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11 May 07:11

High-Pressure Single-Crystal Structures of 3D Lead-Halide Hybrid Perovskites and Pressure Effects on their Electronic and Optical Properties

by Adam Jaffe, Yu Lin, Christine M. Beavers, Johannes Voss, Wendy L. Mao and Hemamala I. Karunadasa

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ACS Central Science
DOI: 10.1021/acscentsci.6b00055
12 Apr 01:29

Solution-Processed p-Dopant as Interlayer in Polymer Solar Cells

by F. Guillain, J. Endres, L. Bourgeois, A. Kahn, L. Vignau and G. Wantz

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ACS Applied Materials & Interfaces
DOI: 10.1021/acsami.6b00356
12 Apr 01:10

Electrospun Polyurethane/Loess Powder Hybrids and Their Absorption of Volatile Organic Compounds

We investigated the effects of composite electrospun polyurethane (PU)/loess powder (LP) fibers for absorption of volatile organic compounds (VOCs) from air. PU films containing different amounts of LP (0, 10, 30, and 50 wt% LP with respect to PU) nanoparticles (NPs) were analyzed using FE-SEM, FTIR, and XRD experimental analyzers. Electron microscopy and spectroscopy indicated that the proper content of LP NPs is homogeneous dispersion in a polymer matrix. In addition, 50 wt% of LP results in a higher concentration spinning nanosuspension that leads to some agglomeration on the film surface. The chloroform, benzene, and toluene (VOCs) absorption capacity of PU/LP composite films showed a trend of toluene > benzene > chloroform. The highest VOC absorption capacity was found with PU composite mats containing 30 wt% LP NPs. The high VOC absorption capacity of PU/LP composite films can be used to remove VOCs from a new house or car.
06 Apr 01:26

Graphdiyne: A Metal-Free Material as Hole Transfer Layer To Fabricate Quantum Dot-Sensitized Photocathodes for Hydrogen Production

by Jian Li, Xin Gao, Bin Liu, Qingliang Feng, Xu-Bing Li, Mao-Yong Huang, Zhongfan Liu, Jin Zhang, Chen-Ho Tung and Li-Zhu Wu

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Journal of the American Chemical Society
DOI: 10.1021/jacs.5b12758
05 Apr 11:52

Non-Fullerene Polymer Solar Cells Based on Alkylthio and Fluorine Substituted 2D-Conjugated Polymers Reach 9.5% Efficiency

by Haijun Bin, Zhi-Guo Zhang, Liang Gao, Shanshan Chen, Lian Zhong, Lingwei Xue, Changduk Yang and Yongfang Li

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Journal of the American Chemical Society
DOI: 10.1021/jacs.6b01744
05 Apr 11:44

High-Performance Electron Acceptor with Thienyl Side Chains for Organic Photovoltaics

by Yuze Lin, Fuwen Zhao, Qiao He, Lijun Huo, Yang Wu, Timothy C. Parker, Wei Ma, Yanming Sun, Chunru Wang, Daoben Zhu, Alan J. Heeger, Seth R. Marder and Xiaowei Zhan

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Journal of the American Chemical Society
DOI: 10.1021/jacs.6b02004
05 Apr 11:42

Templated Self-Assembly of Ultrathin Gold Nanowires by Nanoimprinting for Transparent Flexible Electronics

by Johannes H. M. Maurer, Lola González-García, Beate Reiser, Ioannis Kanelidis and Tobias Kraus

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Nano Letters
DOI: 10.1021/acs.nanolett.5b04319
05 Apr 11:42

Shape-Controlled Deterministic Assembly of Nanowires

by Yunlong Zhao, Jun Yao, Lin Xu, Max N. Mankin, Yinbo Zhu, Hengan Wu, Liqiang Mai, Qingjie Zhang and Charles M. Lieber

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Nano Letters
DOI: 10.1021/acs.nanolett.6b00292
05 Apr 11:38

Energy Transfer of Biexcitons in a Single Semiconductor Nanocrystal

by Xiangnan Huang, Qinfeng Xu, Chunfeng Zhang, Xiaoyong Wang and Min Xiao

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Nano Letters
DOI: 10.1021/acs.nanolett.6b00060
05 Apr 11:37

Energy Transfer from Quantum Dots to Graphene and MoS2: The Role of Absorption and Screening in Two-Dimensional Materials

by Archana Raja, Andrés Montoya−Castillo, Johanna Zultak, Xiao-Xiao Zhang, Ziliang Ye, Cyrielle Roquelet, Daniel A. Chenet, Arend M. van der Zande, Pinshane Huang, Steffen Jockusch, James Hone, David R. Reichman, Louis E. Brus and Tony F. Heinz

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Nano Letters
DOI: 10.1021/acs.nanolett.5b05012
30 Mar 02:34

VIP: A Solar Cell That Is Triggered by Sun and Rain

Prof. Qunwei Tang, Xiaopeng Wang, Prof. Peizhi Yang and Dr. Benlin He

A Solar Cell That Is Triggered by Sun and Rain

A flexible solar cell that can be excited by sunlight and raindrops is presented. The solar-to-electric conversion efficiency is created by complicated photoelectrochemical reactions, while electric signals, produced by dropping raindrops on rGO film, arise from π-electron|cation pseudocapacitance at the rGO/raindrop interface. This work could guide the design of all-weather solar cells.

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30 Mar 01:05

Directed Self-Assembly Pathways of Active Colloidal Clusters

Directed Self‐Assembly Pathways of Active Colloidal Clusters

The journey matters: Self-propelled particles are induced to assemble into different chiral structures that rotate persistently in an electric field. Rather than energy preference, dynamic factors during the non-equilibrium assembly determine which structure is selected.

[Communication]
Jie Zhang, Jing Yan, Steve Granick
Angew. Chem. Int. Ed., March 24, 2016, DOI: 10.1002/anie.201509978. Read article

30 Mar 01:04

Effect of Electron–Hole Overlap and Exchange Interaction on Exciton Radiative Lifetimes of CdTe/CdSe Heteronanocrystals

by Andrés Granados del Águila, Esther Groeneveld, Jan C. Maan, Celso de Mello Donegá and Peter C. M. Christianen

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ACS Nano
DOI: 10.1021/acsnano.5b07158
30 Mar 01:03

Raman Shifts in Electron-Irradiated Monolayer MoS2

by William M. Parkin, Adrian Balan, Liangbo Liang, Paul Masih Das, Michael Lamparski, Carl H. Naylor, Julio A. Rodríguez-Manzo, A. T. Charlie Johnson, Vincent Meunier and Marija Drndić

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ACS Nano
DOI: 10.1021/acsnano.5b07388
30 Mar 01:02

Simultaneous Tunable Selection and Self-Assembly of Si Nanowires from Heterogeneous Feedstock

by Marios Constantinou, Grigorios Panagiotis Rigas, Fernando A. Castro, Vlad Stolojan, Kai F. Hoettges, Michael P. Hughes, Emily Adkins, Brian A. Korgel and Maxim Shkunov

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ACS Nano
DOI: 10.1021/acsnano.6b00005
23 Mar 01:16

Zn–Cu–In–Se Quantum Dot Solar Cells with a Certified Power Conversion Efficiency of 11.6%

by Jun Du, Zhonglin Du, Jin-Song Hu, Zhenxiao Pan, Qing Shen, Jiankun Sun, Donghui Long, Hui Dong, Litao Sun, Xinhua Zhong and Li-Jun Wan

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Journal of the American Chemical Society
DOI: 10.1021/jacs.6b00615
23 Mar 01:14

Competing Interactions between Various Entropic Forces toward Assembly of Pt3Ni Octahedra into a Body-Centered Cubic Superlattice

by Ruipeng Li, Jun Zhang, Rui Tan, Frauke Gerdes, Zhiping Luo, Hongwu Xu, Jennifer A. Hollingsworth, Christian Klinke, Ou Chen and Zhongwu Wang

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Nano Letters
DOI: 10.1021/acs.nanolett.6b00564
23 Mar 00:59

A Photonic Crystal Laser from Solution Based Organo-Lead Iodide Perovskite Thin Films

by Songtao Chen, Kwangdong Roh, Joonhee Lee, Wee Kiang Chong, Yao Lu, Nripan Mathews, Tze Chien Sum and Arto Nurmikko

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ACS Nano
DOI: 10.1021/acsnano.5b08153
18 Mar 01:02

Enhanced Electron Extraction Capability of Polymer Solar Cells via Employing Electrostatically Self-Assembled Molecule on Cathode Interfacial Layer

by Zhiqi Li, Xinyuan Zhang, Chunyu Liu, Zhihui Zhang, Jinfeng Li, Liang Shen, Wenbin Guo and Shengping Ruan

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ACS Applied Materials & Interfaces
DOI: 10.1021/acsami.5b12394
18 Mar 00:58

Organized Aggregation Makes Insoluble Perylene Diimide Efficient for the Reduction of Aryl Halides via Consecutive Visible Light-Induced Electron-Transfer Processes

by Le Zeng, Tao Liu, Cheng He, Dongying Shi, Feili Zhang and Chunying Duan

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Journal of the American Chemical Society
DOI: 10.1021/jacs.5b12931
18 Mar 00:57

Deciphering Halogen Competition in Organometallic Halide Perovskite Growth

by Bin Yang, Jong Keum, Olga S. Ovchinnikova, Alex Belianinov, Shiyou Chen, Mao-Hua Du, Ilia N. Ivanov, Christopher M. Rouleau, David B. Geohegan and Kai Xiao

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Journal of the American Chemical Society
DOI: 10.1021/jacs.5b13254
15 Mar 00:55

Large Molecular Weight Polymer Solar Cells with Strong Chain Alignment Created by Nanoimprint Lithography

by Yi Yang, Kamil Mielczarek, Anvar Zakhidov and Walter Hu

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ACS Applied Materials & Interfaces
DOI: 10.1021/acsami.6b00192
15 Mar 00:52

Hot Paper: End-Group-Functionalized Poly(α-olefinates) as Non-Polar Building Blocks: Self-Assembly of Sugar–Polyolefin Hybrid Conjugates

Tessy S. Thomas, Wonseok Hwang and Prof. Lawrence R. Sita

End-Group-Functionalized Poly(α-olefinates) as Non-Polar Building Blocks: Self-Assembly of Sugar–Polyolefin Hybrid Conjugates

The tail that wags the dog: Living coordinative chain-transfer polymerization of α-olefins provides entry to end-group functionalized poly(α-olefinates) (x-PAOs) serving as non-polar building blocks with tailorable occupied volumes. Application of these x-PAOs for sugar–polyolefin hybrid conjugates demonstrates the ability to manipulate the morphology of the ultra-thin film nanostructure by variation in occupied volume of the x-PAO domain.

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15 Mar 00:42

Increased Photoconductivity Lifetime in GaAs Nanowires by Controlled n-Type and p-Type Doping

by Jessica L. Boland, Alberto Casadei, Gözde Tütüncüoglu, Federico Matteini, Christopher L. Davies, Fauzia Jabeen, Hannah J. Joyce, Laura M. Herz, Anna Fontcuberta i Morral and Michael B. Johnston

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ACS Nano
DOI: 10.1021/acsnano.5b07579
14 Mar 04:41

Highly Efficient Flexible Perovskite Solar Cells Using Solution-Derived NiOx Hole Contacts

by Xingtian Yin, Peng Chen, Meidan Que, Yonglei Xing, Wenxiu Que, Chunming Niu and Jinyou Shao

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ACS Nano
DOI: 10.1021/acsnano.5b08135
11 Mar 00:57

Emissive Polyelectrolytes As Interlayer for Color Tuning and Electron Injection in Solution-Processed Light-Emitting Devices

by Serpil Tekoglu, Martin Petzoldt, Sebastian Stolz, Uwe H. F. Bunz, Uli Lemmer, Manuel Hamburger and Gerardo Hernandez-Sosa

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ACS Applied Materials & Interfaces
DOI: 10.1021/acsami.6b00665
11 Mar 00:56

Self-Assembled Multilayer Structure and Enhanced Thermochromic Performance of Spinodally Decomposed TiO2–VO2 Thin Film

by Guangyao Sun, Huaijuan Zhou, Xun Cao, Rong Li, Masato Tazawa, Masahisa Okada and Ping Jin

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ACS Applied Materials & Interfaces
DOI: 10.1021/acsami.5b12476
11 Mar 00:56

Self-Assembled Monolayers of Perfluoroanthracenylaminoalkane Thiolates on Gold as Potential Electron Injection Layers

by Zibin Zhang, Tobias Wächter, Martin Kind, Swen Schuster, Jan W. Bats, Alexei Nefedov, Michael Zharnikov and Andreas Terfort

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ACS Applied Materials & Interfaces
DOI: 10.1021/acsami.6b00532
11 Mar 00:51

Unravelling the Effects of Grain Boundary and Chemical Doping on Electron–Hole Recombination in CH3NH3PbI3 Perovskite by Time-Domain Atomistic Simulation

by Run Long, Jin Liu and Oleg V. Prezhdo

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Journal of the American Chemical Society
DOI: 10.1021/jacs.6b00645
09 Mar 07:10

Inside Back Cover: Monodisperse Dual-Functional Upconversion Nanoparticles Enabled Near-Infrared Organolead Halide Perovskite Solar Cells (Angew. Chem. Int. Ed. 13/2016)

Inside Back Cover: Monodisperse Dual‐Functional Upconversion Nanoparticles Enabled Near‐Infrared Organolead Halide Perovskite Solar Cells (Angew. Chem. Int. Ed. 13/2016)

The local magnetic anisotropy NaYF4:Yb/Er upconversion nanoparticles as a mesoporous electrode into organolead halide perovskite solar cells makes it possible to operate the cells in near-infrared light. In their Communication on page 4280 ff., Z. Lin et al. show that the upconversion material broadens the solar spectral range used by the solar cell to near-infrared light and minimizes the non-absorption energy loss, thus leading to an enhanced photovoltaic performance.

[Cover Picture]
Ming He, Xinchang Pang, Xueqin Liu, Beibei Jiang, Yanjie He, Henry Snaith, Zhiqun Lin
Angew. Chem. Int. Ed., March 08, 2016, DOI: 10.1002/anie.201601639. Read article