria and swap favorites. This recipe was one of the recipes that she gifted to me during one of those escapes from the cubicle, and it continues to be one of my favorites.

I love that it’s not a straight-up dessert, but rather an awesome sweet snack that’s perfect for get-togethers. If you grew up stealing bites of your mom’s cookie dough, you’ll absolutely love this dip!

Chocolate Chip Cookie Dough Dip - A sweet, creamy dip that tastes like chocolate chip cookie dough without the guilt of raw egg! | browneyedbaker.com #recipe

One year ago: Compost Cookies
Two years ago: Pumpkin Seed Brittle with Vanilla Bean and Cardamom
Four years ago: The Best Chocolate Buttercream Frosting
Five years ago: Egg Bagels

Chocolate Chip Cookie Dough Dip

Yield: 6 to 8 servings

Prep Time: 15 minutes

Total Time: 15 minutes

A sweet, creamy dip that tastes just like chocolate chip cookie dough without the guilt of raw egg!

Ingredients:

½ cup unsalted butter, cut into small pieces
⅓ cup light brown sugar
Pinch of salt
1 teaspoon vanilla extract
8 ounces cream cheese
½ cup powdered sugar
¾ cup semisweet mini chocolate chips
Graham crackers or Nilla wafers, to serve

Directions:

1. In a small saucepan, melt the butter, brown sugar and salt over medium-low heat, stirring continuously, until the brown sugar dissolves. Remove from the heat, whisk in the vanilla extract, and set aside to cool to room temperature.

2. With an electric mixer on medium speed, beat the cream cheese and powdered sugar for 1 minute, until smooth and fluffy.

3. Reduce the mixer speed to low and slowly beat in the cooled butter mixture. Increase the speed to medium and beat for 1 minute. Stir in the chocolate chips.

4. Transfer the dip to a serving bowl and refrigerate if not serving immediately. Remove from the refrigerator 15 to 30 minutes before serving. Serve with graham crackers or Nilla wafers. Leftovers can be stored in the refrigerator for up to 5 days.

22 Oct 01:14

Photo



21 Oct 20:20

Recent Advances in Trifluoromethylation Reactions with Electrophilic Trifluoromethylating Reagents

by Sebastián Barata-Vallejo, Beatriz Lantaño, Al Postigo

Abstract

Electrophilic trifluoromethylation reactions have been the latest approach to achieve the fluoroalkylation of compounds with newly-discovered reagents, such as the Togni’s (1-trifluoromethyl-1,2-benziodoxol-3-(1 H)-one), Umemoto’s (S-(trifluoromethyl)dibenzothiophenium tetrafluoroborate), Yagupolskii’s (S-(trifluoromethyldiarylsulfonium salts), Shreeve’s (S-(trifluoromethyl)dibenzothiophenium triflate), and Shibata’s (trifluoromethylsulfoximine salts) reagents. All these reagents produce an electrophilic trifluoromethylating (CF3+) species that undergoes reaction with nucleophiles. In addition, these latter reactive species (i.e. CF3+) can undergo electron-transfer (ET) processes affording CF3 radicals that expand the scope to substrates other than conventional nucleophiles that can undergo reaction. In this Review, we shall discuss the trifluoromethylation reactions of diverse families of organic substrates of biological interest as a means to comparing the reagents scope and best reaction conditions. Some, though not all, of these reactions require the assistance of metal or organometallic catalysts. Some require additives and catalysts to promote the fluoroalkylation reaction, but invariably all are initiated and carried out by electrophilic trifluoromethylating species.

Thumbnail image of graphical abstract

Trifluoromethylation of alkenes, alkynes, α,β-unsaturated carbonyl compounds, hard nucleophiles such as alcohols, thiols, and also aromatic compounds can be achieved through the use of electrophilic trifluoromethylating reagents, such as Togni’s, Umemoto’s, and Shibata’s reagents. These reagents produce an electrophilic trifluoromethylating (CF3+) species that undergoes reaction with nucleophiles.

21 Oct 20:00

On the Street…After Fendi

by The Sartorialist

91914Fendi6B1846Web

91914Fendi6B1865Web

21 Oct 16:40

johndarnielle: chipsandbeermag: Warning Signs of Satanic...



















johndarnielle:

chipsandbeermag:

Warning Signs of Satanic Behavior. Training video for police, 1990

the perfect photoset

24 Oct 06:46

Цитата #430696

xxx: сидишь ты бывает, пьешь чай, вся такая в мыслях и мечтаниях о НЕМ
xxx: и тут приходит смска!
xxx: и ты такая, в предвкушении вся, берешь телефон, смотришь
xxx: а там зарплата пришла(((
yyy: мне бы твои проблемы, дура ванильная...
24 Oct 04:45

Цитата #430691

xxx: К нам сегодня новый сисадмин пришел. Первое что он сделал на новом рабочем месте - бекап всех бекапов. И только потом пошел с нами знакомиться
yyy: Н-да, тяжёлая жизнь была у мужика.
24 Oct 04:44

Цитата #430690

С Хабра:
..байка, рассказанная мне коллегами об одном из предыдущих проектов. На карте был участок, застроенный не разрушаемыми домиками. Как только камера обращала свой взор на этот участок, то FPS сразу же дико падал. После изучения проблемы выяснилось, что внутри одного из домиков стояла ванна, в которой плавала маленькая «пластиковая» уточка. Все это выглядело бы забавной шалостью художников, если бы не то обстоятельство, что модель уточки содержала около миллиона полигонов.
23 Oct 20:37

Photo



23 Oct 19:46

Ylidenemalononitrile Enamines as Fluorescent “Turn-On” Indicators for Primary Amines

by Ashley R. Longstreet, Minyoung Jo, Rebecca R. Chandler, Kenneth Hanson, Naiqian Zhan, Jeremy J. Hrudka, Hedi Mattoussi, Michael Shatruk and D. Tyler McQuade

TOC Graphic

Journal of the American Chemical Society
DOI: 10.1021/ja509058u
23 Oct 18:10

[Report] Room-temperature enantioselective C–H iodination via kinetic resolution

by Ling Chu
Palladium catalysis produces benzylamine derivatives of interest in medicinal chemistry. Authors: Ling Chu, Kai-Jiong Xiao, Jin-Quan Yu