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05 Feb 14:50

[ASAP] Effect of Shell Thickness on the Oxygen Evolution Activity of Core@shell Fe3O4@CoFe2O4 Nanoparticles

by Iryna Makarchuk, Benjamin Rotonnelli, Lisa Royer, Simon Hettler, Jean-Jacques Gallet, Fabrice Bournel, Julie Guehl, Amandine Brige, Andrea Zitolo, Gwénaëlle Kéranguéven, Antoine Bonnefont, Raul Arenal, Elena Savinova, Tristan Asset, and Benoit P. Pichon

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.4c01784
05 Feb 14:49

[ASAP] B-Site Mixing Effects in Hybrid Perovskites: Phase Transitions and Dielectric Response of MAPb1–xSnxBr3

by Gabrielius Rimkus, Sergejus Balčiu̅nas, Hanna R. Petrosova, Olesia I. Kucheriv, Rokas Lemežis, Vytautas Klimavičius, Vidmantas Kalendra, Ju̅ras Banys, Il’ya A. Gural’skiy, and Mantas Šimėnas

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.4c03381
05 Feb 14:48

Semi-transparent photovoltaics

Energy Environ. Sci., 2025, 18,2095-2135
DOI: 10.1039/D4EE04209C, Review Article
Chunyu Xu, Yifan Chen, Zijin Zhao, Bowen Yang, Jiajia Suo, Kun Ba, Alexey Tarasov, Yulun Wu, Xinxin Lian, Ming Luo, Yiqiang Zhan, Yifeng Chen, Jifan Gao, Xiaoliang Mo, Wallace C. H. Choy, Jianlu Wang, Hong Zhang, Junhao Chu
Semi-transparent photovoltaics (STPVs) have attracted increasing attention owing to their ability to seamlessly integrate power generation with light transmission.
The content of this RSS Feed (c) The Royal Society of Chemistry
05 Feb 14:46

Unveiling the impact of photoinduced halide segregation on performance degradation in wide-bandgap perovskite solar cells

Energy Environ. Sci., 2025, 18,2308-2317
DOI: 10.1039/D4EE05604C, Paper
Yuxiao Guo, Cong Zhang, Linqin Wang, Xingtian Yin, Bihui Sun, Changting Wei, Xin Luo, Shiyu Yang, Licheng Sun, Bo Xu
By varying the thickness of WBG perovskite films, we identified two distinct migration modes of halide ions under light irradiation, as well as their effects on device JSC output, which provides the feasible research direction for stable WBG PSCs.
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05 Feb 14:46

From 20% single-junction organic photovoltaics to 26% perovskite/organic tandem solar cells: self-assembled hole transport molecules matter

Energy Environ. Sci., 2025, 18,2536-2545
DOI: 10.1039/D4EE05533K, Paper
Xiaokang Sun, Fei Wang, Guo Yang, Xiaoman Ding, Jie Lv, Yonggui Sun, Taomiao Wang, Chuanlin Gao, Guangye Zhang, Wenzhu Liu, Xiang Xu, Soumitra Satapathi, Xiaoping Ouyang, Annie Ng, Long Ye, Mingjian Yuan, Hongyu Zhang, Hanlin Hu
The stacking of SAM layers was regulated to form “face-on” orientation via incorporating the volatile solid additive TCB.
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05 Feb 14:45

Simultaneously improving efficiency, stability and intrinsic stretchability of organic photovoltaic films via molecular toughening

Energy Environ. Sci., 2025, 18,2570-2583
DOI: 10.1039/D4EE05893C, Paper
Kaihu Xian, Kai Zhang, Tao Zhang, Kangkang Zhou, Zhiguo Zhang, Jianhui Hou, Haoli Zhang, Yanhou Geng, Long Ye
A tethered molecule is introduced to realize intrinsically stretchable organic photovoltaics (OPVs) with over 15% efficiency via benign solvents, and thickness-dependent mechanical properties is elucidated for the first time in OPVs.
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05 Feb 14:45

Efficient rigid and flexible perovskite solar cells using strongly adsorbed molecules for lattice repair and grain boundary mitigation

Energy Environ. Sci., 2025, 18,2905-2917
DOI: 10.1039/D4EE05232C, Paper
Xi Fan, Jiwen Chen, Jinzhao Wang, Jing Wang, Jixi Zeng, Feng Wei, Shuai Gao, Jia Li, Jing Zhang, Feng Yan, Weijie Song
Molecular passivation reduces the lattice defects and induces large grains for high efficiencies of perovskite solar cells.
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05 Feb 14:45

Melamine holding PbI2 with three “arms”: an effective chelation strategy to control the lead iodide to perovskite conversion for inverted perovskite solar cells

Energy Environ. Sci., 2025, 18,2436-2451
DOI: 10.1039/D4EE04692G, Paper
Shizi Luo, Shuguang Cao, Tongjun Zheng, Zhuoneng Bi, Yupeng Zheng, Yiqun Li, Biniyam Zemene Taye, Victoria V. Ozerova, Lyubov A. Frolova, Nikita A. Emelianov, Eugeniy D. Tarasov, Zheng Liang, Lavrenty G. Gutsev, Sergey M. Aldoshin, Bala R. Ramachandran, Pavel A. Troshin, Xueqing Xu
Herein, we have proposed a novel tridentate chelation strategy to manage the excessive amount of unreacted PbI2 in perovskite films, achieving a inverted PSC device with a PCE of 25.66% by sequential deposition method.
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05 Feb 14:45

Strategies to improve the photovoltaic performance of M-series acceptor-based polymer solar cells: chemical hybridization versus physical blending of acceptors

Energy Environ. Sci., 2025, 18,2895-2904
DOI: 10.1039/D5EE00294J, Paper
Haiting Shi, Hui Guo, Dongdong Cai, Jin-Yun Wang, Yunlong Ma, Qingdong Zheng
A novel asymmetric M-series acceptor (M36-FCl) with a large dielectric constant and a smaller exciton dissociation barrier has been developed for high-performance polymer solar cells.
The content of this RSS Feed (c) The Royal Society of Chemistry
05 Feb 14:44

Suppressing phase segregation and nonradiative losses by a multifunctional cross-linker for high-performance all-perovskite tandem solar cells

Energy Environ. Sci., 2025, 18,2995-3004
DOI: 10.1039/D4EE02898H, Paper
Xin Zheng, Shaomin Yang, Jingwei Zhu, Ranran Liu, Lin Li, Miaomiao Zeng, Chunxiang Lan, Shangzhi Li, Jinghao Li, Yingying Shi, Cong Chen, Rui Guo, Ziwei Zheng, Jing Guo, Xiaoyu Wu, Tian Luan, Zaiwei Wang, Dewei Zhao, Yaoguang Rong, Xiong Li
A cross-linker is designed to suppress the notorious light-induced phase segregation and nonradiative losses. The as-fabricated WBG PSCs deliver a certified VOC of 1.37 V, which is among the highest values for WBG PSCs. And it enables 28.3% APTSCs.
The content of this RSS Feed (c) The Royal Society of Chemistry
15 Jan 15:40

[ASAP] Where Do the Electrons Go? Studying Loss Processes in the Electrochemical Charging of Semiconductor Nanomaterials

by Reinout F. Ubbink, Yan B. Vogel, Maarten Stam, Hua Chen, and Arjan J. Houtepen

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.4c02998
15 Jan 15:40

[ASAP] Impact of Sequential Chemical Doping on the Thin Film Mechanical Properties of Conjugated Polymers

by Kan Tang, Alyssa Shaw, Saroj Upreti, Haoyu Zhao, Yunfei Wang, Gage T. Mason, Jeffrey Aguinaga, Keyi Guo, Derek Patton, Derya Baran, Simon Rondeau-Gagné, and Xiaodan Gu

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.4c03120
15 Jan 15:39

[ASAP] Band Gap Narrowing in Lead-Halide Perovskites by Dynamic Defect Self-Doping for Enhanced Light Absorption and Energy Upconversion

by Yongliang Shi, Weibin Chu, Lili Zhang, Bipeng Wang, Wissam A. Saidi, Jin Zhao, and Oleg V. Prezhdo

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.4c02530
15 Jan 14:40

Surpassing 90% Shockley–Queisser VOC limit in 1.79 eV wide-bandgap perovskite solar cells using bromine-substituted self-assembled monolayers

Energy Environ. Sci., 2025, 18,1847-1855
DOI: 10.1039/D4EE04029E, Paper
Open Access Open Access
Zhouyin Wei, Qilin Zhou, Xiuxiu Niu, Shunchang Liu, Zijing Dong, Haoming Liang, Jinxi Chen, Zhuojie Shi, Xi Wang, Zhenrong Jia, Xiao Guo, Renjun Guo, Xin Meng, Yu-Duan Wang, Nengxu Li, Zhiguang Xu, Zaifang Li, Armin Gerhard Aberle, Xinxing Yin, Yi Hou
DCB-Br-2 is used as a hole-transporting layer for 1.79 eV wide-bandgap perovskite solar cells. Its stronger interaction with the perovskite and better energy level alignment enable the achievement of a notable VOC of 1.37 V.
The content of this RSS Feed (c) The Royal Society of Chemistry
15 Jan 14:40

pH-Independent lead sequestration and light management enable sustainable and efficient perovskite photovoltaics

Energy Environ. Sci., 2025, 18,1901-1910
DOI: 10.1039/D4EE03820G, Paper
Xi Jin, Jun Li, Siyuan Zhu, Wenyan Tan, Jiahong Tang, Xueyuan Gong, Xingyu Liu, Yu Zhang, Chao Zhou, Zhaoheng Tang, Vincent O. Nyamori, Bice S. Martincigh, Matthew L. Davies, Minghua Li, Tongsheng Chen, Qi Chen, Jinsong Hu, Qijie Liang, Weiqiang Chen, Yan Jiang
Textured phosphate-buffered functionalized polymer films are designed to mitigate the lead leakage and optical loss challenges of perovskite solar cells.
The content of this RSS Feed (c) The Royal Society of Chemistry
15 Jan 14:40

19.46%-Efficiency all-polymer organic solar cells with excellent outdoor operating stability enabled by active layer reconstruction

Energy Environ. Sci., 2025, 18,1812-1823
DOI: 10.1039/D4EE05083E, Paper
Xiaohei Wu, Bo Xiao, Rui Sun, Xinrong Yang, Meimei Zhang, Yuan Gao, Biao Xiao, Elizaveta D. Papkovskaya, Yuriy Luponosov, Christoph J. Brabec, Jie Min
Layer-by-layer blade deposition was employed along with a multi-component strategy to construct a quaternary all-polymer system, achieving a high power conversion efficiency of 19.46% and improved outdoor operating stability.
The content of this RSS Feed (c) The Royal Society of Chemistry
15 Jan 14:40

Modular perovskite-BiVO4 artificial leaves towards syngas synthesis on a m2 scale

Energy Environ. Sci., 2025, 18,3623-3632
DOI: 10.1039/D4EE05780E, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Virgil Andrei, Yu-Hsien Chiang, Motiar Rahaman, Miguel Anaya, Taeheon Kang, Edoardo Ruggeri, Samuel D. Stranks, Erwin Reisner
Thermal evaporation enables the scalable production of 10 cm2 perovskite-BiVO4 artificial leaves for unassisted syngas synthesis. A 10 × 10 device array has been demonstrated outdoors in a 0.35 m2 reactor for the EIC Horizon Prize “Fuel from the Sun”.
The content of this RSS Feed (c) The Royal Society of Chemistry
07 Jan 14:53

Photomechanically accelerated degradation of perovskite solar cells

Energy Environ. Sci., 2025, 18,2254-2263
DOI: 10.1039/D4EE04878D, Paper
Haonan Wang, Qing Li, Yan Zhu, Xinyuan Sui, Xiulian Fan, Miaoyu Lin, Yifeng Shi, Yichu Zheng, Haiyang Yuan, Yu Zhou, Haibao Jin, Hua Gui Yang, Yu Hou, Shuang Yang
We conducted the first study on the impact of photomechanical effect on the stability of PSCs. And we demonstrated a photomechanically accelerated degradation mechanism of perovskite thin films.
The content of this RSS Feed (c) The Royal Society of Chemistry
07 Jan 07:57

[ASAP] Asymmetrically Substituted Quinoxaline Enabling Conformation-Locked Polymer Donors toward High-Performance Polymer Solar Cells

by Hongru Chen, Jiongjiong Zhang, Qingyuan Wang, Shixin Meng, Qiuju Zhou, Yang Bai, Ming Zhang, Yongxing Ren, Ping Shen, Lingwei Xue, Liwei Mi, and Zhi-Guo Zhang

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.4c03051
07 Jan 07:57

Interface design based on strain isolation theory with an optimized neutral mechanical plane enables highly ductile and flexible organic photovoltaics

Energy Environ. Sci., 2025, 18,2318-2329
DOI: 10.1039/D4EE02963A, Paper
Shumin Zeng, Haojie Li, Siqi Liu, Tangyue Xue, Kai Zhang, Lin Hu, Zheren Cai, Yongting Cui, Hanlin Wang, Meng Zhang, Xiaotian Hu, Long Ye, Yanlin Song, Yiwang Chen
The neutral mechanical plane design can improve the mechanical properties of PEDOT:PSS film and FOSCs. A twistable organic photovoltaic module that is the first to be evaluated for mechanical stability and has a PCE of more than 14%.
The content of this RSS Feed (c) The Royal Society of Chemistry
07 Jan 07:56

Suppressed surface lattice vacancies and distortion through lattice anchoring for efficient FAPbI3 perovskite quantum dot solar cells

Energy Environ. Sci., 2025, 18,300-312
DOI: 10.1039/D4EE04112G, Paper
Mingxu Zhang, Xinyi Mei, Guoliang Wang, Junming Qiu, Zhimei Sun, Xiaoliang Zhang
A facile surface lattice anchoring strategy is reported to stabilize the surface lattice of perovskite quantum dots, which could substantially improve their optoelectronic properties and crystal stabilities for application in solar cells.
The content of this RSS Feed (c) The Royal Society of Chemistry
07 Jan 07:55

Simultaneously improving the efficiencies of organic photovoltaic devices and modules by finely manipulating the aggregation behaviors of Y-series molecules

Energy Environ. Sci., 2025, 18,256-263
DOI: 10.1039/D4EE04378B, Paper
Yaohui Li, Ziyan Jia, Peihao Huang, Chuanlin Gao, Yufei Wang, Shuangxi Xue, Shirong Lu, Yang (Michael) Yang
We have developed a novel liquid additive that boosts J-aggregation in NFAs through enhanced non-covalent interactions with the BTP core, leading to a record efficiency for thick-film (≥200 nm), large-area OPV modules.
The content of this RSS Feed (c) The Royal Society of Chemistry
07 Jan 07:55

Fine-tuning the hierarchical morphology of multi-component organic photovoltaics via a dual-additive strategy for 20.5% efficiency

Energy Environ. Sci., 2025, 18,313-321
DOI: 10.1039/D4EE03778B, Paper
Shitao Guan, Yaokai Li, ZhaoZhao Bi, Yi Lin, Yuang Fu, Kangwei Wang, Mengting Wang, Wei Ma, Jianlong Xia, Zaifei Ma, Zheng Tang, Xinhui Lu, Lijian Zuo, Hanying Li, Hongzheng Chen
The dual-additive strategy forms balanced crystallization and phase separation, with a record efficiency of 20.52% (certified 19.92%) achieved.
The content of this RSS Feed (c) The Royal Society of Chemistry
17 Dec 08:31

Breaking the symmetry of interfacial molecules with push–pull substituents enables 19.67% efficiency organic solar cells featuring enhanced charge extraction

Energy Environ. Sci., 2025, 18,1722-1731
DOI: 10.1039/D4EE04515G, Paper
Lei Liu, Fengyi Yu, Dingqin Hu, Xue Jiang, Peihao Huang, Yulu Li, Gengsui Tian, Hongliang Lei, Shiwen Wu, Kaihuai Tu, Chen Chen, Teng Gu, Yao Chen, Tainan Duan, Zeyun Xiao
The unsymmetrical push–pull strategy in the interfacial layer enables fast charge extraction and suppresses surface and trap-assisted recombination, achieving a 19.67% efficiency in binary single junction organic solar cells.
The content of this RSS Feed (c) The Royal Society of Chemistry
16 Dec 08:16

Suppressed non-radiative loss and efficient hole transfer at a small highest occupied molecular orbital offset endows binary organic solar cells with 19.73% efficiency and a small efficiency-cost gap

Energy Environ. Sci., 2025, 18,386-396
DOI: 10.1039/D4EE03000A, Paper
Xiaolei Kong, Nana Yang, Xixi Zhang, Jinyuan Zhang, Zhenyu Li, Xinrui Li, Yilei Wu, Rui Sun, Jing Li, Aoxiang Li, Jie Min, Guang Yang, Chenkai Sun
Two novel acceptors are designed and synthesized, and the PTQ11:PEH-F binary system is highly promising for industrial cost-effective organic photovoltaics.
The content of this RSS Feed (c) The Royal Society of Chemistry
16 Dec 08:15

23.2% efficient low band gap perovskite solar cells with cyanogen management

Energy Environ. Sci., 2025, 18,439-453
DOI: 10.1039/D4EE03001J, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
W. Hashini K. Perera, Thomas Webb, Yuliang Xu, Jingwei Zhu, Yundong Zhou, Gustavo F. Trindade, Mateus G. Masteghin, Steven P. Harvey, Sandra Jenatsch, Linjie Dai, Sanjayan Sathasivam, Thomas J. Macdonald, Steven J. Hinder, Yunlong Zhao, Samuel D. Stranks, Dewei Zhao, Wei Zhang, K. D. G. Imalka Jayawardena, Saif A. Haque, S. Ravi P. Silva
The role of thiocyanates in minimising organohalide diffusion into PEDOT:PSS whilst accelerating device degradation is identified and a route towards improving both device efficiency and stability is demonstrated.
The content of this RSS Feed (c) The Royal Society of Chemistry
16 Dec 08:15

Binary all-polymer solar cells with 19.30% efficiency enabled by bromodibenzothiophene-based solid additive

Energy Environ. Sci., 2025, 18,397-405
DOI: 10.1039/D4EE02978J, Paper
Haisheng Ma, Jiali Song, Jiawei Qiao, Bingyu Han, Qianqian Wang, Min Hun Jee, Laju Bu, Donghui Wei, Han Young Woo, Xiaotao Hao, Yanming Sun
Two volatile solid additives were developed to modulate the active-layer morphology of all-polymer solar cells (all-PSCs). Among them, the 4-BDBTP-treated all-PSC achieved an outstanding efficiency of 19.30%.
The content of this RSS Feed (c) The Royal Society of Chemistry
16 Dec 08:15

Light radiation annealing enables unidirectional crystallization of vacuum-assisted Sn–Pb perovskites for efficient tandem solar cells

Energy Environ. Sci., 2025, 18,430-438
DOI: 10.1039/D4EE03419H, Paper
Ciyu Ge, Qi Xu, Dayu Liu, Wenjiang Ye, Yongxin Zhu, Peiyan Zhang, Jiakuan Yang, Guangxing Liang, Ling Xu, Ying Zhou, Haisheng Song, Chao Chen, Jiang Tang
Vacuum-assisted technology, favored for its low cost, environmentally friendly nature, and scalability, is widely used in perovskite solar cells and is a preferred choice for commercialized production.
The content of this RSS Feed (c) The Royal Society of Chemistry
16 Dec 08:14

A review on organic nanoparticle-based optoelectronic devices: from synthesis to applications

Energy Environ. Sci., 2025, 18,155-193
DOI: 10.1039/D4EE03575E, Review Article
Zhe Liu, Chen Xie, Thomas Heumueller, Iain McCulloch, Christoph J. Brabec, Fei Huang, Yong Cao, Ning Li
An overview of water/alcohol-based organic nanoparticles applied in optoelectronic devices, encompassing the entire journey from nanoparticle synthesis to practical applications.
The content of this RSS Feed (c) The Royal Society of Chemistry
16 Dec 08:13

Triphenylamine–ethylenedioxythiophene copolymers for perovskite solar cells: impact of substituent type and alternation

Energy Environ. Sci., 2025, 18,702-712
DOI: 10.1039/D4EE03316G, Paper
Lifei He, Yuyan Zhang, Bing Zhang, Yanfei Mu, Niansheng Xu, Yaohang Cai, Yi Yuan, Jing Zhang, Min Zhang, Peng Wang
A copolymer of triphenylamine and ethylenedioxythiophene affords stable perovskite solar cells with an average efficiency of 25.4%.
The content of this RSS Feed (c) The Royal Society of Chemistry