Shared posts

08 Sep 06:40

[ASAP] Palladium Extraction Following Metal-Catalyzed Reactions: Recent Advances and Applications in the Pharmaceutical Industry

by Marina Economidou, Nisha Mistry, Katherine M. P. Wheelhouse, and David M. Lindsay

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Organic Process Research & Development
DOI: 10.1021/acs.oprd.3c00210
07 Sep 06:53

Hydrogen-bond-acceptor ligands enable distal C(sp3)–H arylation of free alcohols

06 Sep 12:14

NMR deconvolution in the blink of an AI

by Martin Priessner

Nature Reviews Chemistry, Published online: 30 August 2023; doi:10.1038/s41570-023-00538-2

NMR spectroscopic data can now be fed to algorithms capable of deconvoluting the peaks in the search for its structure. Feeding the software with experimental and modelled data means that accurate fits can be produced in little time.
05 Sep 07:37

[ASAP] Poisonous Truth about the Mercury Drop Test: The Effect of Elemental Mercury on Pd(0) and Pd(II)ArX Intermediates

by Ian C. Chagunda, Tiago Fisher, Makenna Schierling, and J. Scott McIndoe

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Organometallics
DOI: 10.1021/acs.organomet.3c00340
29 Aug 15:08

[ASAP] Catalytic Asymmetric P–H Insertion Reactions

by Xiu Gu, Xiaoyu Mo, Wen-Ju Bai, Peng Xie, Wenhao Hu, and Jun Jiang

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Journal of the American Chemical Society
DOI: 10.1021/jacs.3c06906
18 Aug 06:20

[ASAP] Catalytic Conversion of Ethanol to Oxygen-Containing Value-Added Chemicals

by Lei He, Bai-Chuan Zhou, Dan-Hui Sun, Wen-Cui Li, Wen-Lu Lv, Jia Wang, Yong-Qi Liang, and An-Hui Lu

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ACS Catalysis
DOI: 10.1021/acscatal.3c01481
18 Aug 06:18

[ASAP] Access to Amino Lactones through Palladium-Catalyzed Oxyamination with Aromatic Amines as the Nitrogen Source

by Chao Liu, Jiahao Wu, Xiangwen Tan, Jinhui Zhang, Wanqing Wu, and Huanfeng Jiang

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ACS Catalysis
DOI: 10.1021/acscatal.3c02864
18 Aug 05:54

I’m a climate scientist. Here’s how I’m handling climate grief

by Kimberley R. Miner

Nature, Published online: 17 August 2023; doi:10.1038/d41586-023-02619-0

Researchers must find personal ways to cope with impending losses — one way is by taking small solutions-oriented actions, says Kimberley R. Miner.
18 Aug 05:48

[ASAP] Association between Serviceability and Recyclability of Amine-Cured Epoxy Thermosets

by Yuwei Long, Lan Bai, Lulu Liu, Chengfeng Shen, Qiuyue Chen, Xuehui Liu, Shimei Xu, and Yu-Zhong Wang

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ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.3c03486
18 Aug 05:47

[ASAP] Separation and Solvent Based Material Recycling of Polycarbonate from Electronic Waste

by Evan Yu, Kalsoom Jan, and Wan-Ting Chen

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ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.3c03152
16 Aug 06:46

[ASAP] We Already Know Everything about Oxidative Addition to Pd(0): Do We?

by Jordan Rio, Haosheng Liang, Marie-Eve L. Perrin, Luca A. Perego, Laurence Grimaud, and Pierre-Adrien Payard

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ACS Catalysis
DOI: 10.1021/acscatal.3c01943
16 Aug 06:46

[ASAP] Phosphorus and Nitrogen Codoped Carbon Nanoparticles as Both Anode and Cathode Materials with Enhanced Li+/PF6– Storage for High Energy Density Lithium-Ion Capacitors

by Lina Kong, Xueyan Xu, Liyin Hou, Meichen Liu, Xufeng Zhou, Zhaoping Liu, and Guangjie Shao

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ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.3c02068
16 Aug 06:44

Drone missions uncover hidden features of the Battle of the Bulge

Nature, Published online: 15 August 2023; doi:10.1038/d41586-023-02572-y

Laser-based system penetrates the deep forest covering the site of a key battle in the Second World War.
11 Aug 06:56

[ASAP] A Dihydrazone as a Remarkably Nitrogen-Rich Thermostable and Insensitive Energetic Material

by Jatinder Singh, Richard J. Staples, and Jean’ne M. Shreeve

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Organic Letters
DOI: 10.1021/acs.orglett.3c02240
11 Aug 06:55

Bronze Age deforestation changed Europe’s climate

Nature, Published online: 10 August 2023; doi:10.1038/d41586-023-02525-5

Tree-cutting driven by the switch to farming is linked with warmer summers in southern Europe.
09 Aug 14:15

[ASAP] Game of Aliphatics: A Density Functional Theory Study of Base-Catalyzed Substrate-Controlled Dimerizations of Aliphatic Alkynones

by Anton V. Kuzmin and Dmitrii A. Shabalin
Marnix van der Kolk

Meest geforceerde GoT reference ooit

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The Journal of Organic Chemistry
DOI: 10.1021/acs.joc.3c01106
09 Aug 13:18

TXPhos: a highly stable and efficient ligand designed for ppm level Pd-catalyzed Suzuki–Miyaura coupling in water

Green Chem., 2023, 25,6635-6641
DOI: 10.1039/D2GC04885J, Communication
Lei Zhang, Wenbo Hu, Heng Li, Jicheng Shi, Bingxin Yuan
TXPhos, a highly stable and efficient ligand designed for ppm level Pd catalyzed Suzuki–Miyaura coupling reactions under micellar conditions with a TOF up to 40 000 s−1.
The content of this RSS Feed (c) The Royal Society of Chemistry
08 Aug 07:18

[ASAP] ChatGPT Chemistry Assistant for Text Mining and the Prediction of MOF Synthesis

by Zhiling Zheng, Oufan Zhang, Christian Borgs, Jennifer T. Chayes, and Omar M. Yaghi

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Journal of the American Chemical Society
DOI: 10.1021/jacs.3c05819
07 Aug 09:36

[ASAP] A Proposal That Would Ban Manufacture, Supply, and Use of All Fluoropolymers and Most Fluorinated Reagents within the Entire EU

by Nicholas D. Tyrrell

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Organic Process Research & Development
DOI: 10.1021/acs.oprd.3c00199
04 Aug 13:44

[ASAP] Scalable Synthesis of Antihistamines and Sensipar via Intensified Hydrogen Borrowing Methodology

by Xiao Qian Ng, Yu Zhao, and Valerio Isoni

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ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.3c02803
04 Aug 13:43

Lower Impact Factors, but not Lower Impact. 4–6 is the new 5–6

by Joe P. Richmond
Advanced Synthesis &Catalysis, Volume 365, Issue 17, Page 2765-2766, September 5, 2023.
03 Aug 10:59

Could this ancient whale be the heaviest animal ever?

by Emma Marris
Marnix van der Kolk

Nee dat kan niet. Het zwaarste dier ooit is duidelijk yo ...

Nature, Published online: 02 August 2023; doi:10.1038/d41586-023-02457-0

Massive vertebrae and other fossilized remains found in Peru point to an Eocene-epoch beast of colossal proportions.
03 Aug 08:35

Continuous-flow reductive N-methylation with highly active heterogeneous Pd catalysts and sequential-flow synthesis of N-monomethyl amines

Marnix van der Kolk

@ewoud doet martina niet zoiets?

Green Chem., 2023, 25,7524-7528
DOI: 10.1039/D3GC01472J, Communication
Yuki Saito, Taisei Senzaki, Ken Nishizawa, Shū Kobayashi
We describe continuous-flow N-methylation with formaldehyde and H2 using heterogeneous Pd catalysts as a green synthetic method to access N-methyl amines.
The content of this RSS Feed (c) The Royal Society of Chemistry
03 Aug 07:25

[ASAP] A Novel Green Process for Recovery of Transition Metal Ions from Used Lithium-ion Batteries by Selective Coordination of Ethanol

by Yi Luo, Chengzhe Yin, and Leming Ou

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ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.3c01537
02 Aug 09:41

Modern chemistry is rubbish

by Hannah Flerlage

Nature Reviews Chemistry, Published online: 31 July 2023; doi:10.1038/s41570-023-00523-9

To combat worsening environmental crises, chemistry needs a redesign. We see the need for a triple focus on efficiency, safety and circularity as a prerequisite for chemistry to serve sustainability and ensure that essential chemical products and processes are waste-free, functional and safe for both humans and the environment.
01 Aug 06:22

Fluorocarbonylation via palladium/phosphine synergistic catalysis

27 Jul 06:53

[ASAP] Mechanistic Investigations of Phenoxyimine–Cobalt(II)-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Cross-Coupling

by L. Reginald Mills, David Gygi, Eric M. Simmons, Steven R. Wisniewski, Junho Kim, and Paul J. Chirik

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Journal of the American Chemical Society
DOI: 10.1021/jacs.3c02103
27 Jul 06:53

Why Oppenheimer has important lessons for scientists today

by Davide Castelvecchi

Nature, Published online: 26 July 2023; doi:10.1038/d41586-023-02409-8

Atomic bomb historian Richard Rhodes talks to Nature about how researchers fare in the film, and what it gets right and wrong.
26 Jul 14:42

[ASAP] The Nitrosamine “Saga”: Lessons Learned from Five Years of Scrutiny

by Raphael Nudelman, Grace Kocks, Bruno Mouton, David J. Ponting, Joerg Schlingemann, Stephanie Simon, Graham F. Smith, Andrew Teasdale, and Anne-Laure Werner

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Organic Process Research & Development
DOI: 10.1021/acs.oprd.3c00100
26 Jul 14:40

[ASAP] Facile Strategy to Design a Cellulose Nanocrystal-Based Nanocomposite Fire Retardant with Strong Smoke Suppression Efficiency

by Yunyun Zhang, Hou-Yong Yu, Yanjuan Dong, Xiaohua Wang, Xuefei Chen, Xue Ma, and Peng-Cheng Qian

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ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.3c02458