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10 Jun 10:06

Synthetic Rashba spin–orbit system using a silicon metal-oxide semiconductor

by Soobeom Lee

Nature Materials, Published online: 03 June 2021; doi:10.1038/s41563-021-01026-y

Silicon is a light element with high lattice inversion symmetry, and so is not expected to possess a substantial spin–orbit interaction (SOI), which is desirable for spintronics. Here, a silicon-based heterostructure is demonstrated to have a gate-tuneable Rashba-type SOI.
05 Jun 09:34

Ternary 2D Layered Material FePSe3 and Near‐Infrared Photodetector

by Tengfei Xu, Man Luo, Niming Shen, Yiye Yu, Zhen Wang, Zhuangzhuang Cui, Jiayi Qin, Fang Liang, Yunfeng Chen, Yong Zhou, Fang Zhong, Meng Peng, Muhammad Zubair, Ning Li, Jinshui Miao, Wei Lu, Chenhui Yu, Weida Hu
Ternary 2D Layered Material FePSe3 and Near-Infrared Photodetector

This work demonstrates the synthesis and characterization of electrical and optoelectronic properties of a novel ternary 2D layered material (2DLM) FePSe3 and its FET-type photodetector by an optimized CVT method. A wide photocurrent response from visible to near-infrared is achieved, highlighting the opportunity of ternary 2DLM in photodetection of continuum spectrum.


Abstract

The preparation of ternary 2D layered material (2DLM) FePSe3 and field-effect transistor (FET) type photodetector are investigated. By advancing an optimized chemical vapor transport method, bulk crystal FePSe3 is synthesized within several growth hours instead of routinely required weeks, from which 2DLM FePSe3 flakes with a thickness of ≈22.0 nm and high crystalline quality are obtained through mechanical exfoliation. Ohmic contacts for FET structure with good linear conductivity and thermal stability are implemented through the combination of electron-beam lithography and thermal evaporation techniques. Transfer characteristics prove the p-type conductivity of the 2DLM FePSe3 channel. The transistor devices exhibit good performance at 637 nm with a detectivity of 1.17 × 107 Jones. More importantly, a wide photocurrent spectrum from visible (450 nm) to near-infrared (940 nm) of ternary 2DLMs is observed, which is attributed to the improvement of crystal quality of 2DLM, relatively low surface defect states, and high-performance Ohmic electrodes. This work promotes the development of ternary 2DLM and photodetector that are still in their infancy towards continuous broad-spectrum technology.

05 Jun 09:33

[ASAP] Real-Time Multiscale Monitoring and Tailoring of Graphene Growth on Liquid Copper

by Maciej Jankowski, Mehdi Saedi, Francesco La Porta, Anastasios C. Manikas, Christos Tsakonas, Juan S. Cingolani, Mie Andersen, Marc de Voogd, Gertjan J. C. van Baarle, Karsten Reuter, Costas Galiotis, Gilles Renaud, Oleg V. Konovalov, and Irene M. N. Groot

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ACS Nano
DOI: 10.1021/acsnano.0c10377
05 Jun 09:33

[ASAP] Heterogeneously Integrated Graphene/Silicon/Halide Waveguide Photodetectors toward Chip-Scale Zero-Bias Long-Wave Infrared Spectroscopic Sensing

by Yiming Ma, Yuhua Chang, Bowei Dong, Jingxuan Wei, Weixin Liu, and Chengkuo Lee

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ACS Nano
DOI: 10.1021/acsnano.1c01859
05 Jun 09:33

[ASAP] Multidimensional Ti3C2Tx MXene Architectures via Interfacial Electrochemical Self-Assembly

by Taeyeong Yun, Gang San Lee, Jungwoo Choi, Hyerim Kim, Geon Gug Yang, Ho Jin Lee, Jin Goo Kim, Hyuck Mo Lee, Chong Min Koo, Joonwon Lim, and Sang Ouk Kim

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ACS Nano
DOI: 10.1021/acsnano.1c01727
05 Jun 09:32

[ASAP] Structural Monoclinicity and Its Coupling to Layered Magnetism in Few-Layer CrI3

by Xiaoyu Guo△, Wencan Jin△, Zhipeng Ye, Gaihua Ye, Hongchao Xie, Bowen Yang, Hyun Ho Kim, Shaohua Yan, Yang Fu, Shangjie Tian, Hechang Lei, Adam W. Tsen, Kai Sun, Jia-An Yan, Rui He, and Liuyan Zhao

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ACS Nano
DOI: 10.1021/acsnano.1c02868
05 Jun 07:59

[ASAP] Strain-Induced Bandgap Enhancement of InSe Ultrathin Films with Self-Formed Two-Dimensional Electron Gas

by Zhimo Zhang, Yuan Yuan, Weiqing Zhou, Chen Chen, Shengjun Yuan, Hualing Zeng, Ying-Shuang Fu, and Wenhao Zhang

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ACS Nano
DOI: 10.1021/acsnano.1c03724
05 Jun 07:59

[ASAP] Breathable Ti3C2Tx MXene/Protein Nanocomposites for Ultrasensitive Medical Pressure Sensor with Degradability in Solvents

by Mingyuan Chao, Lingzhang He, Min Gong, Na Li, Xiaobin Li, Longfei Peng, Feng Shi, Liqun Zhang, and Pengbo Wan

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ACS Nano
DOI: 10.1021/acsnano.1c00472
05 Jun 07:55

Author Correction: Strong correlations and orbital texture in single-layer 1T-TaSe2

by Yi Chen

Nature Physics, Published online: 03 June 2021; doi:10.1038/s41567-021-01283-3

Author Correction: Strong correlations and orbital texture in single-layer 1T-TaSe2
05 Jun 07:47

Ultrafast non-volatile flash memory based on van der Waals heterostructures

by Lan Liu

Nature Nanotechnology, Published online: 03 June 2021; doi:10.1038/s41565-021-00921-4

MoS2/hBN/graphene van der Waals heterostructures with a clean interface and optimized barrier height and gate coupling ratio enable the realization of ultrafast non-volatile flash memory.
05 Jun 07:47

Electrical tuning of optically active interlayer excitons in bilayer MoS2

by Namphung Peimyoo

Nature Nanotechnology, Published online: 03 June 2021; doi:10.1038/s41565-021-00916-1

The existence of interlayer excitons with strong oscillator strength in bilayer MoS2 enables their electrical manipulation up to room temperature.
05 Jun 07:40

Author Correction: Chern insulators, van Hove singularities and topological flat bands in magic-angle twisted bilayer graphene

by Shuang Wu

Nature Materials, Published online: 01 June 2021; doi:10.1038/s41563-021-00997-2

Author Correction: Chern insulators, van Hove singularities and topological flat bands in magic-angle twisted bilayer graphene
05 Jun 07:34

The twists and turns of chiral chemistry

by Lewis E. MacKenzie

Nature Chemistry, Published online: 01 June 2021; doi:10.1038/s41557-021-00729-8

Chirality is fundamental to chemistry, molecular biology and photonics, but chirality itself is not often in the spotlight. Lewis E. MacKenzie and Patrycja Stachelek report on the 2021 Chiral Materials meeting, which explored how chirality manifests in functional materials, and how it can lead to new technological applications.
05 Jun 07:32

Signatures of moiré trions in WSe2/MoSe2 heterobilayers

by Erfu Liu

Nature, Published online: 02 June 2021; doi:10.1038/s41586-021-03541-z

Optical experiments on WSe2/MoSe2 heterobilayers reveal signatures of moiré trions, including interlayer emission with sharp lines and a complex charge-density dependence, features that differ markedly from those of conventional trions.
05 Jun 07:31

Intrinsic toughening and stable crack propagation in hexagonal boron nitride

by Yingchao Yang

Nature, Published online: 02 June 2021; doi:10.1038/s41586-021-03488-1

Single-crystal monolayer hexagonal boron nitride is unexpectedly tough owing to its asymmetric lattice structure, which facilitates repeated crack deflection, crack branching and edge swapping, enhancing energy dissipation.
31 May 08:16

Magnetic‐Sensitive Crack Sensor with Ultrahigh Sensitivity at Room Temperature by Depositing Graphene Nanosheets upon a Flexible Magnetic Film

by Jianyu Huang, Zheng Ma, Zhenhua Wu, Linghui Peng, Bin Su
Magnetic-Sensitive Crack Sensor with Ultrahigh Sensitivity at Room Temperature by Depositing Graphene Nanosheets upon a Flexible Magnetic Film

A new-type magnetic-sensitive crack sensor is designed by depositing graphene nanosheets upon a flexible magnetic film through a facial infrared drying technique. Such a sensor can obtain an ultra-high sensitivity with relative resistance change of 4.0 × 1010 at room temperature and an excellent cycling stability over 6000 cycles toward a moderate magnetic field.


Abstract

Flexible magnetic field sensors attract significant interests in magnetic detection and flexible electronics. However, two challenges, low sensitivity, and limited working range, impede their practical application. Herein, a new type of magnetic-sensitive crack sensor (M-CS) by depositing graphene nanosheets upon a flexible magnetic film through a facial infrared drying technique is reported. The M-CS exhibits an ultrahigh sensitivity (relative resistance change up to 4.0 × 1010) toward a moderate magnetic field of 43 mT at room temperature. In addition, the M-CS shows a long cycling stability over 10 000 cycles. Such a superior sensitivity is attributed to physically cutting/recovering the pathways of electron transport through nanosheets’ separation/contact. Diverse experimental parameters, such as the concentration of graphene solution and the thickness of bottom magnetic substrates, have been tailored to improve the magnetic sensitivity of M-CS. Furthermore, the array of M-CSs with different relative resistance change can be used as the cipher key to recognize aimed magnetic signal without contact. It is believed that the M-CS with an ultrahigh magnetic sensitivity at operational condition and long-term stability could benefit the development of magneto-sensitive sensors, and exploit the application of 2D materials in flexible electronic devices.

31 May 08:15

1/f Noise Characterization of Bilayer MoS2 Field‐Effect Transistors on Paper with Inkjet‐Printed Contacts and hBN Dielectrics

by Lorenzo Pimpolari, Gabriele Calabrese, Silvia Conti, Robyn Worsley, Subimal Majee, Dmitry K. Polyushkin, Matthias Paur, Cinzia Casiraghi, Thomas Mueller, Giuseppe Iannaccone, Massimo Macucci, Gianluca Fiori
1/f Noise Characterization of Bilayer MoS2 Field-Effect Transistors on Paper with Inkjet-Printed Contacts and hBN Dielectrics

A detailed low-frequency noise analysis of bilayer MoS2 transistors fabricated on paper substrate with inkjet-printed dielectrics and contacts is presented. The extracted noise figure of merit is comparable to those reported for monolayer and bilayer MoS2 transistors fabricated on SiO2 using conventional techniques. These results are promising for the future development of low noise flexible electronics based on 2D materials.


Abstract

1/f noise represents the dominant source of noise in the low-frequency range in several physical systems, including field-effect transistors. Its investigation can provide very important information on the fabrication process, highlighting the steps that are more prone to the introduction of defects. Here, 1/f noise in bilayer MoS2 transistors on paper with inkjet-printed Ag contacts and hBN dielectric is investigated. These devices are promising building blocks for future low-cost, flexible, and easily recyclable disposable electronics. The analysis of 1/f noise, performed following Hooge's empirical approach, results in a Hooge parameter ≈1–10, which is comparable to those reported for bilayer MoS2 transistors on SiO2. The present results indicate that the noise properties of the investigated devices are stable against substrate bending and are mainly determined by the printing of the dielectric, while not being sensibly affected by the use of the paper substrate. These results are promising for the further development of low noise 2D material-based flexible electronics on paper.

31 May 08:13

[ASAP] Ultrabroadband and High-Detectivity Photodetector Based on WS2/Ge Heterojunction through Defect Engineering and Interface Passivation

by Di Wu, Jiawen Guo, Chaoqiang Wang, Xiaoyan Ren, Yongsheng Chen, Pei Lin, Longhui Zeng, Zhifeng Shi, Xin Jian Li, Chong-Xin Shan, and Jiansheng Jie

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ACS Nano
DOI: 10.1021/acsnano.1c02007
31 May 08:11

[ASAP] Engineering Wafer-Scale Epitaxial Two-Dimensional Materials through Sapphire Template Screening for Advanced High-Performance Nanoelectronics

by Yuanyuan Shi, Benjamin Groven, Jill Serron, Xiangyu Wu, Ankit Nalin Mehta, Albert Minj, Stefanie Sergeant, Han Han, Inge Asselberghs, Dennis Lin, Steven Brems, Cedric Huyghebaert, Pierre Morin, Iuliana Radu, and Matty Caymax

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ACS Nano
DOI: 10.1021/acsnano.0c07761
31 May 08:09

[ASAP] Spectrum of Exfoliable 1D van der Waals Molecular Wires and Their Electronic Properties

by Yanbing Zhu, Daniel A. Rehn, Evan R. Antoniuk, Gowoon Cheon, Rodrigo Freitas, Aditi Krishnapriyan, and Evan J. Reed

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ACS Nano
DOI: 10.1021/acsnano.1c00781
28 May 05:26

Bandgap Modulation in BP Field Effect Transistor and Its Applications

by Fanqing Zhang, Jinran Yu, Jia Sun, Qijun Sun, Zhong Lin Wang
Bandgap Modulation in BP Field Effect Transistor and Its Applications

Black phosphorus (BP), with prominent features such as high carrier mobility and easily modulated band structure, fills the deficiencies of graphene and transition metal dichalcogenides. Starting from the introduction of BP's crystal structure, this work reviews the doping strategies, van der Waals heterojunction, and contact engineering thickness control technology in bandgap adjustment and performance improvement of BP-field effect transistor.


Abstract

Black phosphorus (BP), an emerging crystal material with prominent features such as high carrier mobility and easily modulated band structure, fills the deficiencies of graphene and transition metal dichalcogenides. It has become a key component of 2D materials. The biggest advantage of BP is reflected in the fixed and direct energy band structure. Starting from the introduction of BP's crystal structure, this work reviews the important role of doping strategies, van der Waals heterojunction, and contact engineering thickness control technology in bandgap adjustment and performance improvement of BP field effect transistors. The focus is to put on the enhanced performance of electronic devices in high mobility, fast response speed, wide spectral range, low power consumption, and stronger stability caused by bandgap modulation. These methods cover from advanced technology to a wide range of electrical and optoelectronic progress in recent years, showing a booming development trend. In addition, considering the breakthrough of BP in new physics and application prospects, the potential applications of the active field are highlighted in this work.

28 May 05:25

Self-biased magnetoelectric switching at room temperature in three-phase ferroelectric–antiferromagnetic–ferrimagnetic nanocomposites

by Rui Wu

Nature Electronics, Published online: 25 May 2021; doi:10.1038/s41928-021-00584-y

A three-phase system that is composed of a ferroelectric Na0.5Bi0.5TiO3 matrix in which ferrimagnetic NiFe2O4 nanocolumns coated with antiferromagnetic p-type NiO are embedded exhibits self-biased magnetoelectric switching at room temperature.
28 May 05:24

Unipolar barrier photodetectors based on van der Waals heterostructures

by Yunfeng Chen

Nature Electronics, Published online: 25 May 2021; doi:10.1038/s41928-021-00586-w

Band-engineered van der Waals heterostructures that block dark current without suppressing photocurrent can be used to build detectors with high room-temperature detectivity for visible light and blackbody infrared light.
28 May 05:16

Long-range nontopological edge currents in charge-neutral graphene

by A. Aharon-Steinberg

Nature, Published online: 26 May 2021; doi:10.1038/s41586-021-03501-7

Nanoscale imaging of edge currents in charge-neutral graphene shows that charge accumulation can explain various exotic nonlocal transport measurements, bringing into question some theories about their origins.
24 May 01:20

[ASAP] Ultrafast, Kinetically Limited, Ambient Synthesis of Vanadium Dioxides through Laser Direct Writing on Ultrathin Chalcogenide Matrix

by Bolun Wang, Ruixuan Peng, Xuewen Wang, Yueyang Yang, Enze Wang, Zeqin Xin, Yufei Sun, Chenyu Li, Yonghuang Wu, Jinquan Wei, Jingbo Sun, and Kai Liu

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ACS Nano
DOI: 10.1021/acsnano.1c03050
24 May 01:18

[ASAP] Two-Dimensional van der Waals Ferroelectrics: Scientific and Technological Opportunities

by Menghao Wu

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ACS Nano
DOI: 10.1021/acsnano.0c08483
24 May 01:18

[ASAP] Upconversion Photovoltaic Effect of WS2/2D Perovskite Heterostructures by Two-Photon Absorption

by Qixing Wang and Andrew T. S. Wee

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ACS Nano
DOI: 10.1021/acsnano.1c02782
24 May 01:17

[ASAP] Enhanced Piezoelectric Output Performance of the SnS2/SnS Heterostructure Thin-Film Piezoelectric Nanogenerator Realized by Atomic Layer Deposition

by Viet Anh Cao, Minje Kim, Weiguang Hu, Sol Lee, Sukhyeong Youn, Jiwon Chang, Hyo Sik Chang, and Junghyo Nah

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ACS Nano
DOI: 10.1021/acsnano.1c02757
24 May 01:16

[ASAP] Two-Dimensional Nanosheets-Based Soft Electro-Chemo-Mechanical Actuators: Recent Advances in Design, Construction, and Applications

by Xiaolin Zhu, Ying Hu, Guan Wu, Wei Chen, and Ningzhong Bao

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ACS Nano
DOI: 10.1021/acsnano.1c02356
24 May 01:13

Visualization of the strain-induced topological phase transition in a quasi-one-dimensional superconductor TaSe3

by Chun Lin

Nature Materials, Published online: 20 May 2021; doi:10.1038/s41563-021-01004-4

Angle-resolved photoemission spectroscopy is used to track the evolution of the electronic band structure of TaSe3 across a strain-driven topological phase transition.