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13 Nov 15:42

Recent advances in triplet–triplet annihilation upconversion and singlet fission, towards solar energy applications

Energy Environ. Sci., 2022, 15,4982-5016
DOI: 10.1039/D2EE01600A, Review Article
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Andrew J. Carrod, Victor Gray, Karl Börjesson
Here we consolidate recent advances in the fields of triplet–triplet annihilation photon upconversion and singlet fission. We further describe their utility in increasing the efficiency of photovoltaic devices.
The content of this RSS Feed (c) The Royal Society of Chemistry
02 Nov 08:56

[ASAP] Cage Molecules Stabilize Lead Halide Perovskite Thin Films

by Shijing Sun, Ming Liu, Janak Thapa, Noor Titan Putri Hartono□, Yicheng Zhao, Donglin He, Sarah Wieghold, Matthew Chua, Yue Wu, Vladimir Bulović, Sanliang Ling, Christoph J. Brabec, Andrew I. Cooper, and Tonio Buonassisi

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.2c01502
02 Nov 08:54

Direct Z-scheme polymeric heterojunction boosts photocatalytic hydrogen production via a rebuilt extended π-delocalized network

Energy Environ. Sci., 2022, 15,5059-5068
DOI: 10.1039/D2EE02380F, Communication
Linpeng Xu, Bining Tian, Tianyue Wang, Ying Yu, Yucheng Wu, Jiewu Cui, Zhongnan Cao, Jianhong Wu, Weike Zhang, Qi Zhang, Jiaqin Liu, Zhanfeng Li, Yue Tian
We propose a strategy to rebuild the extended π-delocalized network in a Z-scheme polymeric heterojunction to improve the photon utilization efficiency, engendering an unprecedentedly high photocatalytic performance.
The content of this RSS Feed (c) The Royal Society of Chemistry
02 Nov 08:54

Triggering favorable energy landscape: a general approach towards highly efficient and photostable organic solar cells

Energy Environ. Sci., 2022, 15,5261-5273
DOI: 10.1039/D2EE01894B, Paper
Kangning Zhang, Xiaoyan Du, Jiawei Qiao, Haixia Hu, Wenqing Zhang, Linghua Wang, Mingsheng Gao, Hang Yin, Wei Qin, Xiaotao Hao
A synergistic approach of interface modification and morphology control was utilized to trigger favorable energy landscape in the device level, which yields simultaneously improved efficiency and photostability in BTP-based organic solar cells.
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02 Nov 08:54

Performance limitations imposed by the TCO heterojunction in high efficiency perovskite solar cells

Energy Environ. Sci., 2022, 15,5202-5216
DOI: 10.1039/D2EE01742C, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Daniel Walter, Jun Peng, Klaus Weber, Kylie R. Catchpole, Thomas P. White
The efficiency of perovskite solar cells has risen rapidly, but continuing this trend requires addressing all forms of power loss. Here, we show how the TCO heterojunction can cap efficiency and how transport layers should be selected in response.
The content of this RSS Feed (c) The Royal Society of Chemistry
02 Nov 08:53

Novel low-carbon energy solutions for powering emerging wearables, smart textiles, and medical devices

Energy Environ. Sci., 2022, 15,4928-4981
DOI: 10.1039/D2EE02695C, Review Article
Brindha Ramasubramanian, Subramanian Sundarrajan, Rayavarapu Prasada Rao, M. V. Reddy, Vijila Chellappan, Seeram Ramakrishna
Low CO2 emitting energy extraction techniques and their application in healthcare, textile and smart wearables.
The content of this RSS Feed (c) The Royal Society of Chemistry
02 Nov 08:53

Anchoring of halogen-cleaved organic ligands on perovskite surfaces

Energy Environ. Sci., 2022, 15,5340-5349
DOI: 10.1039/D2EE02698H, Paper
Juntao Hu, Peng Chen, Deying Luo, Linjie Dai, Nan Chen, Shunde Li, Shiyu Yang, Zewei Fu, Dengke Wang, Qihuang Gong, Samuel D. Stranks, Rui Zhu, Zheng-Hong Lu
Photoemission spectroscopy reveals halogen cleavage from bulky cation organics and the formation process of 2D-like perovskites on the parent perovskite as well as their impact on band alignment and device performance.
The content of this RSS Feed (c) The Royal Society of Chemistry
24 Oct 14:20

[ASAP] Ternary Dumbbell Nanowires for Photocatalytic Hydrogen Production

by Yuexing Chen, Kaituo Dong, and Lilac Amirav

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.2c01242
21 Oct 13:49

[ASAP] Tetraphenylethene-Based Emissive Pt(II) Coordination Polymer toward Artificial Light-Harvesting Systems with Sequential Energy Transfer

by Shakil Ahmed, Atul Kumar, and Partha Sarathi Mukherjee

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.2c02409
18 Oct 15:33

[ASAP] Catalyst–Support Surface Charge Effects on Structure and Activity of IrNi-Based Oxygen Evolution Reaction Catalysts Deposited on Tin-Oxide Supports

by Hoang Phi Tran, Hong Nhan Nong, Hyung-Suk Oh, Malte Klingenhof, Matthias Kroschel, Benjamin Paul, Jessica Hübner, Detre Teschner, and Peter Strasser

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.2c01098
18 Oct 15:32

[ASAP] Liquid-Phase Epitaxial Growth of Large-Area MAPbBr3–nCln/CsPbBr3 Perovskite Single-Crystal Heterojunction for Enhancing Sensitivity and Stability of X‑ray Detector

by Fucai Cui, Peng Zhang, Longzhen Zhang, Yunqiu Hua, Xue Sun, Xiang Li, Guodong Zhang, and Xutang Tao

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.2c02266
18 Oct 15:32

[ASAP] High-Throughput Characterization of Transition Metal Dichalcogenide Alloys: Thermodynamic Stability and Electronic Band Alignment

by Christopher Linderälv, J. Magnus Rahm, and Paul Erhart

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.2c01176
17 Oct 07:33

Polarity and moisture induced trans-grain-boundaries 2D/3D coupling structure for flexible perovskite solar cells with high mechanical reliability and efficiency

Energy Environ. Sci., 2022, 15,5168-5180
DOI: 10.1039/D2EE01879A, Paper
Ying Yan, Ruiting Wang, Qingshun Dong, Yanfeng Yin, Linghui Zhang, Zhenhuang Su, Chenyue Wang, Jiangshan Feng, Minhuan Wang, Jing Liu, Hongru Ma, Yulin Feng, Wenzhe Shang, Zhiyong Wang, Mingzhu Pei, Yudi Wang, Shengye Jin, Jiming Bian, Xingyu Gao, Shengzhong Liu, Yantao Shi
Precise control of the growth of 2D perovskites on 3D perovskites to form “trans-grain boundaries” 2D/3D structure for the preparation of flexible perovskite solar cells with a certified PCE up to 22.1% and excellent mechanical stability.
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10 Oct 08:27

A structurally simple linear conjugated polymer toward practical application of organic solar cells

Energy Environ. Sci., 2022, 15,4789-4797
DOI: 10.1039/D2EE02769K, Paper
Bingyan Yin, Shuting Pang, Zhili Chen, Wanyuan Deng, Zhitian Liu, Chunhui Duan, Fei Huang, Yong Cao
PTTzF, a linear conjugated polymer donor featuring simple synthesis, high device efficiency, outstanding batch reproducibility, and good universality with different acceptors is a promising candidate for practical application of organic solar cells.
The content of this RSS Feed (c) The Royal Society of Chemistry
10 Oct 08:00

Electrifying the production of sustainable aviation fuel: the risks, economics, and environmental benefits of emerging pathways including CO2

Energy Environ. Sci., 2022, 15,4798-4812
DOI: 10.1039/D2EE02439J, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
R. Gary Grim, Dwarak Ravikumar, Eric C. D. Tan, Zhe Huang, Jack R. Ferrell, Michael Resch, Zhenglong Li, Chirag Mevawala, Steven D. Phillips, Lesley Snowden-Swan, Ling Tao, Joshua A. Schaidle
Emerging CO2 to SAF pathways facilitates diversification of fuel production with the potential for a near carbon neutral footprint.
The content of this RSS Feed (c) The Royal Society of Chemistry
10 Oct 08:00

Design of semitransparent tantalum nitride photoanode for efficient and durable solar water splitting

Energy Environ. Sci., 2022, 15,4761-4775
DOI: 10.1039/D2EE02090D, Paper
Open Access Open Access
Tomohiro Higashi, Hiroshi Nishiyama, Vikas Nandal, Yuriy Pihosh, Yudai Kawase, Ryota Shoji, Mamiko Nakabayashi, Yutaka Sasaki, Naoya Shibata, Hiroyuki Matsuzaki, Kazuhiko Seki, Kazuhiro Takanabe, Kazunari Domen
A semitransparent Ta3N5 photoanode is designed for efficient and durable solar water splitting. The Ta3N5-CuInSe2 tandem device exhibits an initial and stabilized solar-to-hydrogen efficiency of ∼9% (highest for metal oxides/nitrides) and 4%, respectively.
The content of this RSS Feed (c) The Royal Society of Chemistry
26 Sep 16:51

A molecular weight-regulated sequential deposition strategy enabling semitransparent organic solar cells with the light utilization efficiency of over 5%

Energy Environ. Sci., 2022, 15,4776-4788
DOI: 10.1039/D2EE02392J, Paper
Xuexiang Huang, Yujun Cheng, Yuan Fang, Lifu Zhang, Xiaotian Hu, Sang Young Jeong, Hean Zhang, Han Young Woo, Feiyan Wu, Lie Chen
In this work, a molecular weight-regulated efficient SD strategy is firstly employed to improve the performance of the ST-OSCs. More importantly, the light utilization efficiency (LUE) of 5.01% is obtained.
The content of this RSS Feed (c) The Royal Society of Chemistry
26 Sep 16:51

A brief history of zinc–air batteries: 140 years of epic adventures

Energy Environ. Sci., 2022, 15,4542-4553
DOI: 10.1039/D2EE02440C, Perspective
Jia-Ning Liu, Chang-Xin Zhao, Juan Wang, Ding Ren, Bo-Quan Li, Qiang Zhang
A retrospect of the history of zinc–air batteries is provided, including four historical stages regarding the birth, the rising, the stagnancy, and the revival of zinc–air batteries.
The content of this RSS Feed (c) The Royal Society of Chemistry
23 Sep 16:50

Thermodynamic limits of atmospheric water harvesting

Energy Environ. Sci., 2022, 15,4025-4037
DOI: 10.1039/D2EE01071B, Perspective
Akshay K. Rao, Andrew J. Fix, Yun Chi Yang, David M. Warsinger
We use 2nd law analysis to obtain the maximum and practical efficiency for common open system atmospheric water harvesting methods. We apply this metric with supercomputing to map performance globally and suggest key system variables for improvement.
The content of this RSS Feed (c) The Royal Society of Chemistry
23 Sep 16:49

A comparative analysis of the efficiency, timing, and permanence of CO2 removal pathways

Energy Environ. Sci., 2022, 15,4389-4403
DOI: 10.1039/D2EE01021F, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Solene Chiquier, Piera Patrizio, Mai Bui, Nixon Sunny, Niall Mac Dowell
Carbon dioxide removal (CDR) is essential to deliver the climate objectives of the Paris Agreement. Whilst several CDR pathways have been identified, they vary significantly in terms of CO2 removal efficiency, timing, and permanence.
The content of this RSS Feed (c) The Royal Society of Chemistry
23 Sep 16:49

How membrane characteristics influence the performance of CO2 and CO electrolysis

Energy Environ. Sci., 2022, 15,4440-4469
DOI: 10.1039/D2EE01818G, Review Article
Sahil Garg, Carlos A. Giron Rodriguez, Thomas E. Rufford, John R. Varcoe, Brian Seger
Due to the ability to produce sustainably carbon-based chemicals and fuels, CO2 electrolysis and the closely related CO electrolysis are advancing rapidly from fundamental studies toward industrial applications.
The content of this RSS Feed (c) The Royal Society of Chemistry
23 Sep 16:49

Sequentially regular polymer acceptors featuring flexible spacers for high-performance and mechanically robust all-polymer solar cells

Energy Environ. Sci., 2022, 15,4672-4685
DOI: 10.1039/D2EE02523J, Paper
Open Access Open Access
Jin-Woo Lee, Cheng Sun, Sun-Woo Lee, Geon-U. Kim, Sheng Li, Cheng Wang, Taek-Soo Kim, Yun-Hi Kim, Bumjoon J. Kim
We report a new molecular design of sequentially regular polymerized small-molecule-acceptors containing flexible spacer (FS) units (PYFS-Reg) to achieve all-polymer solar cells with both high-performance and mechanical stretchability.
The content of this RSS Feed (c) The Royal Society of Chemistry
23 Sep 16:49

Stable perovskite solar cells with 25.17% efficiency enabled by improving crystallization and passivating defects synergistically

Energy Environ. Sci., 2022, 15,4700-4709
DOI: 10.1039/D2EE02277J, Paper
Yihui Wu, Qi Wang, Yuting Chen, Wuke Qiu, Qiang Peng
Both improving crystallization and passivating the defects of a perovskite film have been realized by introducing 2-amidinopyrimidine hydrochloride, which resulted in an efficiency of 25.17% along with long-term operational stability.
The content of this RSS Feed (c) The Royal Society of Chemistry
23 Sep 16:48

Capacitor-inspired high-performance and durable moist-electric generator

Energy Environ. Sci., 2022, 15,4584-4591
DOI: 10.1039/D2EE02046G, Paper
Zhaoyang Sun, Xian Wen, Liming Wang, Jianyong Yu, Xiaohong Qin
Harvesting clean and sustainable energy from moisture has emerged as a promising technology to break the paradigm of traditional energy generation by utilizing fossil fuels.
The content of this RSS Feed (c) The Royal Society of Chemistry
23 Sep 16:48

Elimination of light-induced degradation at the nickel oxide-perovskite heterojunction by aprotic sulfonium layers towards long-term operationally stable inverted perovskite solar cells

Energy Environ. Sci., 2022, 15,4612-4624
DOI: 10.1039/D2EE01801B, Paper
Open Access Open Access
Tianhao Wu, Luis K. Ono, Rengo Yoshioka, Chenfeng Ding, Congyang Zhang, Silvia Mariotti, Jiahao Zhang, Kirill Mitrofanov, Xiao Liu, Hiroshi Segawa, Ryota Kabe, Liyuan Han, Yabing Qi
This work introduces an aprotic sulfonium buffer layer at the nickel oxide–perovskite heterojunction to eliminate the multi-step photochemical reactions, which leads to inverted perovskite solar cells with long-term operational stability.
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23 Sep 16:47

[ASAP] Jahn−Teller Distortion-Stabilized Halide Double Perovskites with Unusual Rock-Salt-type Ordering of Divalent B-Site Cations

by Guoqi Ji and Zewen Xiao

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.2c01496
23 Sep 16:44

[ASAP] Designing Dual-Functional Metal–Organic Frameworks for Photocatalysis

by Nan-Chieh Chiu, Makenzie T. Nord, Longteng Tang, Logan S. Lancaster, Jacob S. Hirschi, Samuel K. Wolff, Elan Maiti Hutchinson, Konstantinos A. Goulas, William F. Stickle, Tim J. Zuehlsdorff, Chong Fang, and Kyriakos C. Stylianou

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.2c02089
23 Sep 16:43

[ASAP] Phase-Specific Vapor–Liquid–Solid Growth of GeSe and GeSe2 van der Waals Nanoribbons and Formation of GeSe–GeSe2 Heterostructures

by Eli Sutter, Jacob S. French, and Peter Sutter

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.2c02162
23 Sep 16:43

[ASAP] Stimulating Efficient and Stable Ultralong Phosphorescence of 2D Perovskites by Dual-Mode Triplet Exciton Stabilization

by Lei Ge, Yang Wang, Xiang Gao, Min Li, Runqi Zhang, Siyu Liu, Yihang Yu, Mingguang Li, Ligang Xu, Ye Tao, Runfeng Chen, and Wenzhen Lv

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.2c01501
23 Sep 16:42

[ASAP] Optimized Metal Deficiency-Induced Operando Phase Transformation Enhances Charge Polarization Promoting Hydrogen Evolution Reaction

by Ashutosh Kumar Singh, Debabrata Bagchi, Sumanta Sarkar, Saurav Ch. Sarma, Dundappa Mumbaraddi, Seethiraju D. Ramarao, and Sebastian C. Peter

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.2c02667