08 Jun 01:38
by Li Nian, Ke Gao, Yufeng Jiang, Qikun Rong, Xiaowen Hu, Dong Yuan, Feng Liu, Xiaobin Peng, Thomas P. Russell, Guofu Zhou
High-efficiency small-molecule-based organic photovoltaics (SM-OPVs) using two electron donors (p-DTS(FBTTh2)2 and ZnP) with distinctively different absorption and structural features are reported. Such a combination works well and synergically improves device short-circuit current density (Jsc) to 17.99 mA cm−2 and fill factor (FF) to 77.19%, yielding a milestone efficiency of 11%. To the best of our knowledge, this is the highest power conversion efficiency reported for SM-OPVs to date and the first time to combine high Jsc over 17 mA cm−2 and high FF over 77% into one SM-OPV. The strategy of using multicomponent materials, with a selecting role of balancing varied electronic and structural necessities can be an important route to further developing higher performance devices. This development is important, which broadens the dimension and versatility of existing materials without much chemistry input.
High-efficiency all-small-molecule organic solar cells using two electron donors with distinctively different absorption and structural features are reported. Such a combination works well and synergically improves device current and fill factor, yielding a milestone efficiency of 10.97%.
24 May 00:22
by Yong Cui, Huifeng Yao, Bowei Gao, Yunpeng Qin, Shaoqing Zhang, Bei Yang, Chang He, Bowei Xu and Jianhui Hou
Journal of the American Chemical Society
DOI: 10.1021/jacs.7b01493
23 May 00:24
by Wenchao Zhao, Sunsun Li, Huifeng Yao, Shaoqing Zhang, Yun Zhang, Bei Yang and Jianhui Hou
Journal of the American Chemical Society
DOI: 10.1021/jacs.7b02677
12 Feb 06:19
Andong Zhang, Dr. Cheng Li, Fan Yang, Dr. Jianqi Zhang, Prof. Zhaohui Wang, Prof. Zhixiang Wei and Prof. Weiwei Li
Within arm's reach: A star-shaped porphyrin-based molecule with four perylene bisimide arms (PBI-Por) was designed as a non-fullerene electron acceptor for application in solar cells. The combination of a donor polymer with PBI-Por in a solar cell resulted in a photoresponse from λ=300 to 850 nm, with a maximum external quantum efficiency (EQE) of almost 0.70, and a promising power conversion efficiency of 7.4 %.
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12 Feb 06:17
Mind the gap: A non-fullerene electron acceptor with an ultra-narrow optical band gap of 1.24 eV was prepared. Despite a low energy loss of 0.509 eV, the organic solar cell (OSC) device demonstrated a high power conversion efficiency of 10.9 % with an impressive short-circuit current density of 25.3 mA cm−2.
[Communication]
Huifeng Yao, Yong Cui, Runnan Yu, Bowei Gao, Hao Zhang, Jianhui Hou
Angew. Chem. Int. Ed., February 01, 2017, DOI: 10.1002/anie.201610944. Read article
10 Feb 00:54
by Jin-Liang Wang, Kai-Kai Liu, Sha Liu, Fei Xiao, Zheng-Feng Chang, Yu-Qing Zheng, Jin-Hu Dou, Ru-Bo Zhang, Hong-Bin Wu, Jian Pei and Yong Cao
Chemistry of Materials
DOI: 10.1021/acs.chemmater.6b03796
19 Oct 00:40
by Hyunbum Kang, Wonho Lee, Jiho Oh, Taesu Kim, Changyeon Lee and Bumjoon J. Kim
Accounts of Chemical Research
DOI: 10.1021/acs.accounts.6b00347
11 Oct 11:45
by Oksana Ostroverkhova
Chemical Reviews
DOI: 10.1021/acs.chemrev.6b00127
08 Oct 01:51
by Sooncheol Kwon, Hongkyu Kang, Jong-Hoon Lee, Jinho Lee, Soonil Hong, Heejoo Kim, Kwanghee Lee
Due to the short diffusion length of approximately 10 nm of an exciton in bulk heterojunction (BHJ) organic solar cells (OSCs) comprising electron donors and acceptors, a formation with well phase-separated nanomorphology in BHJ films has been one of the most important issues in achieving efficient charge separation and extraction in OSCs. By adding a small amount of a high boiling point solvent or molecules to a bulk heterojunction (BHJ) solution, processing additive techniques have recently begun to offer an attractive and efficient method for controlling the nanoscale BHJ morphology of state-of-the-art OSCs with power conversion efficiencies (PCEs) exceeding approximately 11%. However, it remains unknown whether the effect of processing additives can potentially pave the way for the ongoing development of various BHJ components and the commercialization of OSCs. Here, recent progress in understanding and developing the effects of processing additives on OSCs is highlighted. This overview suggests possible guidelines for a wide range of BHJ components with respect to morphological/structural evolution. Furthermore, the rational correlations among processing additives, BHJ components, and fabrication technologies and the performance of high-performance and low-cost OSCs are discussed along with future commercialization prospects.
For efficient charge separation and extraction in a device, the specific characteristics of processing additives, such as high boiling points and selective solubility, provide a special opportunity to form a well phase-separated nanomorphology in a bulk-heterojunction (BHJ) film. The applications of processing additives to commercial OPVs can be further developed with respect to future demands for various BHJ materials, such as high performance, long-term stability and eco-friendly fabrication.
24 Sep 02:01
J. Mater. Chem. A, 2016, 4,16335-16340
DOI: 10.1039/C6TA06367E, Communication
Sachin Badgujar, Chang Eun Song, Sora Oh, Won Suk Shin, Sang-Jin Moon, Jong-Cheol Lee, In Hwan Jung, Sang Kyu Lee
We studied fullerene-free organic solar cells using rhodanine-terminated BDT3TR and O-IDTBR.
The content of this RSS Feed (c) The Royal Society of Chemistry
22 Sep 23:42
by Cheng Zhou, Guichuan Zhang, Chengmei Zhong, Xiaoe Jia, Peng Luo, Rongguo Xu, Ke Gao, Xiaofang Jiang, Feng Liu, Thomas P. Russell, Fei Huang, Yong Cao
The chemical structure of conjugated polymers plays an important role in determining their physical properties that, in turn, dictates their performance in photovoltaic devices. 5-Fluoro-2,1,3-benzothiadiazole, an asymmetric unit, is incorporated into a thiophene-based polymer backbone to generate a hole conducting polymers with controlled regioregularity. A high dipole moment is seen in regioregular polymers, which have a tighter interchain stacking that promotes the formation of a morphology in bulk heterojunction blends with improved power conversion efficiencies. Aliphatic side chain substitution is systematically varied to understand the influence of side chain length and symmetry on the morphology and resultant performance. This side chain modification is found to influence crystal orientation and the phase separated morphology. Using the asymmetric side chain substitution with regioregularity of the main chain, an optimized power conversion efficiency of 9.06% is achieved, with an open circuit voltage of 0.72 V, a short circuit current of 19.63 mA cm−2, and a fill factor over 65%. These results demonstrate that the local chemical environment can dramatically influence the physical properties of the resultant material.
The unidirectional regioregular conjugated polymers using 5-fluoro-2,1,3-benzothiadiazole (FBT) asymmetric unit were synthesized. Compared with the regiorandom control polymers, the regioregular polymers with a unidirectional fluorine atom alignment can lead to a progressive dipole moment along the backbone. The regioregular FBT polymers exhibit tighter interchain stacking and better morphology in bulk heterojunction blends, giving rise to improved power conversion efficiency.
22 Sep 23:37
by Shengbin Shi, Qiaogan Liao, Yumin Tang, Han Guo, Xin Zhou, Yulun Wang, Tingbin Yang, Yongye Liang, Xing Cheng, Feng Liu, Xugang Guo
Narrow bandgap (1.37–1.46 eV) polymers incorporating a head-to-head linkage containing 3-alkoxy-3′-alkyl-2,2′-bithiophene are synthesized. The head-to-head linkage enables polymers with sufficient solubility and the noncovalent sulfur–oxygen interaction affords polymers with high degree of backbone planarity and film ordering. When integrated into polymer solar cells, the polymers show a promising power conversion efficiency approaching 10%.
21 Sep 00:53
by Yaocheng Jin, Zhiming Chen, Sheng Dong, Nannan Zheng, Lei Ying, Xiao-Fang Jiang, Feng Liu, Fei Huang, Yong Cao
A novel naphtho[1,2-c:5,6-c′]bis([1,2,5]thiadiazole)-based narrow-bandgap π-conjugated polymer is designed for application in polymer solar cells. Remarkable power conversion efficiencies over 10% can be achieved based on both conventional and inverted device architectures with thick photoactive layers, which are processed by using chlorinated or nonhalogenated solvents, suggesting its great promise toward practical applications based on high-throughput roll-to-roll processing.
14 Sep 08:23
by Heng Lu, Jicheng Zhang, Jianya Chen, Qian Liu, Xue Gong, Shiyu Feng, Xinjun Xu, Wei Ma, Zhishan Bo
A ternary-blend strategy is presented to surmount the shortcomings of both fullerene derivatives and nonfullerene small molecules as acceptors for the first time. The optimal ternary device shows a high power conversion efficiency (PCE) of 10.4%. Moreover, a significant enhancement in PCE (≈35%) relative to both of the binary reference devices, which has never been achieved before in high-efficiency ternary devices, is demonstrated.
13 Sep 02:06
Energy Environ. Sci., 2016, 9,3464-3471
DOI: 10.1039/C6EE02255C, Paper
Kwang Hyun Park, Yujin An, Seungon Jung, Hyesung Park, Changduk Yang
Introduction of an n-type macromolecular additive (P(NDI2OD-T2) polymer) in organic solar cells brings significant improvements in power conversion efficiency along with robust thermal stability.
The content of this RSS Feed (c) The Royal Society of Chemistry
08 Sep 02:03
by Yunpeng Qin, Mohammad Afsar Uddin, Yu Chen, Bomee Jang, Kang Zhao, Zhong Zheng, Runnan Yu, Tae Joo Shin, Han Young Woo, Jianhui Hou
A highly efficient fullerene-free polymer solar cell (PSC) based on PDCBT, a polythiophene derivative substituted with alkoxycarbonyl, achieves an impressive power conversion efficiency of 10.16%, which is the best result in PSCs based on polythiophene derivatives to date. In comparison with a poly(3-hexylthiophene):ITIC-based device, the photovoltaic and morphological properties of the PDCBT:ITIC-based device are carefully investigated and interpreted.
贾宇, ZDL and 15 others like this
05 Sep 00:57
by Nailiang Qiu, Xuan Yang, Huijing Zhang, Xiangjian Wan, Chenxi Li, Feng Liu, Hongtao Zhang, Thomas P. Russell and Yongsheng Chen
Chemistry of Materials
DOI: 10.1021/acs.chemmater.6b03323
16 Dec 00:41
Chem. Commun., 2016, 52,1729-1732
DOI: 10.1039/C5CC08164E, Communication
Gao-Juan Cao, Qi Wei, Jian-Wen Cheng, Lin Cheng, Guo-Yu Yang
A well crystalline chiral aluminoborate with extra-large 24-ring channels was solvothermally made by using amines as templates. It exhibits a rare zeolite CAN-type net with very low framework density and high nonframework volume by incorporating B5O10 clusters and AlO4 tetrahedra.
The content of this RSS Feed (c) The Royal Society of Chemistry
16 Dec 00:41
Chem. Commun., 2016, 52,1839-1842
DOI: 10.1039/C5CC09463A, Communication
Ana Primo, Marta Puche, Octavian D. Pavel, Bogdan Cojocaru, Alina Tirsoaga, Vasile Parvulescu, Hermenegildo Garcia
Graphene oxide catalyzes NaClO oxidation of primary benzyl and aliphatic amines to a product distribution comprising nitriles and imines.
The content of this RSS Feed (c) The Royal Society of Chemistry
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