Nature Chemistry, Published online: 01 September 2022; doi:10.1038/s41557-022-01023-x
Given the importance of amine compounds, methods for their synthesis continue to be in high demand. Now, a palladium-catalysed strategy has been developed for the selective oxidative amination of unactivated olefins with Lewis basic amines, via C(sp3)–H activation, forming architecturally versatile and functionally diverse allylamines in a single step.Shared posts
11 Sep 21:50
Palladium-catalysed selective oxidative amination of olefins with Lewis basic amines
by Yangbin Jin
erlyj2006 likes this
03 Jan 17:48
[ASAP] Magnetic Nanoparticles: Synthesis, Anisotropy, and Applications
by Zhenhui Ma, Jeotikanta Mohapatra, Kecheng Wei, J. Ping Liu, and Shouheng Sun
Chemical Reviews
DOI: 10.1021/acs.chemrev.1c00860
Jing Wang likes this
21 Nov 14:26
An Unprecedented Octahydro-3H-oxeto[2,3,4-ij]isochromene Ring System Formed by a Trichloromethyl-Anion-Induced Reaction Cascade
by Schmidt, Witali
Synlett
DOI: 10.1055/s-0036-1588917
Sigillin A is a unique polychlorinated, insect repellent natural product, isolated recently from springtails. During the exploitation of an access to such compounds using a trichloromethyl-anion-induced epoxide opening as key step a new synthetic compound was found. A five-step cascade reaction leads to an oxeto[2,3,4-ij]isochromene compound, including a rare oxetane acetal as well as an trichloroenol ether group. Biological data on the antibacterial properties of this compound and sigillin A are reported as well.
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