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17 Apr 02:02

[ASAP] Two-Dimensional Metal Nanostructures: From Theoretical Understanding to Experiment

by Siying Yu, Cheng Zhang, and Hong Yang

TOC Graphic

Chemical Reviews
DOI: 10.1021/acs.chemrev.2c00469
17 Apr 01:56

Insertion of CO2 in metal ion-doped two-dimensional covalent organic frameworks

by Chengjun KangZhaoqiang ZhangShibo XiHe LiAdam K. UsadiDavid C. CalabroLisa Saunders BaughYuxiang WangDan ZhaoaDepartment of Chemical and Biomolecular Engineering, National University of Singapore, Singapore 117585, SingaporebInstitute of Sustainability for Chemicals, Energy and Environment, Agency for Science, Technology and Research, Jurong Island, Singapore 627833, SingaporecExxonMobil Technology and Engineering Company, Annandale, NJ 08801
Proceedings of the National Academy of Sciences, Volume 120, Issue 9, February 2023.
17 Apr 01:56

Selective binding and periodic arrangement of magic boron clusters on monolayer borophene

by Haifeng LvCaiyun ChenWenbin LiZhiwen ZhuoPeng ChengYi-Qi ZhangBaojie FengKehui WuXiaojun WuLan ChenaHefei National Research Center for Physical Sciences at the Microscale, Synergetic Innovation of Quantum Information and Quantum Technology, University of Science and Technology of China, Hefei, Anhui 230026, ChinabChinese Academy of Sciences (CAS) Center for Excellence in Nanoscience, and School of Chemistry and Materials Sciences, University of Science and Technology of China, Hefei, Anhui 230026, ChinacInstitute of Physics, Chinese Academy of Sciences, Beijing 100190, ChinadSchool of Physical Sciences, University of Chinese Academy of Sciences, Beijing 100190, ChinaeSongshan Lake Materials Laboratory, Dongguan, Guangdong 523808, ChinafHefei National Laboratory, University of Science and Technology of China, Hefei, Anhui 230088, China
Proceedings of the National Academy of Sciences, Volume 120, Issue 11, March 2023.
27 Mar 02:49

Engineering solvation in initiated chemical vapour deposition for control over polymerization kinetics and material properties

by Pengyu Chen

Nature Synthesis, Published online: 09 February 2023; doi:10.1038/s44160-023-00242-5

Manipulating the properties of polymeric thin films independent of their chemistry is challenging. Now, a vapour solvation strategy is introduced to achieve targeted properties, including molecular weight, mechanical strength and film morphology, without the need for chemical modification.
27 Mar 02:49

Synthesis of atomically thin sheets by the intercalation-based exfoliation of layered materials

by Ruijie Yang

Nature Synthesis, Published online: 13 February 2023; doi:10.1038/s44160-022-00232-z

Intercalation-based exfoliation is a reliable strategy for preparing atomically thin sheets. This Review highlights various types of intercalation-based exfoliation methods as well as the potential applications of the exfoliated nanosheets and the challenges and prospects in this emerging field.
27 Mar 02:48

A vacuum-deposited polymer dielectric for wafer-scale stretchable electronics

by Ja Hoon Koo

Nature Electronics, Published online: 02 February 2023; doi:10.1038/s41928-023-00918-y

A thin and stretchable polymer layer can be fabricated over large areas with high uniformity using a vacuum-deposition method and used as the gate dielectric in stretchy carbon-nanotube-based transistors and circuits that can function at 40% strain.
27 Mar 02:48

Hexagonal boron nitride heterostructures go large

by Don N. Futaba

Nature Electronics, Published online: 06 February 2023; doi:10.1038/s41928-023-00917-z

Multilayer hexagonal boron nitride can be synthesized over large areas and used to enhance mobility in graphene heterostructures, illustrating the potential of the material as an insulator in commercial two-dimensional electronics.
27 Mar 02:41

Large-area synthesis and transfer of multilayer hexagonal boron nitride for enhanced graphene device arrays

by Satoru Fukamachi

Nature Electronics, Published online: 06 February 2023; doi:10.1038/s41928-022-00911-x

Multilayers of hexagonal boron nitride can be grown using a chemical vapour deposition process on iron–nickel foil and integrated into a large array of graphene devices that exhibit room-temperature carrier mobilities of up to around 10,000 cm2 V−1 s−1.
27 Mar 02:41

Small-voltage multiferroic control of two-dimensional magnetic insulators

by Shanchuan Liang

Nature Electronics, Published online: 06 March 2023; doi:10.1038/s41928-023-00931-1

Magnetic hysteresis in multiferroic heterostructures formed from the two-dimensional magnetic insulator chromium germanium telluride and a thin ferroelectric polymer can be electrically controlled with voltages of around 5 V.
27 Mar 02:40

[ASAP] Nonequilibrium Scattering/Evaporation Dynamics at the Gas–Liquid Interface: Wetted Wheels, Self-Assembled Monolayers, and Liquid Microjets

by David J. Nesbitt, Alex M. Zolot, Joseph R. Roscioli, and Mikhail Ryazanov

TOC Graphic

Accounts of Chemical Research
DOI: 10.1021/acs.accounts.2c00823
27 Mar 02:37

Unidirectional coherent quasiparticles in the high-temperature rotational symmetry broken phase of AV3Sb5 kagome superconductors

by Hong Li

Nature Physics, Published online: 09 February 2023; doi:10.1038/s41567-022-01932-1

The charge density wave state in kagome superconductors is not fully understood. Now, evidence suggests that the rotational symmetry of the lattice is broken before coherence of unidirectional quasiparticles is established at a lower temperature.
27 Mar 02:37

Polarons in two-dimensional atomic crystals

by Weng Hong Sio

Nature Physics, Published online: 13 February 2023; doi:10.1038/s41567-023-01953-4

When electrons in a crystal interact with the surrounding lattice, they can form quasiparticles known as polarons. A computational approach to studying polarons in two-dimensional materials explains why they are rarely observed in these systems.
27 Mar 02:36

Mesoscopic Klein-Schwinger effect in graphene

by A. Schmitt

Nature Physics, Published online: 09 March 2023; doi:10.1038/s41567-023-01978-9

Observations of the Schwinger effect—the creation of matter by electric fields—have been hindered by the high required field strength. A mesoscopic variant of the Schwinger effect has now been realized in graphene transistors.
27 Mar 02:36

Magnetism and charge density wave order in kagome FeGe

by Xiaokun Teng

Nature Physics, Published online: 13 March 2023; doi:10.1038/s41567-023-01985-w

The observation of band structure features typical of the kagome lattice in FeGe suggests that an interplay of magnetism and electronic correlations determines the physics of this material.
27 Mar 02:14

Far-field coupling between moiré photonic lattices

by Jun Guan

Nature Nanotechnology, Published online: 13 February 2023; doi:10.1038/s41565-023-01320-7

An ultralong-range coupling was demonstrated between photonic lattices in bilayer and multilayer moiré architectures, which is mediated by dark surface lattice resonances in the vertical direction.
27 Mar 02:13

Epitaxial substitution of metal iodides for low-temperature growth of two-dimensional metal chalcogenides

by Kenan Zhang

Nature Nanotechnology, Published online: 13 February 2023; doi:10.1038/s41565-023-01326-1

High-quality crystalline two-dimensional layers of metal halides can be on mica, MoS2 or WS2 at temperatures below 400 °C.
27 Mar 02:13

Hyperbolic whispering-gallery phonon polaritons in boron nitride nanotubes

by Xiangdong Guo

Nature Nanotechnology, Published online: 23 February 2023; doi:10.1038/s41565-023-01324-3

A Purcell factor as high as 1012 is measured in atomically smooth nanocavities of hexagonal boron nitride nanotubes.
27 Mar 02:12

Relativistic quantum phenomena in graphene quantum dots

by Daniel Walkup

Nature Nanotechnology, Published online: 06 March 2023; doi:10.1038/s41565-023-01317-2

Wavefunctions in graphene artificial atoms reveal giant orbital magnetic moments.
27 Mar 02:12

Anomalous thickness dependence of photoluminescence quantum yield in black phosphorous

by Naoki Higashitarumizu

Nature Nanotechnology, Published online: 06 March 2023; doi:10.1038/s41565-023-01335-0

Thickness-dependent photoluminescence quantum yield measurements in black phosphorus reveal a free-carrier to excitonic transition, differing from the behaviour of conventional semiconductors.
27 Mar 02:12

Giant orbital magnetic moments and paramagnetic shift in artificial relativistic atoms and molecules

by Zhehao Ge

Nature Nanotechnology, Published online: 06 March 2023; doi:10.1038/s41565-023-01327-0

Electrostatically defined quantum dots in graphene constitute a testbed to study atomic and molecular physics in the ultrarelativistic regime—when the particle speed is close to the speed of light. Magnetic-field-dependent tunnelling spectroscopy experiments now reveal giant orbital magnetic moments and paramagnetic shifts in single and double quantum dots due to their relativistic nature.
27 Mar 02:10

Orthogonal electric fields turn on and turn off symmetry in BiFeO3 superlattices

Nature Materials, Published online: 02 February 2023; doi:10.1038/s41563-022-01413-z

When BiFeO3 layers are confined between TbScO3 layers in an epitaxial superlattice, crystallographically orthogonal voltages can induce reversible, non-volatile switching between polar and antipolar states in BiFeO3. This symmetry switch also leads to marked changes in the nonlinear optical response, piezoresponse and resistivity of the system.
27 Mar 02:10

Bose–Fermi mixtures in 2D solid-state superstructures

by David A. Ruiz-Tijerina

Nature Materials, Published online: 02 February 2023; doi:10.1038/s41563-022-01469-x

Two studies explore strongly correlated states of Bose–Fermi excitonic complexes realized in two distinct solid-state platforms, setting the stage for tabletop quantum simulators.
27 Mar 02:10

Exceptionally clean single-electron transistors from solutions of molecular graphene nanoribbons

by Wenhui Niu

Nature Materials, Published online: 02 February 2023; doi:10.1038/s41563-022-01460-6

Molecular graphene nanoribbons hold promise for quantum experiments in single-electron transistors but require improvements in their debundling. Here, the authors demonstrate ultra-clean transport devices by enhancing nanoribbon solubility via bulky groups on the nanoribbon edges.
27 Mar 02:10

Proximity-induced superconductivity in epitaxial topological insulator/graphene/gallium heterostructures

by Cequn Li

Nature Materials, Published online: 13 February 2023; doi:10.1038/s41563-023-01478-4

This work reports on the synthesis and proximity-induced superconductivity in a topological insulator-based, thin-film heterostructure towards the development of a scalable material platform that could potentially support robust quantum computing.
27 Mar 02:09

Single-crystalline van der Waals layered dielectric with high dielectric constant

by Congcong Zhang

Nature Materials, Published online: 09 March 2023; doi:10.1038/s41563-023-01502-7

Large-size single-crystal van der Waals layered Bi2SeO5 has been synthesized with a high dielectric constant and high breakdown field strength for two-dimensional electronics applications.
27 Mar 02:09

Axion optical induction of antiferromagnetic order

by Jian-Xiang Qiu

Nature Materials, Published online: 09 March 2023; doi:10.1038/s41563-023-01493-5

The authors demonstrate control of antiferromagnetic order using helical light.
27 Mar 02:09

Intercell moiré exciton complexes in electron lattices

by Xi Wang

Nature Materials, Published online: 09 March 2023; doi:10.1038/s41563-023-01496-2

The authors report on the emergence of intercell moiré exciton complexes where, in H-stacked WS2/WSe2 heterobilayers, the exciton’s hole from the WSe2 layer is surrounded by its bound electron’s wavefunction distributed among three adjacent moiré traps in the WS2 layer exhibiting an out-of-plane dipole and in-plane quadrupole.
27 Mar 02:09

Optically induced ultrafast magnetization switching in ferromagnetic spin valves

by Junta Igarashi

Nature Materials, Published online: 09 March 2023; doi:10.1038/s41563-023-01499-z

The authors demonstrate optically induced ultrafast magnetization reversal taking place within less than a picosecond in rare-earth-free spin valves of [Pt/Co]/Cu/[Co/Pt].
27 Mar 02:09

Author Correction: Asymmetric magnetic proximity interactions in MoSe2/CrBr3 van der Waals heterostructures

by Junho Choi

Nature Materials, Published online: 14 March 2023; doi:10.1038/s41563-023-01526-z

Author Correction: Asymmetric magnetic proximity interactions in MoSe2/CrBr3 van der Waals heterostructures
07 Feb 03:43

Pseudospin-selective Floquet band engineering in black phosphorus

by Shaohua Zhou

Nature, Published online: 01 February 2023; doi:10.1038/s41586-022-05610-3

In black phosphorus, a model semiconductor, analysis of time and angle-resolved photoemission spectroscopy measurements demonstrates a strong light-induced band renormalization with light polarization dependence, suggesting pseudospin-selective Floquet band engineering.