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08 Feb 16:21

Boron nitride nanosheets as barrier enhancing fillers in melt processed composites

Nanoscale, 2015, 7,4443-4450
DOI: 10.1039/C4NR07228F, Paper
Shaobo Xie, Oana M. Istrate, Peter May, Sebastian Barwich, Alan P. Bell, Umar Khan, Jonathan N. Coleman
In this work we have used melt-processing to mix liquid-exfoliated boron-nitride nanosheets with PET to produce composites for gas barrier applications.
The content of this RSS Feed (c) The Royal Society of Chemistry
08 Feb 16:20

Light-Emitting Quantum Dot Transistors: Emission at High Charge Carrier Densities

by Julia Schornbaum, Yuriy Zakharko, Martin Held, Stefan Thiemann, Florentina Gannott, and Jana Zaumseil

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Nano Letters
DOI: 10.1021/nl504582d
Publication Date (Web): February 5, 2015
08 Feb 16:19

The sequential continuous-flow hydrothermal synthesis of molybdenum disulphide

Chem. Commun., 2015, 51,4048-4050
DOI: 10.1039/C4CC10158H, Communication
Peter W. Dunne, Alexis S. Munn, Chris L. Starkey, Edward H. Lester
MoS2 has been prepared by the sequential formation of thiomolybdates, conversion to MoS3 and decomposition to MoS2 in a continuous-flow hydrothermal process.
The content of this RSS Feed (c) The Royal Society of Chemistry
08 Feb 16:18

Recent advances in magnetic nanoparticle-based multi-modal imaging

Chem. Soc. Rev., 2015, 44,4501-4516
DOI: 10.1039/C4CS00345D, Tutorial Review
Tae-Hyun Shin, Youngseon Choi, Soojin Kim, Jinwoo Cheon
This tutorial review discusses the concept and up-to-date applications of magnetic nanoparticle-based multi-modal imaging.
The content of this RSS Feed (c) The Royal Society of Chemistry
08 Feb 16:17

The tunable electronic structure and mechanical properties of halogenated silicene: a first-principles study

J. Mater. Chem. C, 2015, 3,3087-3094
DOI: 10.1039/C4TC02758B, Paper
Wei-Bing Zhang, Zhi-Bo Song, Liu-Ming Dou
Halogenated silicene, with enhanced stability compared with silicene, presents a moderate and tunable direct gap with small carrier effective mass and improved elastic properties.
The content of this RSS Feed (c) The Royal Society of Chemistry
08 Feb 16:17

Film thickness and traction curves of wind turbine gear oils

Publication date: June 2015
Source:Tribology International, Volume 86
Author(s): Carlos M.C.G. Fernandes , Pedro M.T. Marques , Ramiro C. Martins , Jorge H.O. Seabra
The film thickness and the traction curves of four fully formulated wind turbine gear oils were measured on a ball-on-disc device. All oils have the same viscosity grade (ISO VG 320) and different formulations: ester, mineral, PAO and mineral+PAMA. Film thickness and traction coefficient results will be presented. The film thickness measurements were compared with predictions using film thickness equations from the literature.

08 Feb 16:11

Electrically Driven Reversible Insulator–Metal Phase Transition in 1T-TaS2

by Matthew J. Hollander, Yu Liu, Wen-Jian Lu, Li-Jun Li, Yu-Ping Sun, Joshua A. Robinson and Suman Datta

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Nano Letters
DOI: 10.1021/nl504662b
08 Feb 16:09

Two-Dimensional MoS2 Nanosheet-Coated Bi2S3 Discoids: Synthesis, Formation Mechanism, and Photocatalytic Application

by Bo Weng, Xin Zhang, Nan Zhang, Zi-Rong Tang and Yi-Jun Xu

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Langmuir
DOI: 10.1021/la504549y
08 Feb 15:34

The German Chemical Society (GDCh) and Nazi Germany

by Henning Hopf
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“National Socialists were enthusiastic about technology and the natural sciences. Chemistry was of the highest importance in helping the Third Reich to become independent of imports from foreign countries and was crucial for the preparation of the war. The German chemical societies were of major importance in coordinating the contribution of their members to the war …” Read more in the Editorial by Henning Hopf.

08 Feb 15:32

Thin films of tin(II) sulphide (SnS) by aerosol-assisted chemical vapour deposition (AACVD) using tin(II) dithiocarbamates as single-source precursors

Publication date: 1 April 2015
Source:Journal of Crystal Growth, Volume 415
Author(s): Punarja Kevin , David J. Lewis , James Raftery , M. Azad Malik , Paul O’Brien
The synthesis of the asymmetric dithiocarbamates of tin(II) with the formula [Sn(S2CNRR׳)2] (where R=Et, R׳=n-Bu (1); R=Me, R׳=n-Bu (2); R=R׳=Et (3)) and their use for the deposition of SnS thin films by aerosol-assisted chemical vapour deposition (AACVD) is described. The effects of temperature and the concentration of the precursors on deposition were investigated. The stoichiometry of SnS was best at higher concentrations of precursors (250mM) and at 450°C. The direct electronic band gap of the SnS produced by this method was estimated from optical absorbance measurements as 1.2eV. The composition of films was confirmed by powder X-ray diffraction (p-XRD) and energy dispersive analysis of X-rays (EDAX) spectroscopy.

08 Feb 15:31

Thermoelectric Response of Bulk and Monolayer MoSe2 and WSe2

by S. Kumar and U. Schwingenschlögl

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Chemistry of Materials
DOI: 10.1021/cm504244b
08 Feb 15:31

Self-Limiting Layer-by-Layer Oxidation of Atomically Thin WSe2

by Mahito Yamamoto, Sudipta Dutta, Shinya Aikawa, Shu Nakaharai, Katsunori Wakabayashi, Michael S. Fuhrer, Keiji Ueno and Kazuhito Tsukagoshi

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Nano Letters
DOI: 10.1021/nl5049753
04 Feb 15:02

Efficiency of Hole Transfer from Photoexcited Quantum Dots to Covalently Linked Molecular Species

by Tina X. Ding, Jacob H. Olshansky, Stephen R. Leone and A. Paul Alivisatos

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Journal of the American Chemical Society
DOI: 10.1021/ja512278a
04 Feb 14:31

A Power Pack Based on Organometallic Perovskite Solar Cell and Supercapacitor

by Xiaobao Xu, Shaohui Li, Hua Zhang, Yan Shen, Shaik M. Zakeeruddin, Michael Graetzel, Yi-Bing Cheng and Mingkui Wang

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ACS Nano
DOI: 10.1021/nn506651m
03 Feb 11:31

How to get between the sheets: a review of recent works on the electrochemical exfoliation of graphene materials from bulk graphite

DJL

Carry On Graphene

Nanoscale, 2015, 7,6944-6956
DOI: 10.1039/C4NR06942K, Review Article
A. M. Abdelkader, A. J. Cooper, R. A. W. Dryfe, I. A. Kinloch
This review aims to summarise recent relevant electrochemical approaches to the production of graphene and related materials.
The content of this RSS Feed (c) The Royal Society of Chemistry
03 Feb 11:26

A novel synthetic route to transition metal phosphide nanoparticles

Dalton Trans., 2015, 44,5503-5509
DOI: 10.1039/C4DT03886J, Paper
Zhiwei Yao, Meng Li, Xiang Wang, Xue Qiao, Jiang Zhu, Yu Zhao, Guanzhang Wang, Jingzhou Yin, Haiyan Wang
A novel synthetic route was developed to prepare nano-sized and well-dispersed phosphides of transition metals (Mo, Ni, and Co) from their corresponding oxide precursors.
The content of this RSS Feed (c) The Royal Society of Chemistry
03 Feb 11:23

2D materials: Silicene transistors

by Guy Le Lay

Nature Nanotechnology. doi:10.1038/nnano.2015.10

Author: Guy Le Lay

Artificially synthesized silicene — an atomically thin layer of silicon — is set to rival natural layered materials in the development of field-effect transistors.

03 Feb 11:23

Silicene field-effect transistors operating at room temperature

by Li Tao

Nature Nanotechnology. doi:10.1038/nnano.2014.325

Authors: Li Tao, Eugenio Cinquanta, Daniele Chiappe, Carlo Grazianetti, Marco Fanciulli, Madan Dubey, Alessandro Molle & Deji Akinwande

Free-standing silicene, a silicon analogue of graphene, has a buckled honeycomb lattice and, because of its Dirac bandstructure combined with its sensitive surface, offers the potential for a widely tunable two-dimensional monolayer, where external fields and interface interactions can be exploited to influence fundamental properties such as bandgap and band character for future nanoelectronic devices. The quantum spin Hall effect, chiral superconductivity, giant magnetoresistance and various exotic field-dependent states have been predicted in monolayer silicene. Despite recent progress regarding the epitaxial synthesis of silicene and investigation of its electronic properties, to date there has been no report of experimental silicene devices because of its air stability issue. Here, we report a silicene field-effect transistor, corroborating theoretical expectations regarding its ambipolar Dirac charge transport, with a measured room-temperature mobility of ∼100 cm2 V–1 s–1 attributed to acoustic phonon-limited transport and grain boundary scattering. These results are enabled by a growth–transfer–fabrication process that we have devised—silicene encapsulated delamination with native electrodes. This approach addresses a major challenge for material preservation of silicene during transfer and device fabrication and is applicable to other air-sensitive two-dimensional materials such as germanene and phosphorene. Silicene's allotropic affinity with bulk silicon and its low-temperature synthesis compared with graphene or alternative two-dimensional semiconductors suggest a more direct integration with ubiquitous semiconductor technology.

03 Feb 11:16

Hydrothermal Continuous Flow Synthesis and Exfoliation of NiCo Layered Double Hydroxide Nanosheets for Enhanced Oxygen Evolution Catalysis

by Hanfeng Liang, Fei Meng, Miguel Cabán-Acevedo, Linsen Li, Audrey Forticaux, Lichen Xiu, Zhoucheng Wang and Song Jin

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Nano Letters
DOI: 10.1021/nl504872s
03 Feb 11:12

Solid Solution Hardening of Molecular Crystals: Tautomeric Polymorphs of Omeprazole

by Manish Kumar Mishra, Upadrasta Ramamurty and Gautam R. Desiraju
DJL

A medicine I can't live without these days

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Journal of the American Chemical Society
DOI: 10.1021/ja512817f
03 Feb 11:10

Solution-Processed Graphene Quantum Dot Deep-UV Photodetectors

by Qing Zhang, Jiansheng Jie, Senlin Diao, Zhibin Shao, Qiao Zhang, Liu Wang, Wei Deng, Weida Hu, Hui Xia, Xiaodong Yuan and Shuit-Tong Lee

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ACS Nano
DOI: 10.1021/acsnano.5b00437
03 Feb 11:09

High-Quality Black Phosphorus Atomic Layers by Liquid-Phase Exfoliation

by Poya Yasaei, Bijandra Kumar, Tara Foroozan, Canhui Wang, Mohammad Asadi, David Tuschel, J. Ernesto Indacochea, Robert F. Klie, Amin Salehi-Khojin
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Recent isolation of black phosphorus atomic layers (known as phosphorene) has revealed its great potential for use as an alternative 2D semiconductor in many areas of electronics and optoelectronics. Liquid-phase exfoliation is utilized to produce high-quality black phosphorus nanoflakes with thicknesses down to a monolayer in the form of uniform and stable dispersions, allowing for pace toward practical applications.

03 Feb 11:09

Growth dynamics and gas transport mechanism of nanobubbles in graphene liquid cells

by Dongha Shin

Article

Nanobubbles in liquid phase are puzzling, because their internal pressure is estimated to be unphysically large. Here, Shin et al . visualize the dynamics of nanobubbles in water encapsulated by graphene membrane and show fast gas diffusion through ultrathin water layer between two coalescing bubbles.

Nature Communications doi: 10.1038/ncomms7068

Authors: Dongha Shin, Jong Bo Park, Yong-Jin Kim, Sang Jin Kim, Jin Hyoun Kang, Bora Lee, Sung-Pyo Cho, Byung Hee Hong, Konstantin S Novoselov

30 Jan 12:03

Ocular Drug Delivery Nanowafer with Enhanced Therapeutic Efficacy

by Xiaoyong Yuan, Daniela C. Marcano, Crystal S. Shin, Xia Hua, Lucas C. Isenhart, Stephen C. Pflugfelder and Ghanashyam Acharya

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ACS Nano
DOI: 10.1021/nn506599f
30 Jan 11:46

Gate-tunable phase transitions in thin flakes of 1T-TaS2

by Yijun Yu

Nature Nanotechnology. doi:10.1038/nnano.2014.323

Authors: Yijun Yu, Fangyuan Yang, Xiu Fang Lu, Ya Jun Yan, Yong-Heum Cho, Liguo Ma, Xiaohai Niu, Sejoong Kim, Young-Woo Son, Donglai Feng, Shiyan Li, Sang-Wook Cheong, Xian Hui Chen & Yuanbo Zhang

30 Jan 11:41

Identifying the Optimum Morphology in High-Performance Perovskite Solar Cells

by Guijun Li, Kwong Lung Ching, Jacob Y. L. Ho, Man Wong, Hoi-Sing Kwok
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The study of the perovskite solar cells provides insight into the optimum morphology. A bilayer structure is required for efficient solar cells, and one with a high efficiencies of up to 15.2% and an open-circuit voltage (Voc) up to 1110 mV is demonstrated. Furthermore, the 80% high yield also paves the way for the possibility of mass production in the future.

30 Jan 11:40

Compression-Induced Deformation of Individual Metal–Organic Framework Microcrystals

by Zhi Su, Yu-Run Miao, Shi-Min Mao, Guang-Hui Zhang, Shen Dillon, Jeffrey T. Miller and Kenneth S. Suslick

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Journal of the American Chemical Society
DOI: 10.1021/ja5113436
30 Jan 11:25

Ultrathin FeSe2 Nanosheets: Controlled Synthesis and Application as a Heterogeneous Catalyst in Dye-Sensitized Solar Cells

by Shoushuang Huang, Qingquan He, Wenlong Chen, Qiquan Qiao, Jiantao Zai, Xuefeng Qian

Abstract

Two-dimensional (2D) semiconducting nanosheets have emerged as an important field of materials, owing to their unique properties and potential applications in areas ranging from electronics to catalysis. However, the controlled synthesis of ultrathin 2D nanosheets remains a great challenge, due to the lack of an intrinsic driving force for anisotropic growth. High-quality ultrathin 2D FeSe2 nanosheets with average thickness below 7 nm have been synthesized on large scale by a facile solution method, and a formation mechanism has been proposed. Due to their favorable structural features, the as-synthesized ultrathin FeSe2 nanosheets exhibit excellent electrocatalytic activity for the reduction of triiodide to iodide and low charge-transfer resistance at the electrolyte–electrode interface in dye-sensitized solar cells (DSSCs). The DSSCs with FeSe2 nanosheets as counter electrode material achieve a high power conversion efficiency of 7.53 % under a simulated solar illumination of 100 mW cm−2 (AM 1.5), which is comparable with that of Pt-based devices (7.47 %).

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Sheets ahead: Ultrathin 2D non-layered FeSe2 nanosheets with average thickness below 7 nm were prepared by a facile hot-injection method. The resulting nanosheets exhibit favorable structural features that render the sample a highly active and durable catalyst for the reduction of triiodide to iodide in dye-sensitized solar cells.

30 Jan 11:24

Graphene-like Zinc Substituted Hydroxyapatite

by Jun Ma and Jinli Qin

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Crystal Growth & Design
DOI: 10.1021/cg501659x
30 Jan 11:24

Atomistic Description of Thiostannate-Capped CdSe Nanocrystals: Retention of Four-Coordinate SnS4 Motif and Preservation of Cd-Rich Stoichiometry

by Loredana Protesescu, Maarten Nachtegaal, Oleksandr Voznyy, Olga Borovinskaya, Aaron J. Rossini, Lyndon Emsley, Christophe Copéret, Detlef Günther, Edward H. Sargent and Maksym V. Kovalenko

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Journal of the American Chemical Society
DOI: 10.1021/ja510862c