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31 Mar 23:15

[ASAP] Magnitude and Spatial Distribution Control of the Supercurrent in Bi2O2Se-Based Josephson Junction

by Jianghua Ying†‡, Jiangbo He†‡, Guang Yang†‡, Mingli Liu†‡, Zhaozheng Lyu†‡, Xiang Zhang†‡, Huaiyuan Liu†§, Kui Zhao†‡, Ruiyang Jiang†‡, Zhongqing Ji†¶, Jie Fan†¶, Changli Yang†, Xiunian Jing†¶, Guangtong Liu†¶, Xuewei Cao§, Xuefeng Wang#, Li Lu*†‡¶??, and Fanming Qu*†‡¶?

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Nano Letters
DOI: 10.1021/acs.nanolett.0c00025
28 Mar 22:43

[ASAP] Formation of Defects in Two-Dimensional MoS2 in the Transmission Electron Microscope at Electron Energies below the Knock-on Threshold: The Role of Electronic Excitations

by Silvan Kretschmer*†?, Tibor Lehnert‡?, Ute Kaiser‡, and Arkady V. Krasheninnikov†§

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Nano Letters
DOI: 10.1021/acs.nanolett.0c00670
28 Mar 22:43

[ASAP] Single-Carrier Transport in Graphene/hBN Superlattices

by Takuya Iwasaki*†‡, Shu Nakaharai‡, Yutaka Wakayama‡, Kenji Watanabe§, Takashi Taniguchi§, Yoshifumi Morita?, and Satoshi Moriyama*‡

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Nano Letters
DOI: 10.1021/acs.nanolett.9b05332
28 Mar 22:43

[ASAP] Magnetic Enhancement for Hydrogen Evolution Reaction on Ferromagnetic MoS2 Catalyst

by Wenda Zhou†‡?, Mingyue Chen†?, Manman Guo†, Aijun Hong†, Ting Yu†, Xingfang Luo†, Cailei Yuan*†, Wen Lei§, and Shouguo Wang*‡

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Nano Letters
DOI: 10.1021/acs.nanolett.0c00845
28 Mar 22:43

[ASAP] Controllable Thickness Inhomogeneity and Berry Curvature Engineering of Anomalous Hall Effect in SrRuO3 Ultrathin Films

by Lingfei Wang*†‡?, Qiyuan Feng??, Han Gyeol Lee†‡, Eun Kyo Ko†‡, Qingyou Lu*?§, and Tae Won Noh*†‡

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Nano Letters
DOI: 10.1021/acs.nanolett.9b05206
28 Mar 22:43

[ASAP] Nitrogen-Defective Polymeric Carbon Nitride Nanolayer Enabled Efficient Electrocatalytic Nitrogen Reduction with High Faradaic Efficiency

by Guiming Peng†, Jiawen Wu†, Mingzhan Wang†, Jens Niklas‡, Hua Zhou§, and Chong Liu*†

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Nano Letters
DOI: 10.1021/acs.nanolett.0c00698
28 Mar 22:41

Scaling, rotation, and channeling behavior of helical and skyrmion spin textures in thin films of Te-doped Cu2OSeO3

by Han, M.- G., Garlow, J. A., Kharkov, Y., Camacho, L., Rov, R., Sauceda, J., Vats, G., Kisslinger, K., Kato, T., Sushkov, O., Zhu, Y., Ulrich, C., Söhnel, T., Seidel, J.

Topologically nontrivial spin textures such as vortices, skyrmions, and monopoles are promising candidates as information carriers for future quantum information science. Their controlled manipulation including creation and annihilation remains an important challenge toward practical applications and further exploration of their emergent phenomena. Here, we report controlled evolution of the helical and skyrmion phases in thin films of multiferroic Te-doped Cu2OSeO3 as a function of material thickness, dopant, temperature, and magnetic field using in situ Lorentz phase microscopy. We report two previously unknown phenomena in chiral spin textures in multiferroic Cu2OSeO3: anisotropic scaling and channeling with a fixed-Q state. The skyrmion channeling effectively suppresses the recently reported second skyrmion phase formation at low temperature. Our study provides a viable way toward controlled manipulation of skyrmion lattices, envisaging chirality-controlled skyrmion flow circuits and enabling precise measurement of emergent electromagnetic induction and topological Hall effects in skyrmion lattices.

25 Mar 21:53

[ASAP] Monolithic Interface Contact Engineering to Boost Optoelectronic Performances of 2D Semiconductor Photovoltaic Heterojunctions

by Seunghoon Yang†, Janghwan Cha‡, Jong Chan Kim§, Donghun Lee†, Woong Huh†, Yoonseok Kim†, Seong Won Lee?, Hong-Gyu Park†?, Hu Young Jeong?, Suklyun Hong*‡, Gwan-Hyoung Lee*#???, and Chul-Ho Lee*†

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Nano Letters
DOI: 10.1021/acs.nanolett.9b05162
25 Mar 21:52

[ASAP] Intrinsic and Extrinsic Defect-Related Excitons in TMDCs

by Kyrylo Greben*, Sonakshi Arora†, Moshe G. Harats, and Kirill I. Bolotin*

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Nano Letters
DOI: 10.1021/acs.nanolett.9b05323
25 Mar 21:52

[ASAP] Nonvolatile Rewritable Frequency Tuning of a Nanoelectromechanical Resonator Using Photoinduced Doping

by David Miller†‡§, Andrew Blaikie†‡§, and Benjami´n J. Alema´n*†‡§?

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Nano Letters
DOI: 10.1021/acs.nanolett.9b05003
25 Mar 21:52

Breath figure-derived porous semiconducting films for organic electronics

by Zhang, X., Wang, B., Huang, L., Huang, W., Wang, Z., Zhu, W., Chen, Y., Mao, Y., Facchetti, A., Marks, T. J.

Porous semiconductor film morphologies facilitate fluid diffusion and mass transport into the charge-carrying layers of diverse electronic devices. Here, we report the nature-inspired fabrication of several porous organic semiconductor-insulator blend films [semiconductor: P3HT (p-type polymer), C8BTBT (p-type small-molecule), and N2200 (n-type polymer); insulator: PS] by a breath figure patterning method and their broad and general applicability in organic thin-film transistors (OTFTs), gas sensors, organic electrochemical transistors (OECTs), and chemically doped conducting films. Detailed morphological analysis of these films demonstrates formation of textured layers with uniform nanopores reaching the bottom substrate with an unchanged solid-state packing structure. Device data gathered with both porous and dense control semiconductor films demonstrate that the former films are efficient TFT semiconductors but with added advantage of enhanced sensitivity to gases (e.g., 48.2%/ppm for NO2 using P3HT/PS), faster switching speeds (4.7 s for P3HT/PS OECTs), and more efficient molecular doping (conductivity, 0.13 S/m for N2200/PS).

25 Mar 21:51

Zero-energy bound states in the high-temperature superconductors at the two-dimensional limit

by Liu, C., Chen, C., Liu, X., Wang, Z., Liu, Y., Ye, S., Wang, Z., Hu, J., Wang, J.

Majorana zero modes (MZMs) that obey the non-Abelian statistics have been intensively investigated for potential applications in topological quantum computing. The prevailing signals in tunneling experiments "fingerprinting" the existence of MZMs are the zero-energy bound states (ZEBSs). However, nearly all of the previously reported ZEBSs showing signatures of the MZMs are observed in difficult-to-fabricate heterostructures at very low temperatures and additionally require applied magnetic field. Here, by using in situ scanning tunneling spectroscopy, we detect the ZEBSs upon the interstitial Fe adatoms deposited on two different high-temperature superconducting one-unit-cell iron chalcogenides on SrTiO3(001). The spectroscopic results resemble the phenomenological characteristics of the MZMs inside the vortex cores of topological superconductors. Our experimental findings may extend the MZM explorations in connate topological superconductors toward an applicable temperature regime and down to the two-dimensional (2D) limit.

20 Mar 22:24

Reversible spin storage in metal oxide--fullerene heterojunctions

by Moorsom, T., Rogers, M., Scivetti, I., Bandaru, S., Teobaldi, G., Valvidares, M., Flokstra, M., Lee, S., Stewart, R., Prokscha, T., Gargiani, P., Alosaimi, N., Stefanou, G., Ali, M., Al MaMari, F., Burnell, G., Hickey, B. J., Cespedes, O.

We show that hybrid MnOx/C60 heterojunctions can be used to design a storage device for spin-polarized charge: a spin capacitor. Hybridization at the carbon-metal oxide interface leads to spin-polarized charge trapping after an applied voltage or photocurrent. Strong electronic structure changes, including a 1-eV energy shift and spin polarization in the C60 lowest unoccupied molecular orbital, are then revealed by x-ray absorption spectroscopy, in agreement with density functional theory simulations. Muon spin spectroscopy measurements give further independent evidence of local spin ordering and magnetic moments optically/electronically stored at the heterojunctions. These spin-polarized states dissipate when shorting the electrodes. The spin storage decay time is controlled by magnetic ordering at the interface, leading to coherence times of seconds to hours even at room temperature.

20 Mar 05:03

[ASAP] ZnSe/ZnS Core/Shell Quantum Dots with Superior Optical Properties through Thermodynamic Shell Growth

by Botao Ji†‡§?, Somnath Koley†‡?, Ilya Slobodkin†‡, Sergei Remennik‡, and Uri Banin*†‡

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Nano Letters
DOI: 10.1021/acs.nanolett.9b05020
20 Mar 05:02

[ASAP] Persistence of Magnetism in Atomically Thin MnPS3 Crystals

by Gen Long†‡?, Hugo Henck†‡?, Marco Gibertini†§, Dumitru Dumcenco†, Zhe Wang†‡, Takashi Taniguchi?, Kenji Watanabe?, Enrico Giannini†, and Alberto F. Morpurgo*†‡

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Nano Letters
DOI: 10.1021/acs.nanolett.9b05165
20 Mar 05:02

[ASAP] Tunable Cherenkov Radiation of Phonon Polaritons in Silver Nanowire/Hexagonal Boron Nitride Heterostructures

by Yiran Zhang†‡?, Cheng Hu†‡?, Bosai Lyu†‡, Hongyuan Li†‡, Zhe Ying†‡, Lele Wang†‡, Aolin Deng†‡, Xingdong Luo†‡, Qiang Gao†‡, Jiajun Chen†‡, Jing Du†‡, Peiyue Shen†‡, Kenji Watanabe§, Takashi Taniguchi§, Ji-Hun Kang?, Feng Wang?#?, Yueheng Zhang†‡, and Zhiwen Shi*†‡

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Nano Letters
DOI: 10.1021/acs.nanolett.0c00419
20 Mar 05:02

[ASAP] Modulation of Junction Modes in SnSe2/MoTe2 Broken-Gap van der Waals Heterostructure for Multifunctional Devices

by Juchan Lee†, Ngoc Thanh Duong†, Seungho Bang, Chulho Park, Duc Anh Nguyen, Hobeom Jeon, Jiseong Jang, Hye Min Oh*, and Mun Seok Jeong*

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Nano Letters
DOI: 10.1021/acs.nanolett.9b04926
20 Mar 05:01

[ASAP] Characteristic Lengths of Interlayer Charge Transfer in Correlated Oxide Heterostructures

by Ganesh Ji Omar†?, Mengsha Li‡, Xiao Chi§, Zhen Huang*?, Zhi Shiuh Lim†?, Saurav Prakash??, Shengwei Zeng†?, Changjian Li‡, Xiaojiang Yu§, Chunhua Tang‡, Dongsheng Song?#, Andrivo Rusydi†§, Thirumalai Venkatesan†‡??¶, Stephen John Pennycook‡, and Ariando Ariando*†??

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Nano Letters
DOI: 10.1021/acs.nanolett.9b05231
20 Mar 05:01

[ASAP] Strain Modulated Superlattices in Graphene

by Riju Banerjee*†, Viet-Hung Nguyen‡, Tomotaroh Granzier-Nakajima†, Lavish Pabbi†, Aurelien Lherbier‡, Anna Ruth Binion†, Jean-Christophe Charlier‡, Mauricio Terrones†, and Eric William Hudson*†

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Nano Letters
DOI: 10.1021/acs.nanolett.9b05108
20 Mar 05:01

[ASAP] Mechanism of Extreme Optical Nonlinearities in Spiral WS2 above the Bandgap

by Xiaopeng Fan†‡?, Zhurun Ji‡?, Ruixiang Fei?, Weihao Zheng†, Wenjing Liu‡, Xiaoli Zhu†, Shula Chen†, Li Yang?, Hongjun Liu§, Anlian Pan*†, and Ritesh Agarwal*‡

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Nano Letters
DOI: 10.1021/acs.nanolett.0c00305
20 Mar 05:01

[ASAP] Proximity Spin–Orbit Torque on a Two-Dimensional Magnet within van der Waals Heterostructure: Current-Driven Antiferromagnet-to-Ferromagnet Reversible Nonequilibrium Phase Transition in Bilayer CrI3

by Kapildeb Dolui†, Marko D. Petrovic´†, Klaus Zollner¶, Petr Plecha´c?‡, Jaroslav Fabian¶, and Branislav K. Nikolic´*†

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Nano Letters
DOI: 10.1021/acs.nanolett.9b04556
20 Mar 05:00

[ASAP] Two-Dimensional Amorphous SnOx from Liquid Metal: Mass Production, Phase Transfer, and Electrocatalytic CO2 Reduction toward Formic Acid

by Tingbiao Yuan†#, Zheng Hu‡#, Yuxin Zhao§, Jingjie Fang?, Jun Lv‡, Qinghua Zhang?, Zhongbin Zhuang?, Lin Gu?, and Shi Hu*†

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Nano Letters
DOI: 10.1021/acs.nanolett.0c00844
20 Mar 04:59

[ASAP] Large Optical Anisotropy in Two-Dimensional Perovskite [CH(NH2)2][C(NH2)3]PbI4 with Corrugated Inorganic Layers

by Chen Fang†, Meng Xu†, Jiaqi Ma†, Jun Wang†, Long Jin†, Ming Xu†‡, and Dehui Li*†‡

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Nano Letters
DOI: 10.1021/acs.nanolett.9b04777
20 Mar 04:59

[ASAP] Correction to “High Aspect Ratio Fin-Ion Sensitive Field Effect Transistor: Compromises toward Better Electrochemical Biosensing”

by Serena Rollo, Dipti Rani, Renaud Leturcq, Wouter Olthuis, and Ce´sar Pascual Garci´a*

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Nano Letters
DOI: 10.1021/acs.nanolett.0c01081
20 Mar 04:58

[ASAP] 3D Manipulation of 2D Materials Using Microdome Polymer

by Yusai Wakafuji†, Rai Moriya*†, Satoru Masubuchi†, Kenji Watanabe‡, Takashi Taniguchi‡†, and Tomoki Machida*†

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Nano Letters
DOI: 10.1021/acs.nanolett.9b05228
20 Mar 04:58

[ASAP] Chiral Second-Harmonic Generation from Monolayer WS2/Aluminum Plasmonic Vortex Metalens

by Wan-Ping Guo†, Wei-Yun Liang‡, Chang-Wei Cheng§, Wei-Lin Wu§, Yen-Ting Wang?|, Quan Sun#, Shuai Zu#, Hiroaki Misawa#?, Pi-Ju Cheng?, Shu-Wei Chang?, Hyeyoung Ahn*‡, Minn-Tsong Lin*†?, and Shangjr Gwo*§??|

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Nano Letters
DOI: 10.1021/acs.nanolett.0c00645
20 Mar 04:58

[ASAP] Boosting Zinc-Ion Storage Capability by Effectively Suppressing Vanadium Dissolution Based on Robust Layered Barium Vanadate

by Xiao Wang†‡, Baojuan Xi*†, Xiaojian Ma†, Zhenyu Feng†, Yuxi Jia‡, Jinkui Feng‡, Yitai Qian†§, and Shenglin Xiong*†

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Nano Letters
DOI: 10.1021/acs.nanolett.0c00732
20 Mar 04:57

[ASAP] A General Wet Transferring Approach for Diffusion-Facilitated Space-Confined Grown Perovskite Single-Crystalline Optoelectronic Thin Films

by Ran Ding, Chun-Ki Liu, Zehan Wu, Feng Guo, Sin-Yi Pang, Lok Wing Wong, Weng Fu Io, Shuoguo Yuan, Man-Chung Wong, Michal Bartlomiej Jedrzejczyk, Jiong Zhao, Feng Yan, and Jianhua Hao*

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Nano Letters
DOI: 10.1021/acs.nanolett.0c00379
20 Mar 04:57

[ASAP] Inter-layer-calated Thin Li Metal Electrode with Improved Battery Capacity Retention and Dendrite Suppression

by Xi Chen, Mingwei Shang, and Junjie Niu*

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Nano Letters
DOI: 10.1021/acs.nanolett.0c00201
20 Mar 04:33

The electronic thickness of graphene

by Rickhaus, P., Liu, M.-H., Kurpas, M., Kurzmann, A., Lee, Y., Overweg, H., Eich, M., Pisoni, R., Taniguchi, T., Watanabe, K., Richter, K., Ensslin, K., Ihn, T.

When two dimensional crystals are atomically close, their finite thickness becomes relevant. Using transport measurements, we investigate the electrostatics of two graphene layers, twisted by = 22° such that the layers are decoupled by the huge momentum mismatch between the K and K' points of the two layers. We observe a splitting of the zero-density lines of the two layers with increasing interlayer energy difference. This splitting is given by the ratio of single-layer quantum capacitance over interlayer capacitance Cm and is therefore suited to extract Cm. We explain the large observed value of Cm by considering the finite dielectric thickness dg of each graphene layer and determine dg 2.6 Å. In a second experiment, we map out the entire density range with a Fabry-Pérot resonator. We can precisely measure the Fermi wavelength in each layer, showing that the layers are decoupled. Our findings are reproduced using tight-binding calculations.