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27 Sep 08:07

The Worldwide Graphene Flake Production

by Alan P. Kauling , Andressa T. Seefeldt , Diego P. Pisoni , Roshini C. Pradeep , Ricardo Bentini , Ricardo V. B. Oliveira , Konstantin S. Novoselov , Antonio H. Castro Neto
Advanced Materials The Worldwide Graphene Flake Production

“Graphene” is produced by hundreds of companies around the globe, but the products show a large variation in their properties. The creation of stringent standards for graphene, which encompasses both physical properties of the material, as well as the requirements from a particular application, is the only way forward to create a healthy and reliable worldwide graphene market.


Abstract

There are hundreds of companies worldwide claiming to produce “graphene,” showing a large variation in its properties. A systematic and reliable protocol is developed to test graphene quality using electron microscopy, atomic force microscopy, Raman spectroscopy, elemental analysis, X‐ray photoelectron spectrometry, and scanning and transmission electron microscopy, which is used to study graphene from 60 producers. The statistical nature of the liquid‐phase exfoliation of graphite is established. It is shown that the current classification of graphene flakes used in the market is erroneous. A new classification is proposed in terms of distribution functions for number of layers and flake size. It is shown unequivocally that the quality of the graphene produced in the world today is rather poor, not optimal for most applications, and most companies are producing graphite microplatelets. This is possibly the main reason for the slow development of graphene applications, which usually require a customized solution in terms of graphene properties. It is argued that the creation of stringent standards for graphene characterization and production, taking into account both the physical properties, as well as the requirements from the particular application, is the only way forward to create a healthy and reliable worldwide graphene market.

25 Sep 16:25

A porous Brønsted superacid as an efficient and durable solid catalyst

J. Mater. Chem. A, 2018, 6,18712-18719
DOI: 10.1039/C8TA06516K, Paper
Qi Sun, Kewei Hu, Kunyue Leng, Xianfeng Yi, Briana Aguila, Yinyong Sun, Anmin Zheng, Xiangju Meng, Shengqian Ma, Feng-Shou Xiao
A porous superacid material with a high surface area and abundant accessible active sites is rationally designed, showing outstanding catalytic activities and durability in industrial chemical transformations.
The content of this RSS Feed (c) The Royal Society of Chemistry
25 Sep 16:23

Micro-patterned anti-icing coatings with dual hydrophobic/hydrophilic properties

J. Mater. Chem. A, 2018, 6,19353-19357
DOI: 10.1039/C8TA06944A, Communication
Sarra Gam-Derouich, Jean Pinson, Aazdine Lamouri, Philippe Decorse, Sébastien Bellynck, Remy Herbaut, Laurent Royon, Claire Mangeney
Anti-icing coatings coupling hierarchical nano/microstructures and dual hydrophobic/hydrophilic features were successfully prepared.
The content of this RSS Feed (c) The Royal Society of Chemistry
21 Sep 15:32

Progress, Challenges, and Opportunities for 2D Material Based Photodetectors

by Mingsheng Long , Peng Wang , Hehai Fang , Weida Hu
Advanced Functional Materials, EarlyView.
20 Sep 12:16

[ASAP] Orthogonal Ambipolar Semiconductors with Inherently Multi-Dimensional Responses for the Discriminative Sensing of Chemical Vapors

by Weiguo Huang, Ryan C. Hayward

TOC Graphic

ACS Applied Materials & Interfaces
DOI: 10.1021/acsami.8b10789
20 Sep 12:12

[ASAP] General Post-annealing Method Enables High-Efficiency Two-Dimensional Perovskite Solar Cells

by Liang Yan, Jun Hu, Zhenkun Guo, Hong Chen, Michael F. Toney, Andrew M. Moran, Wei You

TOC Graphic

ACS Applied Materials & Interfaces
DOI: 10.1021/acsami.8b10230
14 Sep 15:43

Effect of surface/interfacial defects on photo-stability of thick-shell CdZnSeS/ZnS quantum dots

Nanoscale, 2018, 10,18331-18340
DOI: 10.1039/C8NR04224A, Paper
Bo Huang, Hongyu Yang, Lei Zhang, Yufen Yuan, Yiping Cui, Jiayu Zhang
In this report, we mainly discussed the influence of surface/interfacial defects on the exciton recombination in CdZnSeS/ZnS QDs with different shell thicknesses by spectroelectrochemical and ultraviolet irradiation experiments.
The content of this RSS Feed (c) The Royal Society of Chemistry
14 Sep 15:41

Ultra-high performance flexible piezopotential gated In1−xSnxSe phototransistor

Nanoscale, 2018, 10,18642-18650
DOI: 10.1039/C8NR05234D, Paper
Christy Roshini Paul Inbaraj, Roshan Jesus Mathew, Golam Haider, Tzu-Pei Chen, Rajesh Kumar Ulaganathan, Raman Sankar, Krishna Prasad Bera, Yu-Ming Liao, Monika Kataria, Hung-I Lin, Fang Cheng Chou, Yit-Tsong Chen, Chih-Hao Lee, Yang-Fang Chen
Strain tunable flexible InSnSe phototransistor holds promise for the future piezophototronics.
The content of this RSS Feed (c) The Royal Society of Chemistry
23 Aug 15:46

Growth of Large‐Area SnS Films with Oriented 2D SnS Layers for Energy‐Efficient Broadband Optoelectronics

by Malkeshkumar Patel , Joondong Kim , Yu Kwon Kim
Advanced Functional Materials, Volume 28, Issue 40, October 4, 2018.
23 Aug 15:44

Magnetic Resonance Imaging: Time‐Dependent T1–T2 Switchable Magnetic Resonance Imaging Realized by c(RGDyK) Modified Ultrasmall Fe3O4 Nanoprobes (Adv. Funct. Mater. 32/2018)

by Chen Bai , Zhengyang Jia , Lina Song , Wei Zhang , Yi Chen , Fengchao Zang , Ming Ma , Ning Gu , Yu Zhang
Advanced Functional Materials, Volume 28, Issue 32, August 8, 2018.
23 Aug 15:38

Zwitterionic Nanohydrogel Grafted PVDF Membranes with Comprehensive Antifouling Property and Superior Cycle Stability for Oil‐in‐Water Emulsion Separation

by Yuzhang Zhu , Jinliang Wang , Feng Zhang , Shoujian Gao , Aqiang Wang , Wangxi Fang , Jian Jin
Advanced Functional Materials, Volume 28, Issue 40, October 4, 2018.
25 Jul 15:46

[ASAP] Polymeric Nanomedicine with “Lego” Surface Allowing Modular Functionalization and Drug Encapsulation

by Chen Sun, Haipeng Zhang, Shengke Li, Xiangjun Zhang, Qian Cheng, Yuanfu Ding, Lian-Hui Wang, Ruibing Wang

TOC Graphic

ACS Applied Materials & Interfaces
DOI: 10.1021/acsami.8b06598
24 Jul 15:38

High performance strain sensor based on buckypaper for full-range detection of human motions

Nanoscale, 2018, 10,14966-14975
DOI: 10.1039/C8NR02196A, Paper
Chengwei Li, Dongmei Zhang, Chenghao Deng, Peng Wang, Yunping Hu, Yuezhen Bin, Zeng Fan, Lujun Pan
A high-performance strain sensor based on buckypaper has been fabricated and studied.
The content of this RSS Feed (c) The Royal Society of Chemistry
17 Jul 08:07

[ASAP] Facile Two-Step Strategy for the Construction of a Mechanically Stable Three-Dimensional Superhydrophobic Structure for Continuous Oil–Water Separation

by Yaoguang Wang, Yingming Zhu, Chao Yang, Jiahang Liu, Wei Jiang, Bin Liang

TOC Graphic

ACS Applied Materials & Interfaces
DOI: 10.1021/acsami.8b06877
17 Jul 08:03

[ASAP] Controlled Movement of a Smart Miniature Submarine at Various Interfaces

by Ying Chu, Liming Qin, Liang Zhen, Qinmin Pan

TOC Graphic

ACS Applied Materials & Interfaces
DOI: 10.1021/acsami.8b06631
17 Jul 07:56

High-precision nanofabrication technology for metal nanoparticle ensembles using nanotemplate-guided thermal dewetting

Nanoscale, 2018, 10,14390-14394
DOI: 10.1039/C8NR01480A, Communication
Yusuke Niimura, Naoto Oonishi, Kyohei Okubo, Loan Le Thi Ngoc, Edwin T. Carlen
We present a hybrid nanofabrication technology for realizing single-crystalline metal nanoparticle ensembles, such as trimers, heptamers and periodic arrays; well-suited for nanoplasmonics applications.
The content of this RSS Feed (c) The Royal Society of Chemistry
17 Jul 07:53

Chemical vapor deposition growth of ReS2 nanowires for high-performance nanostructured photodetector

Nanoscale, 2018, 10,14976-14983
DOI: 10.1039/C8NR04143A, Paper
Qinwei An, Yang Liu, Renjie Jiang, Xianquan Meng
Single-crystal triclinic ReS2 nanowires were synthesized via CVD and used as the active layer in a nanostructured photodetector with excellent performance.
The content of this RSS Feed (c) The Royal Society of Chemistry
25 Jun 12:55

[ASAP] Nanoparticle Immobilization for Controllable Experiments in Liquid-Cell Transmission Electron Microscopy

by Alex W. Robertson, Guomin Zhu, B. Layla Mehdi, Robert M. J. Jacobs, James De Yoreo, Nigel D. Browning

TOC Graphic

ACS Applied Materials & Interfaces
DOI: 10.1021/acsami.8b03688
25 Jun 12:51

2D SnSe-based vdW heterojunctions: tuning the Schottky barrier by reducing Fermi level pinning

Nanoscale, 2018, 10,13767-13772
DOI: 10.1039/C8NR02843E, Paper
Wenyang Zhou, Yaguang Guo, Jie Liu, Fancy Qian Wang, Xiaoyin Li, Qian Wang
Tuning the Schottky barrier of 2D SnSe-based vdW heterojunctions.
The content of this RSS Feed (c) The Royal Society of Chemistry
25 Jun 11:26

Inkjet Printing of Self‐Assembled 2D Titanium Carbide and Protein Electrodes for Stimuli‐Responsive Electromagnetic Shielding

by Mert Vural , Abdon Pena‐Francesch , Joan Bars‐Pomes , Huihun Jung , Hemanth Gudapati , Christine B. Hatter , Benjamin D. Allen , Babak Anasori , Ibrahim T. Ozbolat , Yury Gogotsi , Melik C. Demirel
Advanced Functional Materials, EarlyView.
25 Jun 11:24

NIR Light‐Triggered Degradable MoTe2 Nanosheets for Combined Photothermal and Chemotherapy of Cancer

by Ning Ma , Ming‐Kang Zhang , Xiao‐Shuang Wang , Lu Zhang , Jun Feng , Xian‐Zheng Zhang
Advanced Functional Materials, Volume 28, Issue 31, August 1, 2018.
25 Jun 11:23

Nanorobots Constructed from Nanoclay: Using Nature to Create Self‐Propelled Autonomous Nanomachines

by Tijana Maric , Carmen C. Mayorga‐Martinez , Bahareh Khezri , Muhammad Zafir Mohamad Nasir , Xinyi Chia , Martin Pumera
Advanced Functional Materials, Volume 28, Issue 40, October 4, 2018.
20 Jun 11:14

New solvent-stabilized few-layer black phosphorus for antibacterial applications

Nanoscale, 2018, 10,12543-12553
DOI: 10.1039/C8NR03513J, Paper
Zhenyu Sun, Yuqin Zhang, Hao Yu, Chao Yan, Yongchao Liu, Song Hong, Hengcong Tao, Alex W. Robertson, Zhuo Wang, Agílio A. H. Pádua
We demonstrate a new and harmless molecule N,N′-dimethylpropyleneurea (DMPU) for efficient exfoliation and dispersion of BP, showing promising antibacterial application.
The content of this RSS Feed (c) The Royal Society of Chemistry
07 Jun 14:51

Hierarchical assembly and superior sodium storage properties of a sea-sponge structured C/SnS@C nanocomposite

J. Mater. Chem. A, 2018, 6,7631-7638
DOI: 10.1039/C8TA00833G, Paper
Shipei Chen, Ke Xing, Jiahao Wen, Ming Wen, Qingsheng Wu, Yi Cui
A novel sea-sponge structured C/SnS@C nanocomposite exhibits excellent cyclability over 2000 cycles as sodium-ion batteries.
The content of this RSS Feed (c) The Royal Society of Chemistry
07 Jun 14:47

The light-up fluorescence of AgNCs in a "DNA bulb"

Nanoscale, 2018, 10,11517-11523
DOI: 10.1039/C8NR02575D, Paper
Yahui Guo, Fumiao Shen, Yuliang Cheng, Yunfei Xie, Hang Yu, Weirong Yao, Hung-Wing Li, He Qian, Renjun Pei
A "bulb"-like DNA structure was firstly used as a synthesizing template, and bright AgNCs were obtained with a quantum yield of 17.2%.
The content of this RSS Feed (c) The Royal Society of Chemistry
07 Jun 14:46

Over 800% efficiency enhancement of all-inorganic quantum-dot light emitting diodes with an ultrathin alumina passivating layer

Nanoscale, 2018, 10,11103-11109
DOI: 10.1039/C8NR01460D, Paper
Wenyu Ji, Huaibin Shen, Han Zhang, Zhihui Kang, Hanzhuang Zhang
The interactions between QDs and s-NiO can be largely suppressed through introducing a ultrathin Al2O3 passivating layer. This highest current efficiency (external quantum efficiency) of 34.1 cd A-1 (8.1%) is achieved.
The content of this RSS Feed (c) The Royal Society of Chemistry
07 Jun 14:42

Single-cell membrane drug delivery using porous pen nanodeposition

Nanoscale, 2018, 10,12704-12712
DOI: 10.1039/C8NR02600A, Paper
Yongliang Yang, Jing Yu, Amir Monemian Esfahani, Kristina Seiffert-Sinha, Ning Xi, Ilsoon Lee, Animesh A. Sinha, Liangliang Chen, Zhiyong Sun, Ruiguo Yang, Lixin Dong
A large amount of protein molecules were deposited onto the membrane of a single cell using a porous pen nanodeposition method to induce intercellular signaling.
The content of this RSS Feed (c) The Royal Society of Chemistry
01 May 11:27

Inkjet Printed Large‐Area Flexible Few‐Layer Graphene Thermoelectrics

by Taneli Juntunen , Henri Jussila , Mikko Ruoho , Shouhu Liu , Guohua Hu , Tom Albrow‐Owen , Leonard W. T. Ng , Richard C. T. Howe , Tawfique Hasan , Zhipei Sun , Ilkka Tittonen
Advanced Functional Materials, EarlyView.
01 May 11:25

Ultrahigh Performance Nanoengineered Graphene–Concrete Composites for Multifunctional Applications

by Dimitar Dimov , Iddo Amit , Olivier Gorrie , Matthew D. Barnes , Nicola J. Townsend , Ana I. S. Neves , Freddie Withers , Saverio Russo , Monica Felicia Craciun
Advanced Functional Materials, EarlyView.
17 Apr 15:09

Narrow-gap physical vapour deposition synthesis of ultrathin SnS1-xSex (0 [less-than-or-equal] x [less-than-or-equal] 1) two-dimensional alloys with unique polarized Raman spectra and high (opto)electronic properties

Nanoscale, 2018, 10,8787-8795
DOI: 10.1039/C8NR00856F, Paper
Wei Gao, Yongtao Li, Jianhua Guo, Muxun Ni, Ming Liao, Haojie Mo, Jingbo Li
An improved physical vapour deposition for achieving ultrathin SnS1-xSex alloyed nanosheets with unique anisotropic Raman characteristics and good (opto)electrical performance.
The content of this RSS Feed (c) The Royal Society of Chemistry